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Synthesis and evaluation of nickel doped Co3O4 produced through hydrothermal technique
Síntesis y evaluación de Co3O4 dopado con níquel producido mediante la técnica hidrotermal
DOI:
https://doi.org/10.15446/dyna.v87n213.84410Palabras clave:
cobalt oxide, doping, nanostructures, structural parameters (en)óxido de cobalto, dopaje, nanoestructuras, parámetros estructurales (es)
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The synthesis of undoped cobalt oxide and cobalt oxide with 4%nickel doping is studied in samples obtained through hydrothermal technique. After the final heat treatment at 300°C, X-ray diffraction analysis indicated the formation of cobalt spinel oxide with a complete replacement of nickel in the lattice. An average crystallite size of ~42 nm and ~31nm was found, as well as a particle size of ~ 20 nm and ~30 nm for Co3O4 and Co3-xNixO4, respectively. Structural parameters were established through Rietveld refinement with a good correspondence between the simulated and the experimental pattern with values of x2 = 1.25 and GOF = 0.90 for Co3O4. The energy band gap was found through UV-Vis spectroscopy in two different regions: Eg1 and Eg2 values vary between 1.54 and 2.04eV for samples doped with nickel. The SEM results indicated the formation of nanostructures with semi-cubic shape and irregular rods. Parameters such as crystal size, particle size, surface area, as well as morphology of the final product depend on doping.
La síntesis de óxido de cobalto con dopaje de níquel al 4% se estudia en muestras obtenidas mediante técnica hidrotermal. Después del tratamiento térmico final a 300°C, el análisis de difracción de rayos X indicó la formación de óxido de cobalto espinela con una substitución completa de níquel en la red. Se encontró un tamaño promedio de cristalito de ~42 nm ~31 nm, así como un tamaño de partícula de ~20 nm y ~30 nm para Co3O4 y Co3-xNixO4, respectivamente. Los parámetros estructurales se establecieron mediante refinamiento Rietveld con una buena correspondencia entre el patrón simulado y el experimental con valores de X2 = 1.25 y GOF = 0.90 para Co3O4. La brecha de banda de energía se encontró a través de espectroscopía UV-Vis en dos regiones diferentes, los valores Eg1 y Eg2 varían entre 1.54 y 2.04eV para muestras dopadas con níquel. Los resultados SEM indicaron la formación de nanoestructuras con forma semicúbica y bastones irregulares. Parámetros tales como el tamaño del cristal, el tamaño de partícula, el área de superficie, así como la morfología del producto final dependen del dopaje.
Referencias
Mehmood, S,. Synthesis and characterizations of Co3O4 based nanocomposite for electrochemical sensor applications. PhD Thesis, Faculty of Science, Malasya University, Malasya, 2018.
Ding, L., Zhao, M., Fan, S., Ma, Y., Liang, J., Wang, X. and Chen, S., Preparing Co3O4 urchin-like hollow microspheres self-supporting architecture for improved glucose biosensing performance. Sensors and Actuators, B: Chemical, 235, pp. 162-169, 2016. DOI: 10.1016/j.snb.2016.05.068.
Hoa, L.T., Chung, J.S. and Hur, S.H., A highly sensitive enzyme-free glucose sensor based on Co3O4 nanoflowers and 3D graphene oxide hydrogel fabricated via hydrothermal synthesis. Sensors and Actuators, B: Chemical, 223, pp. 76-82, 2016. DOI: 10.1016/j.snb.2015.09.009.
Dalkiran, B., Kaçar, C., Erden, P.E., and Kiliç, E., Amperometric xanthine biosensors based on chitosan- Co3O4- multiwall carbon nanotube modified glassy carbon electrode. Sensors and Actuators, B: Chemical, 2014, pp. 83-91, 2014. DOI: 10.1016/j.snb.2014.04.025.
Qing, X., Liu, S., Huang, K., Lv, K., Yang, Y., Lu, Z. and Liang, X., Facile synthesis of Co3O4 nanoflowers grown on Ni foam with superior electrochemical performance. Electrochimica Acta, 56(14), pp. 4985-4991, 2011. DOI: 10.1016/j.electacta.2011.03.118.
Berenguer, R., Valdés-Solís, T., Fuertes, A.B., Quijada, C. and Morallón, E., Cyanide and phenol oxidation on nanostructured Co3O4 electrodes prepared by different methods. Journal of the Electrochemical Society, 155(7), pp. 110-115, 2008. DOI: 10.1149/1.2917210.
Xiao, Y., Hu, C. and Cao, M., High lithium storage capacity and rate capability achieved by mesoporous Co3O4 hierarchical nanobundles. Journal of Power Sources, 247, pp. 49-56, 2014. DOI: 10.1016/j.jpowsour.2013.08.069.
Liang, Y., Li, Y. and Wang, H., Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nature Mater, 10, pp. 780-786, 201. DOI:10.1038/nmat3087.
Wang, P., Gu, Y., Miao, L., Zhou, J., Su, H., Wei, A. and Cai, H., Co3O4 nanoforest/Ni foam as the interface heating sheet for the efficient solar-driven water evaporation under one sun. Sustainable Materials and Technologies, 20, pp 1-7, 2019. DOI: 10.1016/j.susmat. 2019.e00106.
Lakehal, A., Bedhiaf, B., Bouaza, A., Hadj, B., Ammari, A. and Dalache, C., Structural, optical and electrical properties of Ni-doped Co3O4 prepared via Sol-Gel technique. Materials Research, 21(3), pp. 1-7, 2018. DOI: 10.1590/1980-5373-mr-2017-0545.
Mo, S., He, H., Ren, Q., Li, S., Zhang, W., Fu, M. and Ye, D., Macroporous Ni foam-supported Co3O4 nanobrush and nanomace hybrid arrays for high-efficiency CO oxidation. Journal of Environmental Sciences, 75, pp. 136-144, 2019. DOI: 10.1016/j.jes.2018.02.026.
Li, S., Wu, K., Li, L., Suo, L. and Zhu, Y., An architecture of dandelion-type Ni- Co3O4 microspheres on carbon nanotube films toward an efficient catalyst for oxygen reduction in zinc-air batteries. Applied Surface Science, 481, pp. 40-51, 2019. DOI: 10.1016/j.apsusc.2019.03.053.
Ouyang, K., Guo, G., Liu, Y., Sun, L. and Wei, M., Facile synthesis of heterogeneous Co3O4- nanowires/vertical-graphene-nanosheets on Ni foam for high performance supercapacitors. Materials Letters, 251, pp. 176-179, 2019. DOI: 10.1016/j.matlet.2019.05.062.
Ren, Z., Wu, Z., Song, W., Xiao, W., Guo, Y., Ding, J. and Gao, P.X., Low temperature propane oxidation over Co3O4 based nano-array catalysts: Ni dopant effect, reaction mechanism and structural stability. Applied Catalysis B: Environmental, 180, pp. 150-160, 2016. DOI: 10.1016/j.apcatb.2015.04.021.
Jin, L., Li, X., Ming, H., Wang, H., Jia, Z., Fu, Y. and Zheng, J., Hydrothermal synthesis of Co3O4 with different morphologies towards efficient Li-ion storage. RSC Advances, 4(12), pp. 6083-6089, 2014.
Bahlawane, N., Herve, P., Ngamou, T. and Kohse-höinghaus, K., Functional complex oxides: interplay between the structure, electrical properties and surface reactivity. Society, 516(c), pp. 3282-3282, 2009. DOI: 10.1039/C3RA45904G.
McClure, D.S., The distribution of transition metal cations in spinels. Journal of Physics and Chemistry of Solids, 3(3-4), pp. 311-317, 1957. DOI:10.1016/0022-3697(57)90034-3.
Koneru, A., Non-equilibrium Green’ s Function based calculations of spin voltage in cobalt based spinel oxides. PhD. Thesis, Departament of Mechanical and Aerospace Engineering. West Virginia University, Virginia, United States, 2017.
Pan, A., Wang, Y., Xu, W., Nie, Z., Liang, S., Nie, Z. and Zhang, J.G., High-performance anode based on porous Co3O4 nanodiscs. Journal of Power Sources, 255, pp. 125-129, 2014. DOI: 10.1016/j.jpowsour.2013.12.131.
Cao, J., Wang, S., Zhang, H. and Zhang, T., Constructing one dimensional Co3O4 hierarchical nanofibers as efficient sensing materials for rapid acetone gas detection. Journal of Alloys and Compounds, 799, pp. 513-520, 2019. DOI: 10.1016/j.jallcom.2019.05.356.
Liang, M., Zhao, M., Wang, H., Wang, F. and Song, X., Excellent cycling stabilities of a novel calliandra-like Co3O4 acted as anode materials for the lithium-ion battery. Journal of Energy Storage, 17, pp. 311-317, 2018. DOI: 10.1016/j.est.2018.03.017.
Singhal, A., Bisht, A. and Irusta, S., Enhanced oxygen evolution activity of Co3−xNixO4 compared to Co3O4 by low Ni doping. Journal of Electroanalytical Chemistry, 823, pp. 482-491, 2018. DOI: 10.1016/j.jelechem.2018.06.051.
Xiao, X., Liu, X., Zhao, H., Chen, D., Liu, F., Xiang, J. and Li, Y., Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Advanced materials, 24(42), pp. 5762-5766, 2012. DOI: 10.1002/adma.201202271.
Deng, S., Liu, X., Chen, N., Deng, D., Xiao, X. and Wang, Y., A highly sensitive VOC gas sensor using p-type mesoporous Co3O4 nanosheets prepared by a facile chemical coprecipitation method. Sensors and Actuators B: Chemical, 233, pp. 615-623, 2016. DOI: 10.1016/j.snb.2016.04.138.
Mulinari, T.A., La Porta, F.A., Andrés, J., Cilense, M., Varela, J.A. and Longo, E., Microwave-hydrothermal synthesis of single-crystalline Co 3 O 4 spinel nanocubes. CrystEngComm, 15(37), pp. 7443-7449, 2013. DOI: 10.1039/C3CE41215F.
Li, L., Chu, Y., Liu, Y., Song, J., Wang, D. and Du, X., A facile hydrothermal route to synthesize novel Co3O4 nanoplates. Materials Letters, 62(10-11), pp. 1507-1510, 2008. DOI: 10.1016/j.matlet.2007.09.012.
Rajeshkhanna, G. and Ranga Rao, G., Micro and nano-architectures of Co3O4 on Ni foam for electro-oxidation of methanol. International Journal of Hydrogen Energy, 43(9), pp. 4706-4715, 2018. DOI: 10.1016/j.ijhydene.2017.10.110.
Rajeshkhanna, G., Umeshbabu, E. and Ranga Rao, G., Charge storage, electrocatalytic and sensing activities of nest-like nanostructured Co3O4. Journal of Colloid and Interface Science, 487, pp. 20-30, 2017. DOI: 10.1016/j.jcis.2016.10.011.
Umeshbabu, E., Rajeshkhanna, G., Justin, P. and Rao, G.R., Magnetic, optical and electrocatalytic properties of urchin and sheaf-like NiCo2O4 nanostructures. Materials Chemistry and Physics, 165, pp. 235-244, 2015. DOI: 10.1016/j.matchemphys.2015.09.023.
Meher, S.K. and Rao, G.R., Effect of microwave on the nanowire morphology, optical, magnetic, and pseudocapacitance behavior of Co3O4. Journal of Physical Chemistry C, 115(51), pp. 25543-25556, 2011. DOI:10.1021/jp209165v.
Singhal, A., Bisht, A., Kumar, A. and Sharma, S., One pot, rapid synthesis of Co3O4 by solution combustion method and its electrochemical properties in different electrolytes. Journal of Electroanalytical Chemistry, 776, pp. 152-161, 2016. DOI: 10.1016/j.jelechem.2016.07.004.
Itteboina, R. and Sau, T.K., Sol-gel synthesis and characterizations of morphology-controlled Co3O4 particles. In: Materials Today: Proceedings, 9, 458-467, 2019. DOI: 10.1016/j.matpr.2019.02.176.
Hu, Z., Oskam, G., Penn, R.L., Pesika, N. and Searson, P.C., The influence of anion on the coarsening kinetics of ZnO nanoparticles. Journal of Physical Chemistry B, 107(14), pp. 3124-3130, 2003. DOI:10.1021/jp020580h.
Lu, B., Cao, D., Wang, P., Wang, G. and Gao, Y., Oxygen evolution reaction on Ni-substituted Co3O4 nanowire array electrodes. International Journal of Hydrogen Energy, 36(1), pp. 72-78, 2010. DOI: 10.1016/j.ijhydene.2010.09.056.
Louardi, A., Rmili, A., Ouachtari, F., Bouaoud, A., Elidrissi, B. and Erguig, H., Characterization of cobalt oxide thin films prepared by a facile spray pyrolysis technique using perfume atomizer. Journal of Alloys and Compounds, 509(37), pp. 9183-9189, 2011. DOI: 10.1016/j.jallcom.2011.06.106.
Al-Tuwirqi, R., Al-Ghamdi, A.A., Aal, N.A., Umar, A. and Mahmoud, W.E., Facile synthesis and optical properties of Co3O4 nanostructures by the microwave route. Superlattices and Microstructures, 49(4), pp. 416-421, 2011. DOI: 10.1016/j.spmi.2010.12.010.
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7. Esra Kus, Ayse Kucukarslan, Barbaros Demirselcuk, Emrah Sarica, Idris Akyuz, Vildan Bilgin. (2021). Ultrasonically sprayed cobalt oxide thin films: Enhancing of some physical properties by nickel doping. Materials Letters, 297, p.129962. https://doi.org/10.1016/j.matlet.2021.129962.
8. A. Karthikeyan, R. Mariappan, E. Krishnamoorthy, R. Bakkiyaraj. (2024). Effect of Nickel doping on Cobalt Oxide nanoparticles for energy storage applications. Ionics, 30(4), p.2069. https://doi.org/10.1007/s11581-024-05417-4.
9. Xiangxiang Fan, Susu Yang, Yilin Xu, Yutian Chen. (2024). Surface oxygen vacancy adjustment and acetone sensing performance enhancement of ZIF-67 derived Co3O4 with trace Ni-doping. Materials Science in Semiconductor Processing, 179, p.108494. https://doi.org/10.1016/j.mssp.2024.108494.
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11. Shahed Hassanpoor, Farzaneh Aghely. (2020). Hierarchically self-assembled NiCo2O4 nanopins as a high-performance supercapacitor cathodic material: a morphology controlled study. RSC Advances, 10(58), p.35235. https://doi.org/10.1039/D0RA07620A.
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14. Leydi Julieta Cardenas Flechas, Elena Xuriguera Martín, Jose Antonio Padilla Sanchez, Josep Ma Chimenos Ribera, Miryam Rincón Joya. (2021). Experimental comparison of the effect of temperature on the vibrational and morphological properties of NixCo3-xO4 nanostructures. Materials Letters, 303, p.130477. https://doi.org/10.1016/j.matlet.2021.130477.
15. Leydi Julieta Cardenas Flechas, Elena Xuriguera Martín, Jose Antonio Padilla Sanchez, Josep Ma. Chimenos Ribera, Miryam Rincón Joya. (2023). Effect of nickel and rGO on the photocatalytic properties of Co3−xNixO4 prepared with citric acid and CTAB. Materials Today Communications, 35, p.106406. https://doi.org/10.1016/j.mtcomm.2023.106406.
16. João Otávio Donizette Malafatti, Ailton José Moreira, Elaine Cristina Paris, Leydi Julieta Cardenas Flechas, Otávio Augusto Poli Pereira, Miryam Rincón Joya. (2022). Evaluation of Ni-Doped Tricobalt Tetroxide with Reduced Graphene Oxide: Structural, Photocatalysis, and Antibacterial Response. Catalysts, 12(10), p.1199. https://doi.org/10.3390/catal12101199.
17. Vaishnavi V. Phule, Rutuja N. Gurav, Nilesh L. Tarwal, Umakant M. Patil, Kishor V. Gurav, Jin Hyeok Kim. (2024). Electrocatalytic Materials. , p.177. https://doi.org/10.1007/978-3-031-65902-7_5.
18. Gerrit Küchen, Vinzent Olszok, Bjarne Kreitz, Christoph Mahr, Andreas Rosenauer, Thomas Turek, Alfred P. Weber, Gregor D. Wehinger. (2024). Spray‐dried Ni‐Co Bimetallic Catalysts for Dry Reforming of Methane. ChemCatChem, 16(17) https://doi.org/10.1002/cctc.202400371.
19. L.J. Cardenas-Flechas, Eric Santiago-Hernandez, L.A. Teran. (2026). Anodic formation of molybdenum-doped vanadium oxide films. Materials Today Communications, 50, p.114446. https://doi.org/10.1016/j.mtcomm.2025.114446.
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21. M. Qasim, K. Nadeem, M. Shahid, M. Zareef Khan, Ablikim Baqi. (2025). Effects of Cu and Ni co-doping on magnetic, photocatalytic and dielectric properties of Co3O4 nanoparticles. Ceramics International, 51(9), p.11467. https://doi.org/10.1016/j.ceramint.2025.01.001.
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