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Perspectivas para la producción de alquilato
DOI:
https://doi.org/10.15446/ing.investig.n39.20975Keywords:
Petroquímica, Alquilación, Obtención de alquilato, Producción de gasolinas, Catálisis, Catalizadores, Isobutano (es)Petrochemicals, Alkylation, Getting alkylate, Production of gasoline, Catalysis, Catalysts, Isobutane (en)
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Para disminuir la polución causada por la combustión de las gasolinas en automotores, se requiere la producción de gasolinas reformuladas en el país. Esto implica eliminar algunos componentes de las gasolinas corrientes e incorporar alquilato, isómeros y compuestos oxigenados, para mantener el número de octano y favorecer una combustión limpia. El proceso de alquilación actual emplea catalizadores ácidos líquidos como el H2SO4, HF y H3PO4, que presentan problemas en la salud de los operarios, son altamente corrosivos y causan contaminación ambiental por su disposición final. Actualmente, la investigación se orienta a encontrar procesos heterogéneos con catalizadores ácidos sólidos, eficientes, que eviten los problemas anteriores.
References
Bolton, H., “Zeolite chemistry and catalysis”. Elsevier. Amsterdam. 707, 1992.
Corma, A., Gómez, V., Martínez, A., “Zeolites as catalysts for alkylation of isobutene with 2-butane”. App. Catal. 119. 83-96. 1994. DOI: https://doi.org/10.1016/0926-860X(94)85026-7
Ende, D.J., Albright, L.F., “Degradation and isomerization of isoparafins while contact with sulfonic acid in alkylation units”. Ind. Eng Chem. Ref. 33. 840-848. 1994. DOI: https://doi.org/10.1021/ie00028a009
Groggins, P.A., “Unit Processes in Organic Synthesis”. McGraw-Hill Book Co., New York., 1960.
Jong, K.P., et al. “Paraffin alkylation using zeolite catalysts in a slurry reactor: Chemical engineering principles to extend catalyst life time”. Eng Sci. Vol 51, No 10, 2053-2060. 1996. DOI: https://doi.org/10.1016/0009-2509(96)00062-0
Jezak, A., (Stratco Inc.). Hidro. Proc. 47. Feb. 1994.
Kent, J.A., Riegel’s Handbook of Industrial Chemistry. Van Nostrand, Reinhold Co., New York. 514, 1993.
Le Page, J.F., et al. “Applied heterogeneous catalysis”. Inst. Frangaise du Petrole. Ed. Tecnip, Paris. 290. 1987.
Morrison, R.T., Boyd, R.N., Química orgánica. Addisson Wesley, Iberoamericana, México. 324. 1990.
Muldoon, H.C., Blake, M.I., “Systematic Organic Chemistry”. McGraw-Hill Book Co. Inc, New York. 78. 1957.
Rao, P., Vatchea, S.R., “Solid acid alkylation process development is at crucial stage”. Oil & gas. Sep. 56-61, 1996.
Uriel, N., Seminario de doctorado. Departamento de Química, Universidad. Nacional, Bogotá. Marzo de 1995.
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Copyright (c) 1998 Francisco J. Sánchez C., Alfredo Oviedo
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