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Cement production with pozzolans from residual tropical soils formed from paragneiss with a high silicon oxide content
Producción de cemento con puzolanas de suelos tropicales residuales de paragneis con alto contenido de óxido de silicio
DOI:
https://doi.org/10.15446/dyna.v87n213.83208Palabras clave:
supplementary cementing material, calcined clays, low kaolinite clay, Pozzolans, residual soils in cement manufacturing (en)material cementante suplementario, arcillas calcinadas, arcilla de bajo contenido de caolinita, Puzolanas, suelos residuales en la fabricación de cemento (es)
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The manufacture of cement demands a lot of energy and gives off large amounts of CO2. Calcined clays need less energy and emit water instead of CO2, which has drawn attention to them, especially those rich in kaolinite. However, their use has been discouraged due to their location and high market price. Hence, the present study focuses on calcined clays with a low kaolinite content, specifically those derived
from paragneiss. In Colombia they are located in weathering horizons with depths of up to 40 meters. The results showed contents of 20%
Al2O3, less than 14% Fe2O3, more than 60% SiO2, less than 40% kaolinite, 20% illite and more than 30% quartz. Calcined at 750 °C, they were used in mortars, obtaining SAI values of between 80 and 100% after 28 days, which, added to the results of Frattini tests, show that their use as a supplementary cementing material is feasible.
La manufactura del cemento demanda mucha energía y aporta cantidades importantes de CO2. Las arcillas calcinadas, demandan menos energía y emiten en vez de CO2, agua a la atmósfera, convirtiéndolas en objeto de atención, fundamentalmente aquellas ricas en caolinita.
No obstante, están siendo desincentivadas, por su ubicación y alto precio en el mercado. El presente estudio se enfocó hacia las arcillas de bajo contenido de caolinita, como las derivadas de paragneiss, encontrándose en Colombia, horizontes de meteorización con profundidades
hasta 40 metros. Los resultados arrojaron contenidos de Al2O3 del 20%, Fe2O3 menores al 14%, SiO2 mayores al 60%, contenidos de
caolinita menores de 40%, illita 20% y cuarzo mayores al 30%. Siendo calcinadas a 750 °C, se emplearon en morteros, obteniendo valores de IAR a 28 días entre el 80 y 100%, que sumados a los resultados de ensayos Frattini, muestran que su uso como material cementante
suplementario es factible.
Referencias
Aprianti, S,E., A huge number of artificial waste material can be supplementary cementitious material (SCM) for concrete production - a review part II, J. Clean. Prod., 142(4), pp. 4178-4194, 2017. DOI: 10.1016/j.jclepro.2015.12.115
Sabir, B.B., Wild, S. and Bai, J., Metakaolin and calcined clays as pozzolans for concrete: a review, Cem. Concr. Compos., 23(6), pp. 441-454, 2001. DOI: 10.1016/S0958-9465(00)00092-5
Tironi, A., Trezza, M.A., Scian, A.N. and Irassar, E.F., Assessment of pozzolanic activity of different calcined clays, Cem. Concr. Compos., 37(1), pp. 319-327, 2013. DOI: 10.1016/j.cemconcomp.2013.01.002
Jaber, M., Komarneni, S. and Zhou, C.H., Synthesis of clay minerals, Dev. Clay Sci., 5(1), pp. 223-241, 2013. DOI: 10.1016/B978-0-08-098258-8.00009-2
Alujas, A., Fernández, R., Quintana, R., Scrivener, K.L. and Martirena, F., Pozzolanic reactivity of low grade kaolinitic clays: influence of calcination temperature and impact of calcination products on OPC hydration, Appl. Clay Sci., 108(May), pp. 94-101, 2015. DOI: 10.1016/j.clay.2015.01.028
Tironi, A., Trezza, M.A., Scian, A.N. and Irassar, E.F., Kaolinitic calcined clays: Factors affecting its performance as pozzolans, Constr. Build. Mater., 28(1), pp. 276-281, 2012. DOI: 10.1016/j.conbuildmat.2011.08.064
UNE-EN 196-5: Métodos de ensayo de cementos Parte 5: ensayo de puzolanicidad para los cementos puzolánicos, AENOR, [online]. 2011. Available at: https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma/?c=N0047870
Rashwan, M.A., Saeed, E., Lasheen, R. and Shalaby, B.N., Incorporation of metagabbro as cement replacement in cement-based materials: a role of mafic minerals on the physico-mechanical and durability properties, Construction and Building Materials, 210(June), pp. 256-268, 2019. DOI: 10.1016/j.conbuildmat.2019.03.191
Avet, F., Li, X. and Scrivener, K., Determination of the amount of reacted metakaolin in calcined clay blends, Cem. Concr. Res., 106(April), pp. 40-48, 2018. DOI: 10.1016/j.cemconres.2018.01.009
Antoni, M., Rossen, J., Martirena, F. and Scrivener, K., Cement substitution by a combination of metakaolin and limestone, Cem. Concr. Res., 42(12), pp. 1579-1589, 2012. DOI: 10.1016/j.cemconres.2012.09.006
Scrivener, K., Martirena, F., Bishnoi, S. and Maity, S., Calcined clay limestone cements (LC3), Cem. Concr. Res., 114(August), pp. 49-56, 2018. DOI: 10.1016/j.cemconres.2017.08.017
Fernandez, R., Martirena, F. and Scrivener, K.L., The origin of the pozzolanic activity of calcined clay minerals: a comparison between kaolinite, illite and montmorillonite, Cem. Concr. Res., 41(1), pp. 113-122, 2011. DOI: 10.1016/j.cemconres.2010.09.013
Castillo, R., Fernández, R., Antoni, M., Scrivener, K., Alujas, A. and Martirena, J.F., Activación de arcillas de bajo grado a altas temperaturas, Rev. Ing. Construcción, 25(3), pp. 329-352, 2010. DOI: 10.4067/S0718-50732010000300001
Dietel, J., Warr, L.N., Bertmer, M., Steudel, A., Grathoff, G.H. and Emmerich, K., The importance of specific surface area in the geopolymerization of heated illitic clay, Appl. Clay Sci., 139(April), pp. 99-107, 2017. DOI: 10.1016/j.clay.2017.01.001
Hollanders, S., Adriaens, R., Skibsted, J., Cizer, Ö. and Elsen, J., Pozzolanic reactivity of pure calcined clays, Appl. Clay Sci., 132-133(November), pp. 552-560, 2016. DOI: 10.1016/j.clay.2016.08.003
Yanguatin, H., Ramírez, J.H., Tironi, A. and Tobón, J.I., Effect of thermal treatment on pozzolanic activity of excavated waste clays, Constr. Build. Mater., 211(June), pp. 814-823, 2019. DOI: 10.1016/j.conbuildmat.2019.03.300
Uchima, J S., Restrepo, O.J. and Tobón, J.I., Pozzolanicity of the material obtained in the simultaneous calcination of biomass and kaolinitic clay, Constr. Build. Mater., 95(October), pp. 414-420, 2015. DOI: 10.1016/j.conbuildmat.2015.07.104
Msinjili, N.S., Gluth, G.J.G., Sturm, P., Vogler, N. and Kühne, H.-C., Comparison of calcined illitic clays (brick clays) and low-grade kaolinitic clays as supplementary cementitious materials, Mater. Struct., 52(5), 2019. DOI: 10.1617/s11527-019-1393-2
Roch, G.E., Smiths, M.E. and Drachman, S.R., Solid state characterization of the thermal transformation of an illite-rich clay, Clays Clay Miner., 46(6), pp. 694-704, 1998. DOI: 10.1346/CCMN.1998.0460610
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2. Oscar O. Vásquez‐Torres, Francisco D. Cabrera‐Poloche. (2022). Property modifications of low‐grade clay through physical treatments and its incidence in the pozzolanic activity. International Journal of Applied Ceramic Technology, 19(3), p.1462. https://doi.org/10.1111/ijac.13960.
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