Publicado

2014-09-01

Electrodes friendly with the environment for detect heavy metal

Electrodos amistosos con el medio ambiente para detectar metales pesados

DOI:

https://doi.org/10.15446/dyna.v81n187.40758

Palabras clave:

Bismuth, Electrodes, Voltammetry, Heavy Metals. (en)
Bismuto, Electrodos, Voltamperometría, Metales Pesados (es)

Autores/as

  • Jairo Alberto Barón-Jaimez Universidad Nacional Autónoma de México
  • José Luddey Marulanda-Arévalo Universidad Tecnológica de Pereira - Grupo GIMAV
  • José José Barba-Ortega Universidad Nacional de Colombia - Sede Bogotá - Departamento de Física
In the last centuries, heavy metals have been extracted and processed industrially; today, they are part of our food chain and their detection has generated great international interest due to adverse effects, beyond allowed amounts for humans. For many years, mercury electrodes have been used to detect heavy metals; however, due to the new regulations and its high toxicity, new alternatives for its replacement as electrode in electroanalytical techniques have been investigated. Bismuth electrodes have been positioned as an alternative to this type of activity because of its many features similar to mercury and low toxicity. This paper provides an overview of this new type of electrode, along with different parameters to consider in order to obtain better results
Los últimos siglos, los metales pesados han sido extraídos y procesados industrialmente; hoy en día, hacen parte de nuestra cadena alimenticia y su detección ha generado gran interés a nivel internacional debido a los efectos adversos, en cantidades más allá de las permitidas para el ser humano. Por muchos años, los electrodos de mercurio han sido utilizados para detectar metales pesados; sin embargo, debido a las nuevas regulaciones y su alta toxicidad, nuevas alternativas para su reemplazo como electrodo en las técnicas electroanalíticas han sido investigadas. Los electrodos de Bismuto se han situado como una alternativa para este tipo de actividad debido a sus múltiples características semejantes a las del mercurio y su baja toxicidad, en este documento se presenta un panorama de este nuevo tipo de electrodo, junto con diferentes parámetros a tener en cuenta para obtener mejores resultados.

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Citas

Suwannasom, P. and Ruangviriyachai, C., Simultaneous quantification of Cd, Cu, Pb and Zn in Thai fermented food by DPASV with a microwave digestion, International Food Research Journal, 18, pp. 803-808, 2011.

Auroville, Innovative Urban Management IND-015, Heavy metals and pesticides residue in the foodstuff, Final Report, Annexes, 2003, pp. 1-9.

Barón-Jaimez J.A., Electrodos de Bismuto para Detectar Metales Pesados, MSc. Tesis, Universidad Nacional Autónoma de México UNAM, México, 2012.

He, X., Liping, Z., Dekun, H., Yuezhong, X. and Litong, J., A Nafion-coated bismuth film electrode for the determination of heavy metals in vegetable using differential pulse anodic stripping voltammetry: An alternative to mercury-based electrodes, Food Chemistry, 109, pp. 834-839, 2008.

Guzsvány, V., Papp, Z., Zbiljić, J., Vajdle, O. and Rodić, M., Bismuth modified Carbon-Based electrodes for the determination of selected neonicotinoid insecticides, Molecules, 16, pp. 4451-4466, 2011.

IFCS, Metales pesados: ¿Necesidad de más acciones globales?, 5ta Reunión del Foro Interguvernamental de Seguridad Química, Budapest, Hungría, pp. 1-16, 2006.

Estévez-Hernández, O.L., Furoiltioureas: Naturaleza de sus complejos con CdCl2 y HgCl2 y su utilización en sensores electroquímicos, Tesis, Universidad de Cádiz, España, 2006.

Kokkinos, C., Raptis, L. and Economou, A., Disposable micro-fabricated electrochemical bismuth sensors for the determination of Tl(I) by stripping voltammetry Speliotis T., Procedia Chemistry, I, pp. 1039 -1042, 2009.

Kokkinos, C., Economou, A., Raptis, I. and Efstathioua, C., Lithographically fabricated disposable bismuth-film electrodes for the trace determination of Pb(II) and Cd(II) by anodic stripping voltammetry, Electrochimica Acta, pp. 5294-5299, 2008.

Wang, J., Lu, J., Kirgöz, U., Hocevar, S. and Ogorevc, B., Insights into the anodic stripping voltammetric behavior of bismuth film electrodes, Analytical chimical Acta, 434 pp. 29-34, 2001.

Duwensee, H., Adamovski, M. and Flechsig, G.U., Adsorptive stripping voltammetric detection of daunomycin at mercury and bismuth alloy electrodes, International Journal of Electrochemical Science, 2, pp. 498-507, 2007.

Caoa, L., Jia, J. and Wang, Z., Sensitive determination of Cd and Pb by differential pulse stripping voltammetry with in situ bismuth-modified zeolite doped carbon paste electrodes, Electrochimica Acta, 53, pp. 2177-2182, 2008.

Hocevar, S., Svancara, I., Vytras, K. and Ogorevc, B., Novel electrode for electrochemical stripping analysis based on carbon paste modified with bismuth powder, Electrochimica Acta, 51, pp. 706-710, 2005.

Alghamdi, A.H., Applications of stripping voltammetric techniques in food analysis, Arabian Journal of Chemistry, 3, pp. 1-7, 2010.

Cornelis, R., Crews, H., Caruso, J. and Heumann, K., Handbook of elemental speciation: Techniques and methodology, Chapter 5.9 Speciation Analysis by Electrochemical Methods, 2003.

Baron, J., Silva-Bermudez, P. and Rodil, S.E., Sputtered Bismuth thin films as trace metal electrochemical sensors. Materials Research Society. Symp. Proc., Vol. 1477, 2012.

Meepun, N., Siriket, S. and, Dejmanee, S., Adsorptive stripping voltammetry for determination of Cadmium in the presence of Cupferron on a Nafion-coated Bismuth film electrode, International Journal of electrochemical Science, 7, pp. 10582-10591, 2012.

Serrano, N., Alberich, A., Díaz-Cruz, J.M., Ariño, C. and Esteban, M., Signal splitting in the stripping analysis of heavy metals using bismuth film electrodes: Influence of concentration range and deposition parameters, Electrochimica Acta, 53, pp. 6616-6622, 2008.

Prior, C., Lenehan, C. and Stewart-Walker, G., Utilising gallium for enhanced electrochemical copper analysis at the bismuth film electrode, Analytical Chimica Acta, 598, pp. 65-73, 2007.

Jiao, Y.W., Li, Y., Ran, G., Qun, L.H. and Bing, L.N., Determination of cadmium (II) by square wave anodic stripping voltammetry using bismuth-antimony film electrode, Sensor and Actuators B, 166-167, pp. 544-548, 2012.

Wu, Y., Bing, L.N. and Qun, L.H., Simultaneous measurement of Pb, Cd and Zn using differential pulse anodic stripping voltammetry at a bismuth / poly (p-aminobenzene sulfonic acid) film electrode, Sensor and Actuators B, 133, pp. 677-681, 2008.

Kokkinos, C., Economou, A, Raptis, I., Efstathiou, C. and Speliotis, T., Novel disposable bismuth-sputtered electrodes for the determination of trace metals by stripping voltammetry, Electrochemistry communications, 9 (12), pp. 2795-2800, 2007.

Xiong, Ch.H., Luo, H.Q. and, Li, B.N., A stannum/bismuth/poly(p-aminobenzene sulfonic acid) film electrode for measurement of Cd (II) using square wave anodic stripping voltammetry, Journal of Electroanalytical Chemistry, 651 (1), pp. 19-23, 2011.

Bedoya, C.M., Pinzón, M.J., Alfonso, J.E., Restrepo, E. and Olaya, J.J., Physical-Chemical Properties of Bismuth and Bismuth Oxides: Synthesis, Characterization and Applications, DYNA, 79 (176), pp. 139-148, 2012.

Kokkinos, C., Raptis, I., Economou, A. and Speliotis, T., Disposable micro-fabricated electrochemical bismuth sensor for the determination of Tlv(I) by stripping voltammetr, Procedia Chemistry I, pp. 1039-1042, 2009.

Economou, A., Bismuth-film electrodes: Recent developments and potentialities for electroanalysis, TrAC Trends in Analytical Chemistry, 24 (4), pp. 334-340, 2005.

Xu, H., Zeng, L., Huang, D., Xian, Y. and Jin, L. A Nafion-coated bismuth film electrode for the determination of heavy metals in vegetable using differential pulse anodic stripping voltammetry: An alternative to mercury-based electrodes, Food Chemistry, 109, pp. 834-839, 2008.

Hwang, G.H., Han, W.K., Hong, S.J., Park, J.S. and Kang, S.G., Determination of trace amounts of lead and cadmium using a bismuth/glassy carbon composite electrode, Talanta, 77, pp. 1432-1436, 2009.

Kadara, R. and Tothill, I., Development of disposable bulk-modified screen-printed electrode based on bismuth oxide for stripping chronopotentiometric analysis of lead (II) and cadmium (II) in soil and water samples, Analytica Chimica Acta, 623, pp. 76-81, 2008.

Chen, C., Niu, X., Chai, Y., Zhao, H. and Lan, M., Bismuth-based porous screen-printed carbon electrode with enhanced sensitivity for trace heavy metal detection by stripping voltammetry, Sensors and Actuators B, 178, pp. 339- 342, 2013.

Kokkinos, C., Economou, A., Disposable Nafion-modified micro-fabricated bismuth-film sensors for voltammetric stripping analysis of trace metals in the presence of surfactants, Talanta 84 (3), pp. 696-701, 2011.

European Commission, Lead Standard in Drinking Water. 11th plenary, of 11 January 2011.

Makokha, A., Mghweno, L., Magoha, H., Nakajugo, A. and Wekesa, J., Environmental lead pollution and contamination in food around Lake Victoria, Kisumu, Kenya, African Journal of Environmental Science and Technology, 2 (10), pp. 349-353,2008.