Publicado

2016-10-01

Characterization of construction and demolition waste in order to obtain Ca and Si using a citric acid treatment

Caracterización de un residuo de construcción y demolición para la obtención de Ca y Si mediante tratamiento con ácido cítrico

DOI:

https://doi.org/10.15446/dyna.v83n199.56394

Palabras clave:

construction and demolition waste (CDW), dissolution, organic acid. (en)
residuos urbanos, disolución, ácidos orgánicos (es)

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The paper analyses residual concrete (CW) degradation by organic acids and their potential use as nutrient source for degraded soils. The aims of the research were to carry out a chemical and mineralogical characterization of CW and to evaluate the dissolution of calcium and silicon from CW using citric acid in order to determine its potential use as a source of these elements for degraded soils. The chemical and mineralogical characterization made it possible to identify calcium and silicon as major elements associated with the concrete phases in the form of calcite, portlandite, hydrated calcium silicate, and hydrated calcium aluminosilicates. Calcium and silicon extraction was studied through a chemical and mineralogical analysis of CW (smaller than 4 mm), which was submerged in a citric acid solution for two days at 28 °C and 110 rpm under controlled and uncontrolled pH conditions. Based on the concentration of calcium and silicon in solution, it was possible to conclude that after acidulation, this waste can be used as a source of nutrients for soils degraded by human use.
Los ácidos orgánicos y principalmente el ácido cítrico generan daños en estructuras de concreto, comprometiendo su correcto desempeño. Por otra parte, el concreto residual (CR) es un problema ambiental debido a los grandes volúmenes generados requiriendo para su correcta disposición amplias extensiones de terrenos. El objetivo de este estudio fue caracterizar química y mineralógicamente el CR y evaluar la disolución de calcio y silicio con ácido cítrico, con el fin de determinar su uso potencial como fuente de estos elementos para suelos degradados. La caracterización permitió identificar como elementos mayoritarios el calcio y el silicio asociados a las fases del concreto como la calcita, portlandita y alumino-silicatos de calcio hidratados. La extracción de calcio y silicio fue investigada mediante análisis químico y mineralógico sobre concreto residual sumergido en solución de ácido cítrico por dos días a 28 °C y 110 rpm controlando y no controlando el pH. Debido a la concentración de calcio y silicio en solución se pudo verificar que estos residuos luego de la acidulación podrían ser empleados como fuente de nutrientes para suelos degradados antrópicamente.

Referencias

F. Rodrigues, M. T. Carvalho, L. Evangelista, and J. De Brito, “Physical-chemical and mineralogical characterization of fine aggregates from construction and demolition waste recycling plants,” J. Clean. Prod., vol. 52, pp. 438–445, 2013. DOI: 10.1016/j.jclepro.2013.02.023

M. V. Madurwar, R. V. Ralegaonkar, and S. a. Mandavgane, “Application of agro-waste for sustainable construction materials: A review,” Constr. Build. Mater., vol. 38, pp. 872–878, 2013. DOI: 10.1016/j.conbuildmat.2012.09.011

K. Rahal, “Mechanical properties of concrete with recycled coarse aggregate,” Build. Environ., vol. 42, no. 1, pp. 407–415, 2007. DOI: 10.1016/j.buildenv.2005.07.033

S. C. Angulo, C. Ulsen, V. M. John, H. Kahn, and M. a. Cincotto, “Chemical-mineralogical characterization of C&D waste recycled aggregates from Sao Paulo, Brazil,” Waste Manag., vol. 29, no. 2, pp. 721–730, 2009. Doi:10.1016/j.cemconcomp.2007.02.002.

M. C. Limbachiya, E. Marrocchino, and a. Koulouris, “Chemicalmineralogical characterisation of coarse recycled concrete aggregate,” Waste Manag., vol. 27, no. 2, pp. 201–208, 2007. Doi: doi.org/10.1016/j.wasman.2006.01.005.

C. Ulsen, H. Kahn, S. C. Angulo, and V. M. John, “Applied Mineralogy Characterization of Construction and Demolition Waste from Brazilian Recycling Plants,” Chem. Anal., 2003.

K. McNeil and T. H.-K. Kang, “Recycled Concrete Aggregates: A Review,” Int. J. Concr. Struct. Mater., vol. 7, no. 1, pp. 61–69, 2013. DOI: 10.1007/s40069-013-0032-5

C. Ulsen, H. Kahn, G. Hawlitschek, E. a. Masini, S. C. Angulo, and V. M. John, “Production of recycled sand from construction and demolition waste,” Constr. Build. Mater., vol. 40, pp. 1168–1173, 2012. DOI: dx.doi.org/10.1016/j.conbuildmat.2012.02.004

M. Wahlström, J. Laine-Ylijoki, a. Määttänen, T. Luotojärvi, and L. Kivekäs, “Environmental quality assurance system for use of crushed mineral demolition wastes in earth constructions,” Stud. Environ. Sci., vol. 71, no. C, pp. 725–734, 1997. DOI: doi.org/10.1016/S0956- 053X(99)00319-0

M. Weil, U. Jeske, and L. Schebek, “Closed-loop recycling of construction and demolition waste in Germany in view of stricter environmental threshold values.,” Waste Manag. Res., vol. 24, no. 3, pp. 197–206, 2006. DOI: 10.1177/0734242X06063686

E. C. G. Dos Santos, “Aplicação de resíduos de construção e demolição reciclados (RCD-R) em estruturas de solo reforçado. Dissertação,” Dissertação, 2007. DOI: 10.11606/D.18.2007.tde- 10042007-110106

P. Renato, O. Lasso, C. Manoel, P. Vaz, A. Carlos, and D. C. Bernardi, “CARACTERIZAÇÃO DE RESÍDUOS DE CONSTRUÇÃO E DEMOLIÇÃO RECICLADOS ( RCD-R ) PARA UTILIZAÇÃO COMO CORRETIVO DA ACIDEZ CHARACTERIZATION OF RECYCLED CONSTRUCTION AND DEMOLITION RESIDUES ( RCD-R ) FOR USE AS SOIL ACIDITY CORRECTIVE,” 2013.

F. Pacheco-Torgal and J. a. Labrincha, “The future of construction materials research and the seventh un Millennium Development Goal: A few insights,” Constr. Build. Mater., vol. 40, pp. 729–737, 2013. DOI: dx.doi.org/10.1016/j.conbuildmat.2012.11.007

D. Mottershead, A. Gorbushina, G. Lucas, and J. Wright, “The influence of marine salts, aspect and microbes in the weathering of sandstone in two historic structures,” Build. Environ., vol. 38, no. 9– 10, pp. 1193–1204, 2003. DOI: dx.doi.org/10.1016/S0360- 1323(03)00071-4

S. a Shinkafi, I. Haruna, S.A.Shinkafi, and I.Haruna, “Microorganisms associated with deteriorated desurface painted concrete buildings within Sokoto, Nigeria,” Int. J. Curr. Microbiol. Appl. Sci., vol. 2, no. 10, pp. 314–324, 2013.

J. D. Gu, T. E. Ford, N. S. Berke, and R. Mitchell, “Biodeterioration of concrete by the fungus Fusarium,” Int. Biodeterior. Biodegrad., vol. 41, no. 2, pp. 101–109, 1998. doi:10.1016/S0964- 8305(98)00034-1

T. Verdier, M. Coutand, A. Bertron, and C. Roques, “A review of indoor microbial growth across building materials and sampling and analysis methods,” Build. Environ., vol. 80, pp. 136–149, 2014. DOI: dx.doi.org/10.1016/j.buildenv.2014.05.030

L. G. Sequeda-Castañeda, A. E. Ortiz-Ardila, J. P. Correa-Cuadros, and C. López-Pérez, “Chemical and microbiological comparison of biodeterioration in colombian heritage constructions,” Univ. Sci., vol. 18, no. 1, pp. 51–63, 2013. DOI: http://dx.doi.org/10.1016/j.jclepro.2013.02.023

B. Cwalina, “Biodeterioration of Concrete,” J. Archit. Civ. Eng. Environ., no. 4, pp. 133–140, 2008.

[M. L. Coutinho, A. Z. Miller, and M. F. Macedo, “Biological colonization and biodeterioration of architectural ceramic materials: An overview,” J. Cult. Herit., 2015. DOI: http://dx.doi.org/10.1016/j.culher.2015.01.006

A. Bertron, “Understanding interactions between cementitious materials and microorganisms: a key to sustainable and safe concrete structures in various contexts,” Mater. Struct., pp. 1787–1806, 2014. DOI: 10.1617/s11527-014-0433-1

Wei, S., M. Sanchez, D. Trejo, and C. Gillis, “Microbial mediated deterioration of reinforced concrete structures,” Int. Biodeterior. Biodegrad., vol. 64, no. 8, pp. 748–754, 2010. DOI: dx.doi.org/10.1016/j.ibiod.2010.09.001

D. Nica, J. L. Davis, L. Kirby, G. Zuo, and D. J. Roberts, “Isolation and characterization of microorganisms involved in the biodeterioration of concrete in sewers,” Int. Biodeterior. Biodegrad., vol. 46, no. 1, pp. 61–68, 2000. DOI: dx.doi.org/10.1016/S0964- 8305(00)00064-0

S. Larreur-Cayol, a. Bertron, and G. Escadeillas, “Degradation of cement-based materials by various organic acids in agro-industrial waste-waters,” Cem. Concr. Res., vol. 41, no. 8, pp. 882–892, 2011. DOI: dx.doi.org/10.1016/j.cemconres.2011.04.007

E. Hoffland, T. W. Kuyper, H. Wallander, C. Plassard, A. a. Gorbushina, K. Haselwandter, S. Holmström, R. Landeweert, U. S. Lundström, A. Rosling, R. Sen, M. M. Smits, P. A. van Hees, and N. van Breemen, “The role of fungi in weathering,” Front. Ecol. Environ., vol. 2, no. 5, pp. 258–264, 2004. DOI: 10.1890/1540- 9295(2004)002

:TROFIW]2.0.CO;2

A. Rosling, T. Roose, A. M. Herrmann, F. a. Davidson, R. D. Finlay, and G. M. Gadd, “Approaches to modelling mineral weathering by fungi,” Fungal Biol. Rev., vol. 23, no. 4, pp. 138–144, 2009. DOI: dx.doi.org/10.1016/j.fbr.2009.09.003

S. Wei, Z. Jiang, H. Liu, D. Zhou, and M. Sanchez-Silva, “Microbiologically induced deterioration of concrete - A review,” Brazilian J. Microbiol., vol. 44, no. 4, pp. 1001–1007, 2013. DOI: 10.1590/S1517-83822014005000006

D. de Santos Marián, B. Monercillo Delgado, A. García Martínez, and F. L. D. La Construcción, “Gestión de residuos en las obras de construcción y demolición,” vol. 2a, p. 193, 2011. DOI: dx.doi.org/10.1016/j.jclepro.2013.02.023

M. P. Lavigne, A. Bertron, C. Botanch, L. Auer, G. Hernandez- Raquet, A. Cockx, J. N. Foussard, G. Escadeillas, and E. Paul, “Innovative approach to simulating the biodeterioration of industrial cementitious products in sewer environment. Part II: Validation on CAC and BFSC linings,” Cem. Concr. Res., vol. 79, no. March, pp. 409–418, 2016. DOI: dx.doi.org/10.1016/j.cemconres.2015.10.002

A. Bertron, G. Escadeillas, and J. Duchesne, “Cement pastes alteration by liquid manure organic acids: Chemical and mineralogical characterization,” Cem. Concr. Res., vol. 34, no. 10, pp. 1823–1835, 2004. DOI: dx.doi.org/10.1016/j.cemconres.2004.01.002

a. Bertron, J. Duchesne, and G. Escadeillas, “Degradation of cement pastes by organic acids,” Mater. Struct., vol. 40, no. 3, pp. 341–354, 2007. DOI: 10.1617/s11527-006-9110-3

a. Bertron, J. Duchesne, and G. Escadeillas, “Attack of cement pastes exposed to organic acids in manure,” Cem. Concr. Compos., vol. 27, no. 9–10, pp. 898–909, 2005. DOI: dx.doi.org/10.1016/j.cemconcomp.2005.06.003

L. De Windt and P. Devillers, “Modeling the degradation of Portland cement pastes by biogenic organic acids,” Cem. Concr. Res., vol. 40, no. 8, pp. 1165–1174, 2010. DOI: dx.doi.org/10.1016/j.cemconres.2010.03.005

De Windt, L., & Devillers, P. (2010). Modeling the degradation of Portland cement pastes by biogenic organic acids. Cement and Mejía et al / DYNA 83 (199), pp. 94-101, December 2016. 101 Concrete Research, 40(8), 1165-1174. DOI: dx.doi.org/10.1016/j.cemconres.2010.03.005

Mejía, E., Tobón, J. I., Osorno, L., & Osorio, W. (2015). Mineralogical characterization of urban construction and demolition waste: potential use as a nutrient source for degraded soils. WIT Transactions on Ecology and the Environment, 194, 399-413.

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[1]
“Caracterización de un residuo de construcción y demolición para la obtención de Ca y Si mediante tratamiento con ácido cítrico”, DYNA, vol. 83, no. 199, pp. 94–101, Oct. 2016, doi: 10.15446/dyna.v83n199.56394.

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