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Thermo-mechanical study of the mixture of polylactic acid PLA obtained from potato starch with an aliphatic copolyester PBSA (polybutylene sucyanate adipate)
Estudio termo-mecánico de la mezcla del ácido poliláctico obtenido a partir del almidón de la papa con un copoliéster alifático PBSA (polibutileno sucianato adipato)
DOI:
https://doi.org/10.15446/dyna.v89n221.98414Palabras clave:
dosificación; bioplástico, ácido poliláctico; propiedades termo mecánicas (es)dosages; bioplastic; polylactic acid; thermomechanical properties (en)
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La conservación del medio ambiente ha llevado a investigar algunos polisacáridos con el objetivo de obtener bioplásticos que puedan ser dosificados con otros polímeros y tener mejores propiedades. En esta investigación, se realizó un estudio termo mecánico de dosificaciones entre el ácido poliláctico obtenido del almidón con otro polímero tipo poliéster alifático denominado polibutileno socianato adipato. Se realizaron diferentes mezclas y análisis tales como: análisis diferencial de barrido, termogravimétrico, espectroscopia infrarroja, índice de fluidez, dureza "SHORE" y un mecánico termodinámico; y en base a los resultados obtenidos, se determinó el tipo de procesamiento que puede sufrir la dosificación. Las dosis realizadas fueron desde 94,5% de PLA con 5% de PBSA hasta 20% de PLA con 79,5% de PBSA añadiendo 0,5% de crodamida como agente lubricante. Los resultados concluyeron que el bioplástico puede ser procesado por extrusión y termoformado, debido a que los valores del índice de fusión son relativamente bajos
The conservation of the environment has led to research some polysaccharides with the objective of obtain bioplastics that can be dosed with other polymers and to has better properties. In this research, carried out a thermomechanical study of a dosage between polylactic acid obtained from potato starch with a thermoplastic polymer aliphatic polyester type called adipate socianate polybutylene. They were made different mixtures and analyzes such as differential scanning, thermogravimetric, infrared spectroscopy, fluidity index, hardness "SHORE" and a mechanical thermo-dynamic; and based on the results obtained, was determined the type of processing that the dosage can undergo. The dosages stated was from 94.5% PLA with 5% PBSA to 20% PLA with 79.5% PBSA adding 0.5% crodamide as a lubricating agent. The results concluded that the bioplastic in general can be processed by extrusion and thermoforming, because the values of the melt index are relatively low
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