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Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
Solvatación preferencial de tricin en mezclas etanol + agua a varias temperaturas
DOI:
https://doi.org/10.15446/rcciquifa.v47n2.73933Palabras clave:
Tricin, IKBI, ethanol, preferential solvation (en)Tricina, IKBI, etanol, solvatación preferencial (es)
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The preferential solvation parameters of tricin in {ethanol (1) + water (2)} binary mixtures were obtained from their thermodynamic properties by means of the inverse Kirkwood-Buff integrals method. Tricin is very sensitive to specific solvation effects, so the preferential solvation parameter by ethanol (1), δx1,3, is negative in the water-rich mixtures but positive in all the other compositions at temperatures from
293.15, to 313.15 K. It is conjecturable that in water-rich mixtures the hydrophobic hydration around the aromatic and methyl groups of the drug plays a relevant role
in the solvation. The higher drug solvation by ethanol in mixtures of similar solvent proportions and in ethanol-rich mixtures could be due mainly to polarity effects. In
these mixtures, the drug would be acting as Lewis acid with the ethanol molecules because this co-solvent is more basic than water.
el método de las integrales inversas de Kirkwood-Buff. La tricina es muy sensible a los efectos de solvatación específicos, por lo que el parámetro de solvatación preferencial, δx1,3, es negativo en las mezclas ricas en agua, pero positivo en todas las otras composiciones a temperaturas desde 293,15 hasta 313,15 K. Se puede establecer que en mezclas ricas en agua la hidratación hidrofóbica alrededor de los grupos aromáticos
y metilo del fármaco tiene un papel relevante en la solvatación. La mayor solvatación
del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad.
En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolvente es más básico que el agua.
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