Publicado

2017-10-01

A new mathematical model for coal flotation kinetics

Un nuevo modelo matemático para la cinética de flotación de carbones

Palabras clave:

coal flotation, flotation rate, kinetic model (en)

Autores/as

This study describes the development and formulation of a novel mathematical model for coal flotation kinetic. The flotation rate was considered as a function of chemical, operating and petrographic parameters for a global flotation order n. The equation for flotation rate was obtained by dimensional analysis using the Rayleigh method. It shows the dependency of flotation kinetic on operating parameters, such as air velocity and particle size; chemical parameters, such as reagents dosage and solids content; and mineral and maceral composition of coal. The flotation rate equation integrates the kinetic coefficient and the intrinsic characteristics of coal with dimensional consistency, and it is expressed by three dimensionless numbers which have physical chemical meaning. The model also exhibits similarities with traditional transport phenomena models represented by dimensionless numbers and predicts the flotation kinetic constant of a Colombian coal sample showing a good correlation between experimental and calculated values.
Este estudio describe el desarrollo y formulación de un nuevo modelo matemático para la cinética de flotación de carbón. La velocidad de flotación se considera una función de parámetros químicos, operacionales y petrográficos para la flotación global de orden n. La ecuación de velocidad de flotación se obtuvo por análisis dimensional usando el método de Rayleigh. Este método muestra la dependencia de la cinética de flotación sobre los parámetros de operación tales como velocidad del aire y tamaño de partícula; parámetros químicos tales como dosis de reactivos y contenidos de sólidos; y composición mineral y maceral del carbón. La ecuación de velocidad de flotación integra el coeficiente cinético y las características intrínsecas del carbón con consistencia dimensional, y se expresa por tres números adimensionales que tienen significado químico físico. El modelo también muestra similitudes con los modelos tradicionales de fenómenos de transporte representados por números adimensionales y predice la constante cinética de flotación de un carbón Colombiano mostrando buena correlación entre los valores experimentales y calculados.

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Ahmed, N. and Jameson, G.J., Flotation kinetics. Mineral Processing and Extractive Metallurgy, Review 5, pp. 77-99, 1989. DOI: 10.1080/08827508908952645

Saleh, A.M., A study on the performance of second order models and two phase models in iron ore flotation. Physicochemical Problems of Mineral Processing, 44, pp. 215-230, 2010.

Bu, X., Xie, G., Peng, Y., Ge, L. and Ni, C., Kinetics of flotation. Order of process, rate constant distribution and ultimate recovery. Physicochemical Problems of Mineral Processing, 53, pp. 342-365, 2017.

Yianatos, J., Bergh, L., Vinnett, L., Contreras, F. and Diaz, F., Flotation rate distribution in the collection zone of industrial cells. Minerals Engineering, 23, pp. 1030-1035, 2010. DOI: 10.1016/j.mineng.2010.05.008.

Polat, M. and Chander, S., First-order flotation kinetics models and methods for estimation of the true distribution of flotation rate constants. International Journal of Mineral Processing, 58, pp. 145-166, 2000. DOI: 10.1016/S0301-7516(99)00069-1

Luo, C., He, Y., Bu, X. and Wang, S., And improved classic flotation kinetic model of narrow size slime. Journal of China University of Mining and Technology, 44, pp. 477-482, 2015.

Vinnett, L., Alvarez-Silva, M., Jaques, A., Hinojosa, F. and Yianatos, J., Batch flotation kinetics: Fractional calculus approach. Minerals Engineering, 77, pp. 167-171, 2015. DOI: 10.1016/j.mineng.2015.03.020

Ni, C., Kie, G., Jin, M., Peng, Y. and Xia, W., The difference in

flotation kinetics of various size fraction of bituminous coal between rougher and cleaner flotation processes. Powder Technology, 292, pp. 210-216, 2016. DOI: 10.1016/j.powtec.2016.02.004

Alvarez-Silva, M., Vinnett, L., Langlois, R. and Waters, K.E., A comparison of the predictability of batch flotation kinetic models. Minerals Engineering, 99, pp. 142-150, 2016. DOI: 10.1016/j.mineng.2016.08.019

Ai, G., Yang, X. and Li, X., Flotation characteristics and flotation kinetics of fine wolframite. Powder Technology, 305, pp. 377-381, 2017. DOI: 10.1016/j.powtec.2016.09.068

Xing, Y., Gui, X., Cao, Y., Wang, Y., Xu, M., Wang, D. and Li, C., Effect of compound collector and blending frother on froth stability and flotation performance of oxidized coal. Powder Technology, 305, pp. 166-173, 2017. DOI: 10.1016/j.powtec.2016.10.003

Zhang, N.N., Zhuo, C.C., Pan, J.H., Xia, W., Liu, C., Tang, M.C. and Cao, S.S., The response of diasporic-bauxite flotation to particle size based on flotation kinetic study and neural network simulation. Powder Technology, 318, pp. 272-281, 2017. DOI: 10.1016/j.powtec.2017.06.010

Brozek, M. and Mlynarczykowska, A., Analysis of kinetics models of batch flotation. Physicochemical Problems of Mineral Processing, 41, pp. 51-65, 2007.

Wierink, G., A computational framework for coupled modelling of three-phase systems with soluble surfactants. PhD dissertation, Aalto University, Helsinki, Finland, 2012.

Klassen, V.I. and Mokrousov, V.A., An introduction to the theory of flotation. Butterworths, London, 1963.

De Bruyn, P.L. and Modi, H.J., Particle size and flotation rate of quartz. Trans. AIME, 205, pp. 415-419, 1956.

Tomlinson, H.S. and Fleming, M.G., Flotation rate studies. VI International Mineral Processing Congress Proceedings, 1965, pp. 563-579.

Yoon, R. and Mao, L., Application of extended DLVO theory, IV derivation of flotation rate equation from first principles. Journal of Colloid and Interface Science, 181, pp. 613-626, 1996. DOI: 10.1006/jcis.1996.0419

Sherrel, I.M., Development of flotation rate equation from first principles under turbulent flow conditions. PhD dissertation. Virginia Polytechnic Institute and State University, Blacksburg, VA, 2004.

Piñeres, J.L., Fenómenos superficiales y cinéticos de la separación del grupo maceral vitrinita en fracciones beneficiadas de carbones colombianos obtenidas por flotación burbujeante. PhD dissertation, Universidad del Valle, Cali, Colombia, 2008.

Zhang, J.G., Factor affecting the kinetics of froth flotation. PhD Dissertation, Department of Mining and Mineral Engineering, University of Leeds, Great Britain, 1989.

Stokowski, H. and Freyberger, W.L., Model describing mechanism of the flotation process. Transaction of the Institution of Mining and Metallurgy, 94, C 61-69, 1985.

Inoue, T. and Imauzumi, T., A series of work related to flotation kinetics. 4th Joint Meeting MMIJ-AIME Proceedings, 1980. pp. 84-100.

Trahar, W.J., A rational interpretation of the role of particle size in flotation. International Journal of Mineral Processing, 8, pp. 289-327, 1981. DOI: 10.1016/0301-7516(81)90019-3

Hernáinz, F. and Calero, M., Froth flotation: kinetic models based on chemical analogy. Chemical Engineering and Processing, 40, pp. 269-275, 2001. DOI: 10.1016/S0255-2701(00)00125-2

Mohns, C.A., Effect of particle size on coal flotation kinetics. MSc. Thesis. Department of Mining Engineering, Queen’s University, Kingston, Canada, 1997.

Cilek, E.C., Estimation of flotation kinetic parameters by considering interactions of the operating variables. Minerals Engineering, 17, pp. 81-85, 2004. DOI: 10.1016/j.mineng.2003.10.008

Jovanovic, I. and Miljanovic, I., Modelling of flotation processes by classic mathematical methods - A review. Archives of Mining Sciences, 60(4), pp. 905-919, 2015. DOI: 10.1515/amsc-2015-0059

Perry, R., Green, D.W. andMaloney, J.O., Perry’s chemical engineers’ handbook, vol. 2. 6th ed. McGraw Hill, New York, 1992, pp. 2-120.

Arnold, B. and Aplan, F., The hydrophobicity of coal macerals. Fuel, 68(5), pp. 651-658, 1989. DOI: 10.1016/0016-2361(89)90168-3

Rao, S.R., Surface chemistry of froth flotation. Kluwer Academic / Plenum Publisher. New York, 2004, pp. 660-695.

Wang, L., Peng, Y., Runge, K. and Bradshaw, D., A review of entrainment: Mechanisms, contributing factors and modelling in flotation. Minerals Engineering, 70, pp. 77-91, 2015. DOI: 10.1016/j.mineng.2014.09.003

Barranco, R., Rojas, A., Barraza, J. and Lester, E., A new char combustion kinetic model 1. Formulation. Fuel, 88, pp. 2335-2339, 2009. DOI: 10.1016/j.fuel.2009.02.005