Electrocoagulación de soluciones de índigo carmín empleando ánodos de magnesio y de aleación AZ31

Publicado

2018-07-01

Electrocoagulación de soluciones de índigo carmín empleando ánodos de magnesio y de aleación AZ31

Electrocoagulation of indigo carmine dye solution with magnesium and AZ31 alloy anodes

Palabras clave:

índigo carmín, electrocoagulación, remoción de color, remoción de COD, electrodo de magnesio, aleación AZ31 (es)
carmine indigo, electrocoagulation, colour removal, DOC removal, magnesium electrode, alloy AZ31 (en)

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Autores/as

Dayana Donneys-Victoria Universidad del Valle https://orcid.org/0000-0002-1943-6328
Cristian Camilo Ospina-Toro Universidad del Valle https://orcid.org/0000-0002-9792-6963
Mónica Vanesa Zapata-Villegas Universidad del Valle https://orcid.org/0000-0002-8793-7634
Nilson de Jesús Marriaga-Cabrales Universidad del Valle https://orcid.org/0000-0002-5046-9371
Fiderman Machuca-Martínez Universidad del Valle https://orcid.org/0000-0002-4553-3957
Juan M. Peralta-Hernández Universidad de Guanajuato https://orcid.org/0000-0003-2733-4126
Carlos A. Martínez-Huitle Universidade Federal Do Rio Grande do Norte https://orcid.org/0000-0002-6209-5426

Resumen (es)
Resumen (en)

El índigo carmín es uno de los componentes más contaminantes encontrados en los efluentes de la industria textil. Se exploró el desempeño del magnesio de alta pureza y la aleación AZ31 como ánodos de sacrificio en la electrocoagulación de soluciones de índigo carmín para la disminución de color y carbono orgánico disuelto (COD). Los experimentos se llevaron a cabo empleando un diseño factorial fraccionado a dos niveles con los siguientes factores: velocidad de agitación (cero y 840 rpm), temperatura (28 y 50 °C), concentración de colorante (100 y 300 mg/L) y densidad de corriente (20 y 50 A/m2). Como electrolito se utilizó NaCl y la magnitud de la carga eléctrica específica se mantuvo constante en 5,000 coulomb/litro (C/L). Se alcanzaron disminuciones cercanas al 99% en color y 84% en COD. Se evidenció que ambos materiales son competitivos en relación con la remoción de color y de COD alcanzadas.

Indigo carmine is one of the most polluting components found in the textile industry effluents. It was carried out an exploratory study about the performance of the high purity magnesium and the alloy AZ31 used as sacrifice electrodes for removing color and dissolved organic carbon (DOC) in indigo carmine solutions treated by the electrocoagulation process. Tests were developed through a two levels fractionate factorial design. Factors and levels were: stirring speed (zero or 840 rpm), temperature (28 or 50 °C), dye concentration (100 or 300 mg/L) and current density (20 or 50 A/m2). It was used a concentration NaCl as support electrolyte, and contrary to other studies all the runs were carried out at the same electric charge (5,000 C/L). Removals around 99% colour and 84% in DOC were obtained. Both materials were competitive for colour and DOC removal.

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Citas

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