Publicado

2018-10-01

A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering

Un estudio de la microestructura y resistencia a la corrosión de recubrimientos de (Zr, Si, Ti)N-Ni producidas mediante co-sputtering

DOI:

https://doi.org/10.15446/dyna.v85n207.73304

Palabras clave:

sputtering, thin films, corrosive, nickel (en)
sputtering, películas delgadas, corrosión, níquel (es)

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Autores/as

This work researches the influence of the nickel content on the structural and anticorrosive properties of ZrSiTiN films deposited by means of reactive co-sputtering on alloys of Ti6Al4V. The morphology and structure were analyzed by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD), and the chemical composition was identified via X-ray scattering spectroscopy (EDS). The corrosion resistance was studied using potentiodynamic polarization (PP) tests employing a 3.5% by weight NaCl solution. In the films, an increase of Ni up to 6.97 at% was observed, while in XRD the FCC phase of (Zr, Ti) N was identified, with a mixed orientation in planes (111) and (200), which tended to diminish with the increase of Ni. Finally, with the addition of Ni, the corrosion current densities were reduced from 5.56 𝑥 10−8 to 2.64 𝑥 10−9 𝐴/𝑐m2. The improvement in the corrosion resistance is due to the effect of the Ni on the microstructure of the system (Zr, Ti) N, which can improve the quality of the passive film and prevent crystalline defects and corrosion zones.
En el presente trabajo se investiga la influencia del contenido de níquel sobre las propiedades estructurales y anticorrosivas de películas de TiSiZrN depositadas mediante co-sputtering reactivo sobre aleaciones de Ti6Al4V. La morfología y estructura se realizó mediante microscopía electrónica de barrido (SEM) y difracción de rayos X (XRD), y la composición química se identificó mediante espectroscopía de dispersión de rayos X (EDS). La resistencia a la corrosión se estudió mediante ensayos de polarización potenciodinámica (PP) utilizando una solución de NaCl al 3.5% en peso. En las películas se observó un aumento del Ni hasta 6,97 at%, mientras que en XRD se identificó la fase fcc de (Zr,Ti)N, con una orientación mixta en los planos (111) y (200), la cual tiende a reducir con el incremento de Ni. Finalmente, con la adición de Ni se redujeron las densidades de corriente de corrosión de 5,56 𝑥 10−8 a 2,64 𝑥 10−9 𝐴/𝑐m2. La mejora de la resistencia a la corrosión se debe efecto del Ni sobre la microestructura del sistema (Zr, Ti)N, las cuales pueden mejorar la calidad de la película pasiva, prevenir defectos cristalinos y zonas de corrosión.

Referencias

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Cómo citar

IEEE

[1]
E. N. Borja-Goyeneche y J. J. Olaya-Florez, «A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering», DYNA, vol. 85, n.º 207, pp. 192–197, oct. 2018.

ACM

[1]
Borja-Goyeneche, E.N. y Olaya-Florez, J.J. 2018. A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering. DYNA. 85, 207 (oct. 2018), 192–197. DOI:https://doi.org/10.15446/dyna.v85n207.73304.

ACS

(1)
Borja-Goyeneche, E. N.; Olaya-Florez, J. J. A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering. DYNA 2018, 85, 192-197.

APA

Borja-Goyeneche, E. N. & Olaya-Florez, J. J. (2018). A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering. DYNA, 85(207), 192–197. https://doi.org/10.15446/dyna.v85n207.73304

ABNT

BORJA-GOYENECHE, E. N.; OLAYA-FLOREZ, J. J. A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering. DYNA, [S. l.], v. 85, n. 207, p. 192–197, 2018. DOI: 10.15446/dyna.v85n207.73304. Disponível em: https://revistas.unal.edu.co/index.php/dyna/article/view/73304. Acesso em: 18 mar. 2026.

Chicago

Borja-Goyeneche, Estrella Natali, y Jhon Jairo Olaya-Florez. 2018. «A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering». DYNA 85 (207):192-97. https://doi.org/10.15446/dyna.v85n207.73304.

Harvard

Borja-Goyeneche, E. N. y Olaya-Florez, J. J. (2018) «A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering», DYNA, 85(207), pp. 192–197. doi: 10.15446/dyna.v85n207.73304.

MLA

Borja-Goyeneche, E. N., y J. J. Olaya-Florez. «A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering». DYNA, vol. 85, n.º 207, octubre de 2018, pp. 192-7, doi:10.15446/dyna.v85n207.73304.

Turabian

Borja-Goyeneche, Estrella Natali, y Jhon Jairo Olaya-Florez. «A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering». DYNA 85, no. 207 (octubre 1, 2018): 192–197. Accedido marzo 18, 2026. https://revistas.unal.edu.co/index.php/dyna/article/view/73304.

Vancouver

1.
Borja-Goyeneche EN, Olaya-Florez JJ. A microstructural and corrosion resistance study of (Zr, Si, Ti)N-Ni coatings produced through co-sputtering. DYNA [Internet]. 1 de octubre de 2018 [citado 18 de marzo de 2026];85(207):192-7. Disponible en: https://revistas.unal.edu.co/index.php/dyna/article/view/73304

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CrossRef Cited-by

CrossRef citations2

1. Henry Samir Vanegas Parra, Sebastián Calderón Velasco, José Edgar Alfonso Orjuela, Jhon Jairo Olaya Florez, Sandra Carvalho. (2023). Influence of Ag Doping on the Microstructural, Optical, and Electrical Properties of ZrSiN Coatings Deposited through Pulsed-DC Reactive Magnetron Sputtering. Coatings, 13(7), p.1154. https://doi.org/10.3390/coatings13071154.

2. Julieta Cardenas, Jersson Leon, Jhon J. Olaya. (2019). Synthesis and high-temperature corrosion resistance of Ti-Zr-Si-N coatings deposited by means of sputtering. Corrosion Engineering, Science and Technology, 54(3), p.233. https://doi.org/10.1080/1478422X.2019.1573498.

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