Publicado

2014-05-01

Flower wastes as a low-cost adsorbent for the removal of acid blue 9

Residuos de flores como adsorbentes de bajo costo para la remoción de azul ácido 9

DOI:

https://doi.org/10.15446/dyna.v81n185.37234

Palabras clave:

adsorption, isotherms, kinetics, acid blue 9, flower wastes (en)
adsorción, isotermas, cinética, azul ácido 9, residuos de flores (es)

Descargas

Autores/as

  • Ana María Echavarria-Alvarez Universidad Nacional de Colombia - Facultad de Ciencias
  • Angelina Hormaza-Anaguano Universidad Nacional de Colombia - Facultad de Ciencias
This paper describes the use of flower wastes (carnation, rose and daisy) as a potential, alternative and low-cost adsorbent for the removal of Acid Blue 9 (AB9). The best conditions to achieve an efficient adsorption were evaluated in a batch process. With an acidic pH of 2.0, a removal exceeding 90% was obtained using concentrations of AB9 of 15.0 mgL-1 and a dosage of adsorbent of 4.0 gL-1. The equilibrium of the process was modeled using the Langmuir and Freundlich isotherms, obtaining a better fit with the latter one. Kinetic studies indicated a better fit of the process to a pseudo-second order model and negligible effect of temperature. In addition, the bromatological characterization of the adsorbent is shown.
El presente artículo describe el uso de residuos de flores (claveles, rosas y margaritas) como un adsorbente potencial, alternativo y de bajo costo para la remoción del colorante azul ácido 9 (AB9). Las mejores condiciones para lograr una adsorción eficiente fueron evaluadas en un proceso discontinuo. Un pH ácido de 2.0 permitió obtener una remoción superior al 90%, usando concentraciones de AB9 de 15.0 mgL-1 y una dosificación de adsorbente de 4.0 gL-1. El equilibrio del proceso fue modelado usando las isotermas de Langmuir y Freundlich, obteniendo un mejor ajuste con la última. Estudios cinéticos señalaron un proceso de pseudo-segundo orden y un efecto de la temperatura poco significativo. Adicionalmente, se presenta la caracterización bromatológica del adsorbente.

Referencias

Robinson, T., Chandran, B. and Nigam, P. Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water research, vol. 36 (11), pp. 2824–2830, 2002.

Robinson, T., McMullan, G., Marchant, R. and Nigam, P. Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresource technology, vol. 77 (3), pp. 247–555, 2001.

Zollinger, H. Color Chemistry Colour Chemistry: Synthesis, Properties of Organic Dyes and Pigments. Third. Zurich: Wiley-VCH, 2003, pp. 637.

Anliker, R. and Clarke, E. A. Organic dyes and pigments, in Part A. Anthropogenic compounds, the handbook of environmental chemistry, vol. 3, O. Hutzinger, Ed. Springer, 1980, pp. 181 – 215.

Kariminiaae-Hamedaani, H. R., Sakurai, A. and M. Sakakibara. Decolorization of synthetic dyes by a new manganese peroxidase-producing white rot fungus. Dyes and Pigments, 72 (2), pp. 157–162, 2007.

Bhatnagar A. and Sillanpää M. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment: a review. Chemical Engineering Journal, vol. 157 (2–3), pp. 277–296, 2010.

Rangabhashiyam, S., Anu, N. and Selvaraju, N. Sequestration of dye from textile industry wastewater using agricultural waste products as adsorbents. Journal of Environmental Chemical Engineering, vol. 1 (4), pp. 629–641, 2013.

Nethajia, S., Sivasamya, A., Thennarasua G. and Saravananb, S. Adsorption of Malachite Green dye onto activated carbon derived from Borassus aethiopum flower biomass. Journal of Hazardous Materials, vol. 181 (1–3), pp. 271–280, 2010.

Rafatullah, M., Sulaiman, O., Hashim R. and Ahmad, A. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of Hazardous Materials, vol. 177 (1–3), pp. 70–80, 2010.

Gupta V. K. and Suhas. Application of low-cost adsorbents for dye removal a review, Journal of environmental management, vol. 90 (8), pp. 2313–2342, 2009.

G. Crini, Non-conventional low-cost adsorbents for dye removal: a review. Bioresource technology, vol. 97 (9), pp. 1061–1085, 2006.

Srinivasan A. and Viraraghavan, T. Decolorization of dye wastewaters by biosorbents: a review. Journal of environmental management, vol. 91 (10), pp. 1915–1929, 2010.

Hormaza A. and Suárez García E. Estudio del proceso de Biosorción de dos colorantes estructuralmente diferentes sobre residuos avícolas. Revista de la Sociedad Química del Perú, vol. 75 (3), pp. 329–338, 2009.

Hirata, M., Kawasaki, N., Nakamura, T., Matsumoto, K., Kabayama, M., Tamura, T. and Tanada, S. Adsorption of Dyes onto Carbonaceous Materials Produced from Coffee Grounds by Microwave Treatment. Journal of Colloid and Interface Science, vol. 254 (1), pp. 17–22, 2002.

Osma, J. F., Saravia, V., J. L. Toca-Herrera, J. L. and Couto, S. R. Sunflower seed shells: a novel and effective low-cost adsorbent for the removal of the diazo dye Reactive Black 5 from aqueous solution. Journal of Hazardous Materials, vol. 147 (3), pp. 900–905, 2007.

Hameed, B. H. and Ahmad, A. Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. Journal of Hazardous Materials, vol. 164 (2–3), pp. 870–587, 2009.

Aksu, Z. Application of biosorption for the removal of organic pollutants: a review. Process Biochemistry, vol. 40 (3–4), pp. 997–1026, 2005.

Garg, V. Basic dye (methylene blue) removal from simulated wastewater by adsorption using Indian Rosewood sawdust: a timber industry waste. Dyes and Pigments, vol. 63 (3), pp. 243–250, 2004.

Forgacs, E., Cserháti, T. and Oros, G. Removal of synthetic dyes from wastewaters: a review. Environment international, vol. 30 (7), pp. 953–971, 2004.

Fernández, B. and Ayala, J. Evaluation of fly ashes for the removal of Cu, Ni and Cd from acidic waters. Dyna, vol. 77 (161), pp. 141–147, 2010.

Bansal, M., Garg, U., Singh, D. and Garg, V. K. Removal of Cr(VI) from aqueous solutions using pre-consumer processing agricultural waste: a case study of rice husk. Journal of Hazardous Materials, vol. 162 (1), pp. 312–320, 2009.

Van Soest, P. J. and Wine, R. H. Use of detergents in the analysis of fibrous feeds IV. Determination of plant cell-wall constituents. Journal of the Association of Official Analytical Chemists, 50, pp. 50–55, 1967.

Aksu, Z. and Dönmez, G. A comparative study on the biosorption characteristics of some yeasts for Remazol Blue reactive dye. Chemosphere, vol. 50 (8), pp. 1075–1083, 2003.

Chuah, T. G., Jumasiah, A., Azni, I., Katayon, S. and Thomas Choong, S. Y. Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal: an overview. Desalination, vol. 175, pp. 305–316, 2005.

Doria, G. M., Hormaza, A. and Gallego Suarez, D. Cascarilla de arroz: Material alternativo y de bajo costo para el tratameinto de aguas contaminadas con Cromo (VI). Revista Gestión y Ambiente, vol. 14 (1), pp. 73–84, 2011.

Valverde, A., Sarria, B. and Monteagudo J. Análisis comparativo de las características fisicoquímicas de la cascarilla de arroz. Scientia et Technica, vol. 5 (37), pp. 255-260, 2007.

Aksu, Z., Tatli, A. I. and Tunç, Ö. A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters. Chemical Engineering Journal, vol. 142 (1), pp. 23–39, 2008.

Akar, T., Ozcan, A. S., Tunali, S. and Ozcan, A. Biosorption of a textile dye (Acid Blue 40) by cone biomass of Thuja orientalis: estimation of equilibrium, thermodynamic and kinetic parameters. Bioresource technology, vol. 99 (8), pp. 3057–3065, 2008.

Dimensions

PlumX

Visitas a la página del resumen del artículo

808

Descargas

Los datos de descarga aún no están disponibles.

Cómo citar

[1]
“Residuos de flores como adsorbentes de bajo costo para la remoción de azul ácido 9”, DYNA, vol. 81, no. 185, pp. 132–138, May 2014, doi: 10.15446/dyna.v81n185.37234.

Licencia

Derechos de autor 2014 DYNA

Creative Commons License

Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.

El autor o autores de un artículo aceptado para publicación en cualquiera de las revistas editadas por la facultad de Minas cederán la totalidad de los derechos patrimoniales a la Universidad Nacional de Colombia de manera gratuita, dentro de los cuáles se incluyen: el derecho a editar, publicar, reproducir y distribuir tanto en medios impresos como digitales, además de incluir en artículo en índices internacionales y/o bases de datos, de igual manera, se faculta a la editorial para utilizar las imágenes, tablas y/o cualquier material gráfico presentado en el artículo para el diseño de carátulas o posters de la misma revista.