Publicado

2018-07-01

Using a non-reducing sugar in the green synthesis of gold and silver nanoparticles by the chemical reduction method

Uso de una azúcar no reductora en la síntesis verde de nanopartículas de oro y plata por medio de reducción química

Palabras clave:

metal nanoparticles, sucrose, hydrolysis, reduction oxide reaction, salt of carboxylic acid (en)
nanopartículas metálicas, sacarosa, hidrólisis, óxido reducción, sales de ácido carboxílico (es)

Autores/as

The use of more biocompatible and renewable chemical compounds to obtain metal nanoparticles with desired properties and characteristics becomes an alternative route for the reduction of environmental risks and to minimize the incompatibility of these structures when interacting with biological models for their possible application in the health area. The purpose of this research was focused on the use of sucrose, as a reducing agent for gold and silver nanoparticles using different volumes of sodium hydroxide. The nanoparticles obtained were characterized by UV-visible spectrometry, transmission electron microscopy TEM and Fourier transform infrared spectroscopy FTIR, which allowed to determine the surface plasmon resonance, experimental and theoretical particle sizes, morphology and structural changes in the reducing agent, as well as the influence of sodium hydroxide in the synthesis process. The results obtained confirm the generation of gold and silver nanoparticles by the previous formation of reducing sugars and oxidation of the functional group from glucose to salts of carboxylic acid.
El uso de compuestos químicos más biocompatibles y renovables para la obtención de nanopartículas metálicas con propiedades y características deseadas, se convierte en una ruta alternativa para la reducción de riesgos ambientales y del grado de incompatibilidad de estas estructuras al interactuar con modelos biológicos para su posible aplicación en el área de la salud. El propósito de este trabajo se centró en el uso de sacarosa, como agente reductor de nanopartículas de oro y plata al emplear diferentes volúmenes de hidróxido de sodio. Las nanopartículas obtenidas fueron caracterizadas mediante espectrometría UV-visible, microscopía electrónica de transmisión TEM y espectroscopia infrarroja por transformada de Fourier FTIR, la cual permitió determinar los plasmones de resonancia superficial, tamaños de partícula experimentales y teóricos, morfología y cambios estructurales en el agente reductor, así como la influencia del hidróxido de sodio en el proceso de síntesis. Los resultados obtenidos confirman la formación de nanopartículas de oro y plata mediante la previa formación de azúcares reductores. Así mismo, la oxidación del grupo funcional de la glucosa a sales de ácido carboxílico.

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