Publicado

2016-01-01

Estudo matemático de estabilidade do desempenho do sistema [Fe(CN)6]3–/[Fe(CN)6]4– como mediador na eletrorredução de nitrito, com fins eletroanalíticos

The mathematical stability study for the work of the [Fe(CN)6]3-/[Fe(CN)6]4- system as a mediator in nitrite electroreduction, used for electroanalytical means

DOI:

https://doi.org/10.15446/rcciquifa.v45n1.58017

Palabras clave:

nitrito eletrorredução, hexacianoferrato, sensores eletroquímicos, estado estacionário estável (pt)
Nitrite, Electroreduction, Hexacyanoferrate, Electrochemical sensors, Stable steady-state (en)

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Autores/as

  • Volodymyr V. Tkach Universidade Nacional de Chernivtsi
  • André Santos Universidade Federal de Uberlândia
  • Reza Ojani Universidade de Mazandarã
  • Petró I. Yagodynets Universidade Nacional de Chernivtsi

O desempenho do sensor de nitrito, baseado no elétrodo, modificado pelo sistema de hexacianoferratos (II) e (III) como mediador, foi descrito matematicamente, sendo o modelo matemático correspondente analisado mediante a teoria de estabilidade lineal e análise de bifurcações. O modelo foi comparado com os análogos e com os sistemas experimentais.

The work of nitrite sensor, based on the electrode, modified by the system of hexacianoferrates (II) and (III) as mediator, was mathematically described, and the corresponding mathematical model was analyzed by means of linear stability theory and bifurcation analysis. The model was compared with its analogues and experimental systems.

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Cómo citar

Tkach, V. V., Santos, A., Ojani, R., & Yagodynets, P. I. (2016). Estudo matemático de estabilidade do desempenho do sistema [Fe(CN)6]3–/[Fe(CN)6]4– como mediador na eletrorredução de nitrito, com fins eletroanalíticos. Revista Colombiana De Ciencias Químico-Farmacéuticas, 45(1), 77-91. https://doi.org/10.15446/rcciquifa.v45n1.58017

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