Publicado

2018-10-01

Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering

Películas de WS2-Ti producidas por magnetrón co-sputtering variando la potencia del cátodo de titanio: comportamiento tribológico y resistencia a la corrosión

DOI:

https://doi.org/10.15446/dyna.v85n207.67980

Palabras clave:

solid lubricant, TMD, Raman, EIS, doping (en)
lubricante sólido, TMD, Raman, EIS, dopaje (es)

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Autores/as

Titanium-doped tungsten disulfide thin films (WS2-Ti) were deposited using a DC magnetron co-sputtering on AISI 304 stainless steel and silicon substrates. Different Ti cathode power densities between 0 and 1.25 W/cm2 were used for coating deposition. Energy-dispersive spectroscopy evidenced an increase in Ti percentage at the expense of W, as well as a sulfur deficiency. Raman spectroscopy was used to identify bands corresponding to W-S for undoped WS2. As the material was doped, changes in crystalline structure caused W-S main bands to separate. Scratch adhesion testing showed that Ti percentage increased along with the critical load (Lc). Furthermore, adhesive failure type changed from plastic to elastic. Finally, corrosion resistance analysis using electrochemical impedance spectroscopy (EIS) showed that, at high Ti concentrations, corrosion resistance was enhanced as Ti facilitates coating densification and generates a protective layer.
Películas delgadas de bisulfuro de tungsteno dopado con titanio fueron depositadas usando la técnica de magnetron co- sputtering DC sobre sustratos de acero inoxidable AISI 304 y Silicio. Para producir los recubrimientos, la densidad de potencia del cátodo de titanio fue variada entre 0 y 1.25 W/cm2. Los resultados de espectroscopia de energía dispersiva muestran un incremento en el porcentaje de Ti a expensas de W, además muestra una disminución en el porcentaje de azufre. Con las medidas de espectroscopía Raman se identificaron las bandas al enlace W-S para WS2 sin dopar. Cuando el material es dopado, los cambios en la estructura cristalina producen la separación de las principales bandas del enlace W-S. Usando la prueba de rayado dinámico, la adhesión de los recubrimientos fue estudiada, mostrando que la carga critica (Lc) incrementa con el porcentaje de Ti; además, la falla pasa de adhesiva a cohesiva con el incremento de Ti. Finalmente, la resistencia a la corrosión fue evaluada usando la técnica espectroscopia de impedancia electroquímica (EIS), y es observado que a altas cantidades de Ti, se mejora la resistencia a la corrosión debido a que el Ti facilita la densificación y genera una capa protectora.

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Cómo citar

IEEE

[1]
J. de la Roche-Yepes, J. M. Gonzalez Carmona, E. Restrepo-Parra, y H. Sanchez-Sthepa, «Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering», DYNA, vol. 85, n.º 207, pp. 221–226, oct. 2018.

ACM

[1]
de la Roche-Yepes, J., Gonzalez Carmona, J.M., Restrepo-Parra, E. y Sanchez-Sthepa, H. 2018. Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering. DYNA. 85, 207 (oct. 2018), 221–226. DOI:https://doi.org/10.15446/dyna.v85n207.67980.

ACS

(1)
de la Roche-Yepes, J.; Gonzalez Carmona, J. M.; Restrepo-Parra, E.; Sanchez-Sthepa, H. Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering. DYNA 2018, 85, 221-226.

APA

de la Roche-Yepes, J., Gonzalez Carmona, J. M., Restrepo-Parra, E. & Sanchez-Sthepa, H. (2018). Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering. DYNA, 85(207), 221–226. https://doi.org/10.15446/dyna.v85n207.67980

ABNT

DE LA ROCHE-YEPES, J.; GONZALEZ CARMONA, J. M.; RESTREPO-PARRA, E.; SANCHEZ-STHEPA, H. Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering. DYNA, [S. l.], v. 85, n. 207, p. 221–226, 2018. DOI: 10.15446/dyna.v85n207.67980. Disponível em: https://revistas.unal.edu.co/index.php/dyna/article/view/67980. Acesso em: 22 mar. 2026.

Chicago

de la Roche-Yepes, Jhonattan, Juan Manuel Gonzalez Carmona, Elizabeth Restrepo-Parra, y Hector Sanchez-Sthepa. 2018. «Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering». DYNA 85 (207):221-26. https://doi.org/10.15446/dyna.v85n207.67980.

Harvard

de la Roche-Yepes, J., Gonzalez Carmona, J. M., Restrepo-Parra, E. y Sanchez-Sthepa, H. (2018) «Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering», DYNA, 85(207), pp. 221–226. doi: 10.15446/dyna.v85n207.67980.

MLA

de la Roche-Yepes, J., J. M. Gonzalez Carmona, E. Restrepo-Parra, y H. Sanchez-Sthepa. «Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering». DYNA, vol. 85, n.º 207, octubre de 2018, pp. 221-6, doi:10.15446/dyna.v85n207.67980.

Turabian

de la Roche-Yepes, Jhonattan, Juan Manuel Gonzalez Carmona, Elizabeth Restrepo-Parra, y Hector Sanchez-Sthepa. «Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering». DYNA 85, no. 207 (octubre 1, 2018): 221–226. Accedido marzo 22, 2026. https://revistas.unal.edu.co/index.php/dyna/article/view/67980.

Vancouver

1.
de la Roche-Yepes J, Gonzalez Carmona JM, Restrepo-Parra E, Sanchez-Sthepa H. Corrosion resistance and tribological behavior of WS2-Ti coatings by Ti cathode power changes in magnetron co-sputtering. DYNA [Internet]. 1 de octubre de 2018 [citado 22 de marzo de 2026];85(207):221-6. Disponible en: https://revistas.unal.edu.co/index.php/dyna/article/view/67980

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CrossRef Cited-by

CrossRef citations5

1. Feng Ming Yap, Jian Yiing Loh, Wee-Jun Ong. (2024). Synergistic integration of self-supported 1T/2H−WS2 and nitrogen-doped rGO on carbon cloth for pH-universal electrocatalytic hydrogen evolution. Nano Research, 17(3), p.1267. https://doi.org/10.1007/s12274-023-6118-8.

2. Tuan Van Nguyen, Thang Phan Nguyen, Quyet Van Le, Dung Van Dao, Sang Hyun Ahn, Soo Young Kim. (2023). Facile route for synthesizing WS2/W2C nano hollow flowers and their application for hydrogen evolution reaction. Journal of Alloys and Compounds, 955, p.170231. https://doi.org/10.1016/j.jallcom.2023.170231.

3. Tuan Van Nguyen, Thang Phan Nguyen, Quyet Van Le, Dung Van Dao, Sang Hyun Ahn, Soo Young Kim. (2022). Facile Route for Synthesizing Ws2/W2c Nano Hollow Flowers and Their Application for Hydrogen Evolution Reaction. SSRN Electronic Journal , https://doi.org/10.2139/ssrn.4143264.

4. Tuan Van Nguyen, Ha Huu Do, Mahider Tekalgne, Quyet Van Le, Thang Phan Nguyen, Sung Hyun Hong, Jin Hyuk Cho, Dung Van Dao, Sang Hyun Ahn, Soo Young Kim. (2021). WS2–WC–WO3 nano-hollow spheres as an efficient and durable catalyst for hydrogen evolution reaction. Nano Convergence, 8(1) https://doi.org/10.1186/s40580-021-00278-3.

5. Haichao Cai, Yujun Xue, Jiangtao He, Fang Yang, Xiqiang Ma. (2020). Effect of target power on the structure and tribological Properties of La-Ti/WS2 composite films prepared by unbalanced magnetron sputtering. Materials Research Express, 7(3), p.036401. https://doi.org/10.1088/2053-1591/ab77f2.

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