Published

2021-04-16

Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study

Evaluación del uso de turbas tropicales como materiales alternativos locales para la adsorción de Pb, Zn y Cd: Un estudio de equilibrio

DOI:

https://doi.org/10.15446/esrj.v25n1.84276

Keywords:

Batch equilibrium test, Freundlich isotherm, Langmuir isotherm, Potentially toxic elements, Sorption (en)
Prueba de equilibrio de lote, Isoterma de Freundlich, Isoterma de Langmuir, Elementos potencialmente tóxicos, Sorción (es)

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Authors

  • Isabela Monici Raimondi São Carlos School of Engineering; University of São Paulo
  • Valéria Guimarães Rodrigues São Carlos School of Engineering; University of São Paulo https://orcid.org/0000-0001-8937-839X
  • Jacqueline Zanin Lima São Carlos School of Engineering; University of São Paulo
  • Jéssica Pelinsom Marques São Carlos School of Engineering; University of São Paulo
  • Luiz Augusto Artimonti Vaz Cronos Consultoria
  • Eny Maria Vieira Department of Chemistry and Molecular Physics, Institute of Chemistry of São Carlos, University of São Paulo

Peat is an organic material that has been widely used as an efficient and low-cost adsorbent. As many studies tend to focus on temperate peats, there is a lack of knowledge about the adsorption mechanism of tropical peats. This paper investigates the use of two Brazilian peats (Cravinhos - C and Luis Antônio - LA) from the Mogi-Guaçu river basin for the adsorption of lead (Pb), zinc (Zn), and cadmium (Cd), in order to contribute to the use of local and easy access materials to remediate contaminated sites. The peats adsorbed a high percentage of cations, especially Pb cations (100.0-46.3%), with commercial peat C showing higher adsorption than peat LA. The removal order was Pb2+ > Cd2+ ≥ Zn2+ for C and Pb2+ > Zn2+ > Cd2+ for LA. The batch data for both peats and for all metals were better fit by the Langmuir isotherm, with adsorption capacities (qm) for Pb, Zn, and Cd of 37.3134, 29.0674 and 21.2890 mmol kg-1 in peat C and 21.7391, 14.2550 and 3.6460 mmol kg-1 in LA, respectively, values comparable to those of other peats and biosorbents. The studied peats are considered efficient, alternative and low-cost adsorptive materials for these metals. The proximity of peatlands to areas with high potential for contamination necessitates the use of local materials to reduce remediation costs.             

La turba es un material orgánico que se ha utilizado ampliamente como un adsorbente eficiente y de bajo costo. Como muchos estudios tienden a centrarse en las turbas templadas, existe una falta de conocimiento sobre el mecanismo de adsorción de las turbas tropicales. Este artículo investiga el uso de dos turbas brasileñas (C y LA) de la cuenca del río Mogi-Guaçu para la adsorción de plomo (Pb), zinc (Zn) y cadmio (Cd). Las turbas adsorbieron un alto porcentaje de cationes, especialmente cationes Pb (100.0-55.5%), con la turba comercial C mostrando una mayor adsorción que la turba LA. El orden de eliminación fue Pb2 +> Cd2 + ≥ Zn2 + para C y Pb2 +> Zn2 +> Cd2 + para LA. La isoterma de Langmuir ajustó mejor los datos de lote para las turbas y para todos los metales, con capacidades de adsorción (qm) para Pb, Zn y Cd de 37.313, 29.070 y 21.288 mmol kg-1 en turba C y 21.739, 14.255 y 3.645 mmol kg-1 en LA, respectivamente, valores comparables a los de otras turbas y biosorbentes. Las turbas estudiadas se consideran materiales adsorbentes eficientes, alternativos y de bajo costo para estos metales. La proximidad de las turberas a las áreas con alto potencial de contaminación requiere el uso de materiales locales para reducir los costos de remediación.

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How to Cite

APA

Raimondi, I. M., Rodrigues, V. G., Lima, J. Z., Marques, J. P., Vaz, L. A. A. and Vieira, E. M. (2021). Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal, 25(1). https://doi.org/10.15446/esrj.v25n1.84276

ACM

[1]
Raimondi, I.M., Rodrigues, V.G., Lima, J.Z., Marques, J.P., Vaz, L.A.A. and Vieira, E.M. 2021. Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal. 25, 1 (Apr. 2021). DOI:https://doi.org/10.15446/esrj.v25n1.84276.

ACS

(1)
Raimondi, I. M.; Rodrigues, V. G.; Lima, J. Z.; Marques, J. P.; Vaz, L. A. A.; Vieira, E. M. Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth sci. res. j. 2021, 25.

ABNT

RAIMONDI, I. M.; RODRIGUES, V. G.; LIMA, J. Z.; MARQUES, J. P.; VAZ, L. A. A.; VIEIRA, E. M. Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth Sciences Research Journal, [S. l.], v. 25, n. 1, 2021. DOI: 10.15446/esrj.v25n1.84276. Disponível em: https://revistas.unal.edu.co/index.php/esrj/article/view/29-40. Acesso em: 1 oct. 2024.

Chicago

Raimondi, Isabela Monici, Valéria Guimarães Rodrigues, Jacqueline Zanin Lima, Jéssica Pelinsom Marques, Luiz Augusto Artimonti Vaz, and Eny Maria Vieira. 2021. “Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study”. Earth Sciences Research Journal 25 (1). https://doi.org/10.15446/esrj.v25n1.84276.

Harvard

Raimondi, I. M., Rodrigues, V. G., Lima, J. Z., Marques, J. P., Vaz, L. A. A. and Vieira, E. M. (2021) “Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study”, Earth Sciences Research Journal, 25(1). doi: 10.15446/esrj.v25n1.84276.

IEEE

[1]
I. M. Raimondi, V. G. Rodrigues, J. Z. Lima, J. P. Marques, L. A. A. Vaz, and E. M. Vieira, “Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study”, Earth sci. res. j., vol. 25, no. 1, Apr. 2021.

MLA

Raimondi, I. M., V. G. Rodrigues, J. Z. Lima, J. P. Marques, L. A. A. Vaz, and E. M. Vieira. “Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study”. Earth Sciences Research Journal, vol. 25, no. 1, Apr. 2021, doi:10.15446/esrj.v25n1.84276.

Turabian

Raimondi, Isabela Monici, Valéria Guimarães Rodrigues, Jacqueline Zanin Lima, Jéssica Pelinsom Marques, Luiz Augusto Artimonti Vaz, and Eny Maria Vieira. “Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study”. Earth Sciences Research Journal 25, no. 1 (April 16, 2021). Accessed October 1, 2024. https://revistas.unal.edu.co/index.php/esrj/article/view/29-40.

Vancouver

1.
Raimondi IM, Rodrigues VG, Lima JZ, Marques JP, Vaz LAA, Vieira EM. Assessment of the use of tropical peats as local alternative materials for the adsorption of Pb, Zn and Cd: An equilibrium study. Earth sci. res. j. [Internet]. 2021 Apr. 16 [cited 2024 Oct. 1];25(1). Available from: https://revistas.unal.edu.co/index.php/esrj/article/view/29-40

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CrossRef citations8

1. Jacqueline Zanin Lima, Renan Marques Lupion, Isabela Monici Raimondi, Osni José Pejon, Valéria Guimarães Silvestre Rodrigues. (2021). Sorption Efficiency of Potentially Toxic Elements onto Low-Cost Materials: Peat and Compost. Sustainability, 13(22), p.12847. https://doi.org/10.3390/su132212847.

2. Olga Shvartseva, Tatiana Skripkina, Olga Gaskova, Ekaterina Podgorbunskikh. (2022). Modification of Natural Peat for Removal of Copper Ions from Aqueous Solutions. Water, 14(13), p.2114. https://doi.org/10.3390/w14132114.

3. Jacqueline Zanin Lima, Isabela Monici Raimondi Nauerth, Eduardo Ferreira da Silva, Osni José Pejon, Valéria Guimarães Silvestre Rodrigues. (2023). Competitive sorption and desorption of cadmium, lead, and zinc onto peat, compost, and biochar. Journal of Environmental Management, 344, p.118515. https://doi.org/10.1016/j.jenvman.2023.118515.

4. Jacqueline Zanin Lima, Eduardo Anselmo Ferreira da Silva, Valéria Guimarães Silvestre Rodrigues. (2024). Sorption and economic viability of peat, compost and biochar for zinc-contaminated site. Environmental Geotechnics, 11(6), p.459. https://doi.org/10.1680/jenge.22.00046.

5. Jéssica Pelinsom Marques, Isabela Monici Raimondi Nauerth, Mariana Consiglio Kasemodel, Valéria Guimarães Silvestre Rodrigues. (2024). Systematic review of alternative materials that improve retention of potentially toxic metals in soil/clay liners in waste disposal areas. Environmental Monitoring and Assessment, 196(4) https://doi.org/10.1007/s10661-024-12546-w.

6. Jacqueline Zanin Lima, Allan Pretti Ogura, Evaldo Luiz Gaeta Espíndola, Eduardo Ferreira da Silva, Valéria Guimarães Silvestre Rodrigues. (2024). Post-sorption of Cd, Pb, and Zn onto peat, compost, and biochar: Short-term effects of ecotoxicity and bioaccessibility. Chemosphere, 352, p.141521. https://doi.org/10.1016/j.chemosphere.2024.141521.

7. Jacqueline Zanin Lima, Eduardo Ferreira da Silva, Carla Patinha, Valéria Guimarães Silvestre Rodrigues. (2022). Sorption and post-sorption performances of Cd, Pb and Zn onto peat, compost and biochar. Journal of Environmental Management, 321, p.115968. https://doi.org/10.1016/j.jenvman.2022.115968.

8. I. M. Raimondi, E. M. Vieira, L. A. A. Vaz, V. G. S. Rodrigues. (2022). Comparison of sugarcane pressmud with traditional low-cost materials for adsorption of lead and zinc in mining areas. International Journal of Environmental Science and Technology, 19(6), p.4627. https://doi.org/10.1007/s13762-021-03420-0.

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