Publicado

2018-10-01

Evaluation of the lubricating power of chemical modified Sesame oil additivated with Cu and Al2O3 nanoparticles

Evaluación del poder lubricante de aceite de Ajonjolí modificado por vía química y aditivado con nanopartículas de Cu y Al2O3

Palabras clave:

Al2O3 nanoparticles, biolubricants, Cu nanoparticles, sesame oil, tribology (en)
aceite de ajonjolí, biolubricantes, nanopartículas de Al2O3, nanopartículas de Cu, tribología (es)

Descargas

Autores/as

Biolubricant from modified sesame oil (Sesamumindicum L.) was produced. The lubricant base consists of a mixture in a volume ratio of 74 parts of epoxidized sesame and 26 parts of transesterified sesame oil. This mixture was characterized by FT-IR, thermo-oxidative stability was determined and heating and cooling curves were performed, where a crystallization and solidification temperature of -8 °C was obtained. To improve the lubricating capacity of the oil blend concentrations of 0.05, 0.10, 0.15 and 0.20% of copper nanoparticles (NPsCu) and alumina nanoparticles (NPsAl2O3) were added, which had been subjected to tribological tests for the wear scar measurement and characterized by scanning electron microscopy (SEM). The addition of NPsCu and NPsAl2O3 improved the lubricating power of oil base-stock. The NPsCu percentage in modified sesame oil that showed the best lubricating performance was in the interval between 0.15-0.2; as for the oil with NPs2O3 better result was obtained with 0,05% of NPs.
Biolubricante a partir de aceite de ajonjolí modificado fue producido. La base lubricante consiste de una mezcla cuya relación en volumen fueron 74 partes de aceite epoxidado y 26 partes de aceite transesterificado de ajonjolí. Esta base lubricante fue caracterizada mediante FT-IR, se determinó la estabilidad termo-oxidativa y se realizaron curvas de calentamiento y enfriamiento, donde se obtuvo una temperatura de cristalización y solidificación de –8 °C. Para mejorar la capacidad lubricante de la mezcla de aceites se adicionaron las concentraciones de 0.05, 0.1, 0.15 y 0.20% de nanopartículas de cobre (NPsCu) y nanopartículas de alúmina (NPsAl2O3), a los cuales se les realizó ensayos tribológicos de medición del desgaste de huella y se caracterizó mediante microscopía de barrido electrónico (SEM). La adición de NPsCu y NPsAl2O3 mejoró el poder lubricante del aceite base. El porcentaje de NPsCu en el aceite de ajonjolí modificado que mostró el mejor desempeño estuvo en el intervalo entre 0.15-0.2. Para el aceite con NPsAl2O3 el mejor resultado fue obtenido con 0.05% de NPs.

Descargas

Los datos de descargas todavía no están disponibles.

Citas

Salimon, J., Salih, N. and Yousif, E., Biolubricants: Raw materials, chemical modifications and environmental benefits. European Journal of Lipid Science and Technology, 112(5), pp. 519-530, 2010. DOI: 10.1002/ejlt.200900205

Salimon, J., Salih, N. and Yousif, E., Biolubricant base stocks from chemically modified ricinoleic acid. Journal of King Saud University–Science, 24(1), pp. 11-17, 2012. DOI: 10.1016/j.jksus.2010.08.008

Bart, J., Gucciardi, E. and Cavallaro, S., Biolubricants, Science and Technology [Online], Cambridge, Woodhead Publishing, 2013. Available at: https://www.elsevier.com/books/biolubricants/bart/978-0-85709-263-2

McNutt, J. and He, Q., Development of biolubricants from vegetable oils via chemical modification. Journal of Industrial and Engineering Chemistry, 36, pp. 1-12, 2015. DOI: 10.1016/j.jiec.2016.02.008

Petran, J., Pedišić, L., Orlović, M., Podolski, S. and Bradač, V., Biolubricants from natural waste oils and fats. Goriva I Maziva [Online], 47(6), pp. 463-478, 2008. Availanle at: https://hrcak.srce.hr/file/52008

Wang, A., Chen, L., Jiang, D., Zeng, H. and Yan, Z., Vegetable oil-based ionic liquid microemulsion biolubricants: Effect of integrated surfactants. Industrial Crops and Products, 62, pp. 515-521, 2014. DOI: 10.1016/j.indcrop.2014.09.031

Boyacá, L. and Beltrán, A., Soybean epoxide production with in situ peractic acid using homogeneus catalysis. Ingeniería e Investigación, 30(1), pp. 136-140, 2010.

Ren, Q., Pan, J., Zhou, J., Na, Y., Chen, C. and Li, W., Synthesis and tribological studies of branched alcohol derived epoxidized biodiesel. Materials, 8(10), pp. 6623-6632, 2015. DOI:10.3390/ma8105326.

Nagendramma, P. and Kaul, S., Development of ecofriendly/ biodegradable lubricants: An overview. Renewable and Sustainable Energy Reviews, 16(1), pp. 764-774, 2012. DOI: 10.1016/j.rser.2011.09.002

Arumugam, S., Sriram, G. and Ellappan, R., Bio-lubricant-biodiesel combination of rapeseed oil: An experimental investigation on engine oil tribology, performance, and emissions of variable compression engine. Energy, 72, pp. 618-627, 2014. DOI: 10.1016/j.energy.2014.05.087

Erhan, S. and Asadauskas, S., Lubricant base stocks from vegetable oils. Industrial Crops and Products, 11(2–3), pp. 277-282, 2000. DOI: 10.1016/S0926-6690(99)00061-8

Garcés, R., Martínez-Force, E. and Salas, J., Vegetable oil base stocks for lubricants. Grasas y Aceites, 62(1), pp. 21-28, 2011. DOI: 10.3989/gya.045210

Igartua, A., Fernández, X., Areitioaurtena, R., Luther, R., Seyfert, C., Rausch, J., Illarramendi, I., Berg, M., Schulthei, H., Duffau, B., Plouseau, S. and Woydt, M., Biolubricants and triboreactive materials for automotive applications. Tribology International, 42(4), pp. 561-568, 2009. DOI: 10.1016/j.triboint.2008.10.015

Alves, S., Barros, B., Trajano, M., Ribeiro, K. and Moura, E., Tribological behavior of vegetable oil-based lubricants with nanoparticles of oxides in boundary lubrication conditions. Tribology International, 65, pp. 28-36, 2013. DOI: 10.1016/j.triboint.2013.03.027

Dai, W., Kheireddin, B., Gao, H. and Liang, H., Roles of nanoparticles in oil lubrication. Tribology International, 102, pp. 88-98, 2016. DOI: 10.1016/j.triboint.2016.05.020

Koppula, S. and Sudheer, N., A review on effect of adding additives and nano additives on thermal properties of gear box lubricants. International Journal Applied Engineering Research [Online], 11(5), pp. 3509-3526, 2016. Available at: https://www.ripublication.com/Volume/ijaerv11n5.htm

Yu, X., Jiang, Z., Zhao, J., Wei, D., Zhou, J., Zhou, C. and Huang, Q., The role of oxide-scale microtexture on tribological behaviour in the nanoparticle lubrication of hot rolling. Tribology International, 93(A), pp. 190-201, 2016. DOI: 10.1016/j.triboint.2015.08.049

Zulkifli, N., Kalam, M., Masjuki, H. and Yunus, R., Experimental analysis of tribological properties of biolubricant with nanoparticle additive. Procedia Engineering, 68, pp. 152-157, 2013. DOI: 10.1016/j.proeng.2013.12.161

Karak, N., Vegetable oil-based polymer nanocomposites. In: Vegetable oil-based polymers, Woodhead Publishing [Online], 2012. Available at: https://www.elsevier.com/books/vegetable-oil-based-polymers/karak/978-0-85709-710-1

Panchal, T., Patel, A., Chauhan, D., Thomas, M. and Patel, J., A methodological review on bio-lubricants from vegetable oil based resources. Renewable and Sustainable Energy Reviews, 70, pp. 65-70, 2017. DOI: 10.1016/j.rser.2016.11.105

Sharmin, E., Zafar, F., Akram, D., Alam, M. and Ahmad, S., Recent advances in vegetable oils based environment friendly coatings: A review. Industrial Crops and Products, 76, pp. 215-229, 2015. DOI: 10.1016/j.indcrop.2015.06.022

Srivastava, A. and Sahai, P., Vegetable oils as lube base stocks: A review. African Journal of Biotechnology, 12(9), pp. 880-891, 2013. DOI: 10.5897/AJB12.2823

Gulzar, M., Masjuki, H., Varman, M., Kalam, M., Mufti, R. and Zulki, N., Improving the AW / EP ability of chemically modified palm oil by adding CuO and MoS2 nanoparticles. Tribology International, 88, pp. 271-279, 2015. DOI: 10.1016/j.triboint.2015.03.035

Hernández, A., González, R., Viesca, J., Fernández, J., Díaz, J., Machado, A., Chou, R. and Riba, J., CuO, ZrO2 and ZnO nanoparticles as antiwear additive in oil lubricants. Wear, 265(3–4), pp. 422-428, 2008. DOI: 10.1016/j.wear.2007.11.013

Kedzierski, M., Viscosity and density of CuO nanolubricant. International Journal of Refrigeration, 35(7), pp. 1997-2002, 2012. DOI: 10.1016/j.ijrefrig.2012.06.012

Luo, T., Wei, X., Huang, X., Huang, L. and Yang, F., Tribological properties of Al2O3 nanoparticles as lubricating oil additives. Ceramics International, 40(5), pp. 7143-7149, 2014. DOI: 10.1016/j.ceramint.2013.12.050

Peña, L., Taha, J., Garza, L., Maldonado, D., Michalczewski, R. and Lapray, C., Effect of CuO and Al2O3 nanoparticle additives on the tribological behavior of fully formulated oils. Wear, 332-333, pp. 1256-1261, 2015. DOI: 10.1016/j.wear.2015.02.038

Guo, D., Xie, G. and Luo, J., Mechanical properties of nanoparticles: basics and applications. Journal of Physics D: Applied Physics, 47(1), pp. 25, 2014. DOI: 10.1088/0022-3727/47/1/013001

Lee, G., Park, J., Lee, M. and Rhee, C., Stable dispersion of nanodiamonds in oil and their tribological properties as lubricant additives. Applied Surface Science, pp. 10-13, 2016. DOI: 10.1016/j.apsusc.2016.12.109

Asrul, M., Zulkifli, N., Masjuki, H. and Kalam, M., Tribological properties and lubricant mechanism of nanoparticle in engine oil. Procedia Engineering, 68, pp. 320-325, 2013. DOI: 10.1016/j.proeng.2013.12.186

Yu, H., Shi, P., Xu, B., Wang, X. and Liu, Q., Tribological properties and lubricating mechanisms of Cu nanoparticles in lubricant. Transactions of Nonferrous Metals Society of China, 18, pp. 636-641, 2008. DOI: 10.1016/S1003-6326(08)60111-9

Jiao, D., Zheng, S., Wang, Y., Guan, R. and Cao, B., The tribology properties of alumina/silica composite nanoparticles as lubricant additives. Applied Surface Science, 257, pp. 5720-5725, 2011. DOI: 10.1016/j.apsusc.2011.01.084

Zin, V., Agresti, F., Barison, S., Colla, L. and Fabrizio, M., Influence of Cu, TiO2 nanoparticles and carbon nano-horns on tribological properties of engine oil. Journal of Nanoscience and Nanotechnology [Online], 15(5), pp. 3590-8, 2015. Available at: https://www.ncbi.nlm.nih.gov/pubmed/26504981

Delgado, A. and Aperador, W., Estudio comparativo del poder lubricante y estabilidad oxidativa entre el aceite de ajonjol y aceite mineral 360. Información Tecnológica, 25(4), pp. 79-90, 2014. DOI: 10.4067/S0718-07642014000400011.

Delgado, A., Palacio, O. and Aperador, W., Efecto de Butil Hidroxitolueno (BHT) en la estabilidad oxidativa de un lubricante a base de aceite de ajonjolí. Información Tecnológica, 26(4), pp. 81-88, 2015. DOI: 10.4067/S0718-07642015000400011.

Delgado, A., García, R. and Aperador, W., Estudio del poder lubricante del aceite de ajonjolí con adición de nanopartículas de cobre. Información Tecnológica, 27(6), pp. 175-184, 2016. DOI: 10.4067/S0718-07642016000600018

ASTM D4172-94, Standard test method for wear preventive characteristics of lubricating fluid (Four-Ball Method), 2010.

Abdullah, B.M. and Salimon, J., Epoxidation of vegetable oils- catalyst, methods and advantages. Journal of Applied Sciences, 10, pp. 1545-1553, 2010. DOI: 10.3923/jas.2010.1545.1553

Okieimen, F., Pavithran, C. and Bakare, I., Epoxidation and hydroxlation of rubber seed oil: One-pot multi-step reactions. European Journal of Lipid Science and Technology, 107(5), pp. 330-336, 2005. DOI: 10.1002/ejlt.200401126

Wadumesthrige, K., Salley, S. and Simon, K., Effects of partial hydrogenation, epoxidation, and hydroxylation on the fuel properties of fatty acid methyl esters. Fuel Processing Technology, 90(10), pp. 1292-1299, 2009. DOI: 10.1016/j.fuproc.2009.06.013

Alam, M., Akram, D., Sharmin, E., Zafar, F. and Ahmad, S., Vegetable oil based eco-friendly coating materials: A review article. Arabian Journal of Chemistry, 7(4), pp. 469-479, 2014. DOI: 10.1016/j.arabjc.2013.12.023

Berasategi, I., Barriuso, B., Ansorena, D. and Astiasarán, I., Stability of avocado oil during heating: Comparative study to olive oil. Food Chemistry, 132(1), pp. 439-446, 2012. DOI: 10.1016/j.foodchem.2011.11.018

de Torres, M., Arends, I., Mayoral, J., Pires, E. and Jiménez-Osés, G., A highly efficient, green and recoverable catalytic system for the epoxidation of fatty esters and biodiesel with H2O2. Applied Catalysis A: General, 425-426, pp. 91-96, 2012. DOI: 10.1016/j.apcata.2012.03.009

Solís, J., Amador, C., Hernández, M. and Durán-de Bazúa, C., Caracterización fisicoquímica y comportamiento térmico del aceite de almendra de guanábana (Annona muricata, L). Grasas y aceites, 61(1), pp. 58-66, 2010. DOI: 10.3989/gya.064309

Shahnazar, S., Bagheri, S. and Abd, S., Enhancing lubricant properties by nanoparticle additives. International Journal of Hydrogen Energy, 41(4), pp. 3153-3170, 2016. DOI: 10.1016/j.ijhydene.2015.12.040

Zin, V., Agresti, F., Barison, S., Colla, L., Gondolini, A. and. Fabrizio, M., The synthesis and effect of copper nanoparticles on the tribological properties of lubricant oils. IEEE Transactions on Nanotechnology [Online], 12(5), pp. 751-759, 2013. Available at: https://ieeexplore.ieee.org/document/6560433

Licencia

Derechos de autor 2018 DYNA

Creative Commons License

Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.

El autor o autores de un artículo aceptado para publicación en cualquiera de las revistas editadas por la facultad de Minas cederán la totalidad de los derechos patrimoniales a la Universidad Nacional de Colombia de manera gratuita, dentro de los cuáles se incluyen: el derecho a editar, publicar, reproducir y distribuir tanto en medios impresos como digitales, además de incluir en artículo en índices internacionales y/o bases de datos, de igual manera, se faculta a la editorial para utilizar las imágenes, tablas y/o cualquier material gráfico presentado en el artículo para el diseño de carátulas o posters de la misma revista.