Correo Electrónico
DNINFOA - SIA
Bibliotecas
Convocatorias
Identidad U.N.
Publicado
Characteristics of NiO present in solids obtained from hydrotalcites based on Ni/Al and Ni-Zn/Al
Características del NiO presente en solidos obtenidos de hidrotalcitas del tipo Ni/Al y Ni-Zn/Al
DOI:
https://doi.org/10.15446/dyna.v86n210.78559Palabras clave:
hidrotalcite, NiO, lattice parameters, spectroscopy Raman (en)hidrotalcitas, NiO, parámetros de red, espectroscopia Raman (es)
Descargas
NiO has a variety of applications, mainly in the production of electrochemical sensors and of metallic nickel. In addition, it is widely used as catalysts to produce hydrogen from natural gas. In this work, hydrotalcites based on nickel-aluminum and nickel-zinc-aluminum were synthesized, calcined at 500 °C and studied by different techniques. It was observed that nickel-aluminum hydrotalcites are thermally more stable, collapsing at higher temperatures than hydrotalcites containing zinc. During calcination, aluminum is incorporated into NiO lattice, leading to a decrease in crystallographic parameters. However, zinc decreases this effect, favoring the formation of NiO with lattice parameters close to pure nickel oxide. Zinc also contributes to the formation of smaller NiO particles, which is very useful for its use as a catalyst. In addition, aluminum led to a distortion in NiO lattice, an effect that is minimized by zinc, showing that it hinders the incorporation of Al3+ in the NiO lattice.
El NiO es útil en la producción de sensores electroquímicos y para la obtención de níquel metálico, el cual es usado como catalizador para producir hidrogeno a partir de gas natural. En este trabajo, se sintetizaron hidrotalcitas a base de níquel-aluminio y níquel-zinc-aluminio, las cuales fueron calcinadas a 500 oC y estudiadas por diferentes técnicas instrumentales. Se observó que las hidrotalcitas a base de níquel y aluminio son más estables térmicamente, colapsando a temperaturas más altas que aquellas conteniendo zinc. Durante el proceso de calcinación el aluminio se incorpora en la red cristalina del NiO, disminuyendo los parámetros cristalográficos de este óxido. La adición de zinc disminuye este efecto, contribuyendo además con la formación de partículas más pequeñas del NiO. Adicionalmente el aluminio distorsiona la red del NiO, efecto que es minimizado por el zinc, dificultando la incorporación de Al3+ en la red cubica del NiO.
Referencias
Meza-Fuentes, E., Cadete-Santos, F., Prakash, S., da Costa-Faro, A., de Freitas-Silva, T., Mansur-Assaf, J. and Rangel, M., The effect of metal content on nickel-based catalysts obtained from hydrotalcites for WGSR in one step. International Journal of Hydrogen Energy, 39, pp. 815-828, 2014. DOI: 10.1016/j.ijhydene.2013.10.114
Meza, E., Faro, A., de Freitas, T., Assaf, J. and Rangel, M., A comparison between copper and nickel-based catalysts obtained from hydrotalcite-like precursors for WGSR. Catalysis Today, 171, pp. 290-296, 2011. DOI: 10.1016/j.cattod.2011.03.082
Yuvakkumar, R., Suresh, J., Nathanael, A., Sundrarajan, M. and Hong, S., Rambutan (Nephelium lappaceum L.) peel extract assisted biomimetic synthesis of nickel oxide nanocrystals. Materials Letter, 128, pp. 170-174, 2014. DOI: 10.1016/j.matlet.2014.04.112
Yu, Y., Xia, Y., Zeng, W. and Liu, R., Synthesis of multiple networked NiO nanostructures for enhanced gas sensing performance. Materials Letter, 206, pp. 80-83, 2017. DOI: 10.1016/j.matlet.2017.06.119
Xia, Q., Zhao, H., Teng, Y., Du, Z., Wang, J. and Zhang, T., Synthesis of NiO/Ni nanocomposite anode material for high rate lithium-ion batteries. Materials Letter, 142, pp. 67-70, 2015. DOI: 10.1016/j.matlet.2014.11.142
Kaura, N., Zappa, D., Ferroni, M., Poli, N., Campanini, M., Negrea, R. and Comini, E., Branch-like NiO/ZnO heterostructures for VOC sensing. Sensors and Actuators B: Chemical, 262, pp. 477-485, 2018. DOI: 10.1016/j.snb.2018.02.042
Zhao, S., Yi, H., Tang, X., Kang, D., Gao, F., Wang, J., Huang, Y. and Yang, Z., Calcined ZnNiAl hydrotalcite-like compounds as bifunctional catalysts for carbonyl sulfide removal. Catalysis Today, Article in Press. DOI: 10.1016/j.cattod.2018.05.011
Zhang, S., Pang, Y., Wang, Y., Dong, B., Lu, S., Li, M. and Ding, S., NiO nanosheets anchored on honeycomb porous carbon derived from wheat husk for symmetric supercapacitor with high performance. Journal of Alloys and Compounds, 735, pp. 1722-1729, 2018. DOI: 10.1016/j.jallcom.2017.11.294
Lang, F., Sun, D., Liu, J., Wang, H. and Yan, H., Improved size-tunable synthesis of monodisperse NiO nanoparticles. Materials Letter, 181, pp. 328-330, 2016. DOI: 10.1016/j.matlet.2016.06.056
Kalam, A., Al-Shihri, A., Al-Sehemi, A., Awwad, N., Du, G. and Ahmad, T., Effect of pH on solvothermal synthesis of β-Ni(OH)2 and NiO nano-architectures: surface area studies, optical properties and adsorption studies. Superlattices and Microstructures, 55, pp. 83-97, 2013. DOI: 10.1016/j.spmi.2012.11.024
Tian, K., Wang, X., Li, H., Nadimicherla, R. and Guo, X., Lotus pollen derived 3-dimensional hierarchically porous NiO microspheres for NO2 gas sensing. Sensors and Actuators B: Chemical, 277, pp. 554-560, 2016. DOI: 10.1016/j.snb.2015.12.104
Oliveira, E., Grande, C. and Rodrigues, A., Steam methane reforming in a Ni/Al2O3 catalyst: kinetics and diffusional limitations in extrudates. The Canadian Journal Chemical Engineering, 87, pp. 945-956, 2009 DOI: 10.1002/cjce.20223
Osaki, T. and Mori, T., Role of Potassium in Carbon-free CO2 reforming of methane on K-promoted Ni/Al2O3 catalysts. Journal of Catalysis, 204, pp. 89-97, 2001. DOI: 10.1006/jcat.2001.3382
Jiang, Z., Liao, X. and Zhao, Y., Comparative study of the dry reforming of methane on fluidised aerogel and xerogel Ni/Al2O3 catalysts. Applied Petrochemical Research, 3, pp. 91-99, 2012. DOI: 10.1007/s13203-013-0035-9
Touahra, F., Sehailia, M., Ketir, W., Bachari, K., Chebout, R., Trari, M., Cherifi, O. and Halliche, D., Effect of the Ni/Al ratio of hydrotalcite-type catalysts on their performance in the methane dry reforming process. Applied Petrochemical Research, 6, pp. 1-13, 2016. DOI: 10.1007/s13203-015-0109-y
Meza, E. y Rangel M., Síntesis de catalizadores de Ni/ZnO/Al2O3 para la reacción WGS a través del estudio de las propiedades estructurales y catalíticas de Ni/ZnO y Ni/Al2O3. Revista Colombiana de Química, 40, pp. 105-123, 2011. DOI: 10.15446/rev.colomb.quim
Cavani, F., Trifiro, F. and Vaccari, A., Hydrotalcite-type ânionic clays: preparation, properties and application. Catalysis Today, 11, pp. 173-301, 1991. DOI: 10.1016/0920-5861(91)80068-K
Crepaldi, E.L. and Barros, J., Hidróxidos duplos lamelares: síntese, estrutura, propriedades e aplicações. Química Nova, 21, pp. 300-311, 1998. DOI: 10.1590/S0100-40421998000300011
Rodriguez-Ruiz, J., Pajaro-Payares, A., Meza-Fuentes, E., Síntesis y caracterización estructural de hidrotalcitas de Cu-Zn-Al. Revista Colombiana de Química, 45, pp. 33-38, 2016. DOI: 10.15446/rev.colomb.quim.v45n3.61381
Bhojaraj, N., Harley, P. and Rajamathi M., Cannizzaro reactions over calcined hydrotalcite. Applied Clay Science, 147, pp. 86-89, 2019. DOI: 10.1016/j.clay.2019.03.028
He, J., Wei, M., Li, B., Kang, Y., Evans, D. and Duan, X., Preparation of layered double hydroxides. Structure and Bonding, 119, pp. 89-119. 2006. DOI: 10.1007/430_006
Borges, R., Ferreira, R., Rabelo-Neto, R., Noronha, F. and Hori, C., Hydrogen production by steam reforming of acetic acid using hydrotalcite type precursors. International Journal of Hydrogen Energy, 43, pp. 7881-7892, 2018. DOI: 10.1016/j.ijhydene.2018.03.028
Meza. E., Solano. C., Pájaro, A., Rodriguez, J. and Rangel, M., Estudo do efeito da composição na temperatura do colapso da estrutura de Hidrotalcitas de Ní-Zn-Al. In: Memorias XXIV Congreso Iberoamericano de Catálisis, Medellín, Colombia, 2014.
Massalski, T. and Mizutani, U., Electronic structure of Hume-Rothery phases. Progress in Materials Science, 22, pp. 151-262, 1978. DOI: 10.1016/0079-6425(78)90001-4
Wang, W., Liu, Y., Xua, C., Zheng, C. and Wang, G., Synthesis of NiO nanorods by a novel simple precursor thermal decomposition approach. Chemical Physics Letters, 362, pp. 119-122, 2002. DOI: 10.1016/S0009-2614(02)00996-X
Ni, X., Zhao, Q., Zhou, F., Zheng, H., Cheng, J. and Li, B., Synthesis and characterization of NiO strips from a single source. Journal of Crystal Growth, 289, pp. 299-302, 2006. DOI: 10.1016/j.jcrysgro.2005.10.017
Mironova-Ulmanea, N., Kuzmina, A. and Grube, M., Raman and infrared spectromicroscopy of manganese oxides. Journal of Alloys and Compounds, 480, pp. 97-99, 2009. DOI: 10.1016/j.jallcom.2008.10.056
Thamri, S., Sta, I., Jlassi, M., Hajji, M. and Ezzaouia, H., Fabrication of ZnO-NiO nanocomposite thin films and experimental study of the effect of the NiO, ZnO concentration on its physical properties. Materials Science in Semiconductor Processing, 71, pp. 310-320, 2017. DOI: 10.1016/j.mssp.2017.08.017
Švegl, F., Šurca-Vuk, A., Hajzeri, M., Slemenik-Perše, L. and Orel, B., Electrochromic properties of Ni(1−x)O and composite Ni(1−x)O- polyaniline thin films prepared by the peroxo soft chemistry route. Solar Energy Materials and Solar Cells, 99, pp. 14-25, 2012. DOI: 10.1016/j.solmat.2011.11.043 [30] Jang, M., Yoon, M., Lee, S., Kim, H., Onodera. A. and Kojima, S., A study on the Raman spectra of Al-doped and Ga-doped ZnO ceramics. Current Applied Physics, 9, pp. 651-657, 2009. DOI: 10.1016/j.cap.2008.05.019
Tangcharoen, T., Klysubun, W. and Kongmark, C., Synthesis of nanocrystalline NiO/ZnO heterostructured composite powders by sol-gel auto combustion method and their characterizations. Journal of Molecular Structure, 1156, pp. 524-533, 2018. DOI: 10.1016/j.molstruc.2017.12.019
Cómo citar
IEEE
ACM
ACS
APA
ABNT
Chicago
Harvard
MLA
Turabian
Vancouver
Descargar cita
CrossRef Cited-by
1. Ahmed T. Al-Qathmi, Gazali Tanimu, Hassan S. Alasiri, Ziyauddin S. Qureshi, Mohammad M. Hossain, Zuhair O. Malaibari. (2023). Influence of Zn and Fe promoters on Ni-Bi/γ-Al2O3 catalyst for oxidative dehydrogenation of n-butane to butadiene. Molecular Catalysis, 540, p.113067. https://doi.org/10.1016/j.mcat.2023.113067.
2. Zahra Nazari, Vahid Mahdavi, Kaveh Khosravi. (2024). Preparation of M–Al and M–Ca–Al (M: Sr, Cd, Ni, Ca, and Co) mixed oxides derived from LDH precursors as the high performance heterogeneous base catalysts for efficient synthesis of chalcones. Journal of the Iranian Chemical Society, 21(4), p.1113. https://doi.org/10.1007/s13738-024-02983-2.
3. Edgardo Meza-Fuentes, Johana Rodríguez Ruíz, Edinson Castellar Arroyo, Maria Rangel, Eduardo Espinosa Fuentes. (2023). Study of NiO/Al2O3 and NiO/Zn-Al2O3 catalysts for water gas shift reaction. Universitas Scientiarum, 28(3), p.316. https://doi.org/10.11144/Javeriana.SC283.sona.
4. Roba Saab, Kyriaki Polychronopoulou, Dalaver H. Anjum, Nikolaos D. Charisiou, Maria A. Goula, Steven J. Hinder, Mark A. Baker, Andreas Schiffer. (2022). Effect of SiO2/Al2O3 ratio in Ni/Zeolite-Y and Ni-W/Zeolite-Y catalysts on hydrocracking of heptane. Molecular Catalysis, 528, p.112484. https://doi.org/10.1016/j.mcat.2022.112484.
5. Zuhair Omar Malaibari, Ahmed T. Al-Qathmi, Gazali Tanimu, Hassan S. Alasiri, Ziyauddin S. Qureshi, Mohammad M. Hossain. (2022). Influence of Zn and Fe Promoters on Ni-Bi/Γ-Al2o3 Catalyst for Oxidative Dehydrogenation of N-Butane to Butadiene. SSRN Electronic Journal , https://doi.org/10.2139/ssrn.4142105.
6. E. Meza-Fuentes, J. Rodriguez-Ruiz, C. Solano-Polo, M.C. Rangel, A. Faro. (2020). Monitoring the structural and textural changes of Ni-Zn-Al hydrotalcites under heating. Thermochimica Acta, 687, p.178594. https://doi.org/10.1016/j.tca.2020.178594.
Dimensions
PlumX
Visitas a la página del resumen del artículo
Descargas
Licencia
Derechos de autor 2019 DYNA
Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.
El autor o autores de un artículo aceptado para publicación en cualquiera de las revistas editadas por la facultad de Minas cederán la totalidad de los derechos patrimoniales a la Universidad Nacional de Colombia de manera gratuita, dentro de los cuáles se incluyen: el derecho a editar, publicar, reproducir y distribuir tanto en medios impresos como digitales, además de incluir en artículo en índices internacionales y/o bases de datos, de igual manera, se faculta a la editorial para utilizar las imágenes, tablas y/o cualquier material gráfico presentado en el artículo para el diseño de carátulas o posters de la misma revista.
