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Structural and magnetic properties of the Bi1-xLuxFeO3 (x = 0.00, 0.02 and 0.04) system
Propiedades estructurales y magnéticas del sistema Bi1-xLuxFeO3 (x = 0.00, 0.02 y 0.04)
DOI:
https://doi.org/10.15446/dyna.v87n215.83538Palabras clave:
perovskite, lutetium, magnetic properties. (en)ferita de bismuto; lutecio; propiedades magnéticas (es)
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This paper reports the synthesis and characterization of Bi1-xLuxFeO3 (x = 0.00, 0.02 and 0.04) produced by solid-state reaction, in order to evaluate the influence of lutetium on the structural and magnetic properties of bismuth ferrite (BiFeO3). The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and magnetic analysis by vibrating sample magnetometer (VSM) in temperature range from 50 to 320 K. The obtained results allowed to confirm the formation of crystalline materials of rhombohedral structure, space-group R3c (161), with defined morphology and particle sizes between 2.25 and 4.5 μm. The Lu3+ insertion in structure generated an increasing in magnetization, purity of BiFeO3 and a decrease in the synthesis temperature compared with the reported in the literature.
Este artículo reporta la síntesis y caracterización de Bi1-xLuxFeO3 (x = 0.00, 0.02 and 0.04) producido por reacción de estado sólido, con el fin de evaluar la influencia del catión lutecio sobre las propiedades estructurales y magnéticas de la ferrita de bismuto (BiFeO3). Las muestras fueron caracterizadas por difracción de rayos X (DRX), microscopia electrónica de barrido (MEB), espectroscopia de energía dispersiva de rayos X (EDX) y análisis magnético por medio de magnetometría de muestra vibrante (VSM) en un rango de temperatura de 50 a 320 K. Los resultados obtenidos permitieron confirman la formación de materiales cristalinos de estructura romboédrica, grupo espacial R3c (161), de morfología definida y tamaños de partícula entre 2.25 y 4.50 μm. La inserción de Lu3+ en la estructura provocó un aumento en la magnetización, la pureza de BiFeO3 y una disminución en la temperatura de síntesis en comparación con lo reportado en la literatura.
Referencias
Béa, H., Gajek, M., Bibes, M., & Barthélémy, A. (2008). Spintronics with multiferroics. Journal of Physics: Condensed Matter, 20(43), pp. 1-11, 2008. DOI: https://doi.org/10.1088/0953-8984/20/43/434221
Catalan, G., & Scott, J. F. Physics and applications of bismuth ferrite. Advanced materials, 21(24), pp. 2463-2485, 2009. DOI: https://doi.org/10.1002/adma.200802849
Hill N.A. Why are there so few magnetic ferroelectrics?. J Phys Chem B, 29, pp. 6694-6709, 2000. DOI: https://doi.org/10.1021/jp000114x
Mazumder, R., Sujatha Devi, P., Bhattacharya, D., Choudhury, P., Sen, A., & Raja, M. Ferromagnetism in nanoscale BiFeO3. Applied Physics Letters, 91(6), pp. 1-13, 2007. DOI: https://doi.org/10.1063/1.2768201
Khomchenko, V. A., Troyanchuk, I. O., Kovetskaya, M. I., Kopcewicz, M., & Paixão, J. A. Effect of Mn substitution on crystal structure and magnetic properties of Bi1−xPrxFeO3 multiferroics. Journal of Physics D: Applied Physics, 45(4), pp. 1-5, 2012. DOI: https://doi.org/10.1088/0022-3727/45/4/045302
Ederer, C., & Spaldin, N. A. Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite. Physical Review B, 71(6), pp.1-4, 2005.
Mao, W., Wang, X., Han, Y., Li, X. A., Li, Y., Wang, Y. & Huang, W. Effect of Ln (Ln= La, Pr) and Co co-doped on the magnetic and ferroelectric properties of BiFeO3 nanoparticles. Journal of Alloys and Compounds, 584, pp. 520-523, 2014. DOI: https://doi.org/10.1016/j.jallcom.2013.09.117
Singh, H., & Yadav, K. L. Structural, dielectric, vibrational and magnetic properties of Sm doped BiFeO3 multiferroic ceramics prepared by a rapid liquid phase sintering method. Ceramics International, 41(8), pp. 9285-9295, 2015. DOI: https://doi.org/10.1016/j.ceramint.2015.03.212
Khomchenko, V. A., Kiselev, D. A., Bdikin, I. K., Shvartsman, V. V., Borisov, P., Kleemann, W., ... & Kholkin, A. L. Crystal structure and multiferroic properties of Gd-substituted BiFeO3. Applied Physics Letters, 93(26), pp. 1-3, 2008. DOI: https://doi.org/10.1063/1.3058708
Yuan, G. L., Or, S. W., Liu, J. M., & Liu, Z. G. Structural transformation and ferroelectromagnetic behavior in single-phase Bi1-xNdxFeO3 multiferroic ceramics. Applied physics letters, 89(5), pp. 1-4, 2006. DOI: https://doi.org/10.1063/1.2266992.
Yuan, G. L., & Or, S. W. Enhanced piezoelectric and pyroelectric effects in single-phase multiferroic Bi1-xNdxFeO3 (x = 0–0.15) ceramics. Applied physics letters, 88(6), pp. 1-3, 2006. DOI: https://doi.org/10.1063/1.2169905.
Jeon, N., Rout, D., Kim, I. W., & Kang, S. J. L. Enhanced multiferroic properties of single-phase BiFeO3 bulk ceramics by Ho doping. Applied Physics Letters, 98(7), pp. 1-3, 2011. DOI: https://doi.org/10.1063/1.3552682.
Khomchenko, V. A., Karpinsky, D. V., Kholkin, A. L., Sobolev, N. A., Kakazei, G. N., Araujo, J. P., & Paixao, J. A. Rhombohedral-to-orthorhombic transition and multiferroic properties of Dy-substituted BiFeO3. Journal of Applied Physics, 108(7), pp.1-5, 2010. DOI: https://doi.org/10.1063/1.3486500
Varshney, D., Sharma, P., Satapathy, S., & Gupta, P. K. Structural, magnetic and dielectric properties of Pr-modified BiFeO3 multiferroic. Journal of Alloys and Compounds, 584, pp. 232-239, 2014. DOI: http://dx.doi.org/10.1016/j.jallcom.2013.08.159
Lin, Y. H., Jiang, Q., Wang, Y., Nan, C. W., Chen, L., & Yu, J. Enhancement of ferromagnetic properties in BiFeO3 polycrystalline ceramic by La doping. Applied physics letters, 90(17), pp. 1-3, 2007. DOI: 10.1063/1.2732182.
Lotey, G. S., & Verma, N. K. Structural, magnetic, and electrical properties of Gd-doped BiFeO3 nanoparticles with reduced particle size. Journal of Nanoparticle Research, 14(3), pp. 1-11, 2012. DOI: https://doi.org/10.1007/s11051-012-0742-7.
Kothari, D., Reddy, VR, Gupta, A., Meneghini, C. y Aquilanti, G. Dopaje con Eu en cerámicas BiFeO3 multiferroicas estudiadas por Mossbauer y espectroscopía EXAFS. Journal of Physics: Condensed Matter, 22 (35), pp. 1-10, 2010. DOI: https://doi.org/10.1088/0953-8984/22/35/356001.
Carvalho, T. T., & Tavares, P. B. Synthesis and thermodynamic stability of multiferroic BiFeO3. Materials Letters, 62(24), pp. 3984-3986, 2008. DOI: https://doi.org/10.1016/j.matlet.2008.05.051
Miao, J. H., Fang, T. T., Chung, H. Y., & Yang, C. W. Effect of La doping on the phase conversion, microstructure change, and electrical properties of Bi2Fe4O9 ceramics. Journal of the American Ceramic Society, 92(11), pp. 2762-2764, 2009. DOI: https://doi.org/10.1111/j.1551-2916.2009.03238.x
Gautam, A., Uniyal, P., Yadav, K. L., & Rangra, V. S. Dielectric and magnetic properties of Bi1− xYxFeO3 ceramics. Journal of Physics and Chemistry of Solids, 73(2), pp. 188-192, 2012. DOI: https://doi.org/10.1016/j.jpcs.2011.11.005.
Li, Q., Bao, S., Liu, Y., Li, Y., Jing, Y., & Li, J. (2016). Influence of lightly Sm-substitution on crystal structure, magnetic and dielectric properties of BiFeO3 ceramics. Journal of Alloys and Compounds, 682, pp. 672-678, 2016. DOI: https://doi.org/10.1016/j.jallcom.2016.05.023
Sati, P. C., Arora, M., Chauhan, S., Kumar, M., & Chhoker, S. Effect of Dy substitution on structural, magnetic and optical properties of BiFeO3 ceramics. Journal of Physics and Chemistry of Solids, 75(1), pp. 105-108, 2014. DOI: https://doi.org/10.1016/j.jpcs.2013.09.003
Tang, P., Kuang, D., Yang, S., & Zhang, Y. The structural, optical and enhanced magnetic properties of Bi1− xGdxFe1− yMnyO3 nanoparticles synthesized by sol–gel. Journal of Alloys and Compounds, 622, pp. 194-199, 2015. DOI: https://doi.org/10.1016/j.jallcom.2014.10.035
Kumar, A., & Varshney, D. (2015). Structural transition and enhanced ferromagnetic properties of La, Nd, Gd, and Dy-doped BiFeO3 ceramics. Journal of Electronic Materials, 44(11), pp. 4354-4366, 2015. DOI: https://doi.org/10.1007/s11664-015-3962-7.
Karthik, T., Rao, T. D., Srinivas, A., & Asthana, S. A-Site Cation disorder and Size variance effects on the physical properties of multiferroic Bi0. 9RE0. 1FeO3 Ceramics (RE = Gd3+, Tb3+, Dy3+), pp. 1-12, 2012, arXiv preprint arXiv:1206.5606.
Gómez, J. M., Canaria, C., Burgos, R. O., Ortiz, C. A., Supelano, G. I., & Vargas, C. P. Structural study of yttrium substituted BiFeO3. In Journal of Physics: Conference Series, 687 (1), pp. 012091, 2016. DOI: 10.1088/1742-6596/687/1/012091.
Londoño, J. S., Peña, S. S., Sáchica, E. H., Pacheco, A. C., Santos, A. S., & Vargas, C. P. Structural and magnetic analysis of the Bix-1SmxFeO3 (x= 0.04 and 0.07) system. In Journal of Physics: Conference Series, 935(1), pp. 012007, 2017. DOI: 10.1088/1742-6596/935/1/012007.
Garca, F., Sánchez, F., Cortés, C. A., Barba, A., Bolarín, A. M. Mechanically assisted synthesis of multiferroic BiFeO3: Effect of synthesis parameters. Journal of Alloys and Compounds, 711, pp. 77-84, 2017. DOI: https://doi.org/10.1016/j.jallcom.2017.03.292
Köferstein, R. Synthesis, phase evolution and properties of phase-pure nanocrystalline BiFeO3 prepared by a starch-based combustion method. Journal of Alloys and Compounds, 590, pp. 324-330, 2014. DOI: https://doi.org/10.1016/j.jallcom.2013.12.120
Wang, L., Xu, J. B., Gao, B., Bian, L., & Chen, X. Y. Synthesis of pure phase BiFeO3 powders by direct thermal decomposition of metal nitrates. Ceramics International, 39, S221-S225, 2013. DOI: https://doi.org/10.1016/j.ceramint.2012.10.066
Pedro, F., Betancourt-Cantera, L. G., Bolarín-Miró, A. M., Cortés-Escobedo, C. A., Barba-Pingarrón, A., & Sánchez-De Jesús, F. Magnetoelectric coupling in multiferroic BiFeO3 by co-doping with strontium and nickel. Ceramics International, 45(8), pp. 10114-10119, 2019. DOI: https://doi.org/10.1016/j.ceramint.2019.02.058
Zhao, J., Liu, T., Xu, Y., He, Y., & Chen, W. Synthesis and characterization of Bi2Fe4O9 powders. Materials Chemistry and Physics, 128(3), pp. 388-391, 2011. DOI: https://doi.org/10.1016/j.matchemphys.2011.03.011
Layek, S., & Verma, H. C. (2015). Magnetic and dielectric properties of multiferroic BiFeO3 nanoparticles synthesized by a novel citrate combustion method. arXiv preprint, pp. 1-14, 2015. arXiv:1502.05797
Gómez, J. M., García, G. S., Palacio, C. A., & Vargas, C. P. Production and structural and magnetic characterization of a Bi1-xYxFeO3 (x = 0, 0.25 and 0.30) system. In Journal of Physics: Conference Series, IOP Publishing, 614(1), pp. 1-5, 2015. DOI: 10.1088/1742-6596/614/1/012003.
Park, T. J., Papaefthymiou, G. C., Viescas, A. J., Moodenbaugh, A. R., & Wong, S. S. Size-dependent magnetic properties of single-crystalline multiferroic BiFeO3 nanoparticles. Nano letters, 7(3), pp. 766-772, 2007. DOI: https://doi.org/10.1021/nl063039w
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