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Prediction of sulfamerazine and sulfamethazine solubility in some cosolvent mixtures using non-ideal solution models
Predicción de la solubilidad de sulfamerazina y sulfametazina en algunas mezclas cosolventes utilizando modelos de solución no ideales
Predição da solubilidade de sulfamerazina e sulfametazina em algumas misturas de cosolventes usando modelos de solução não ideais
DOI:
https://doi.org/10.15446/rcciquifa.v50n1.95463Keywords:
Sulfamerazine, sulfamethazine, solubility, van’t Hoff model, Apelblat modified model, Buchowski-Ksiazaczak λh model, van’t Hoff-Yaws model, twoparameter Weibull function model (en)Sulfametazina, sulfamerazina, solubilidade, modelo van’t Hoff, modelo Apelblat modificado, modelo Buchowski-Ksiazaczak λh, modelo van’t Hoff-Yaws, modelo Weibull de dois parâmetros (pt)
Sulfametazina, sulfamerazina, solubilidad, modelo de van’t Hoff, modelo de Apelblat modificado, modelo de Buchowski-Ksiazaczak λh, modelo de van’t Hoff-Yaws, modelo de Weibull de dos parámetros (es)
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Introduction: Experimental Solubilities of sulfamerazine (SMR) and sulfamethazine (SMT) in some (methanol + water), (ethanol + water) and (1-propanol + water) cosolvent mixtures were collected from the literature at five temperatures from 293.15 to 313.15 K. Methodology: The results were analyzed with the van’t Hoff, Apelblat modified, Buchowski-Ksiazaczak λh, van’t Hoff-Yaws model, twoparameter Weibull function model. It was determined that the models that best describe the solubility of these sulfonamides in (alcohol + water) mixtures were the van’t Hoff and Apelblat models, obtaining correlation indices greater than 0.99 in all cases. Results: The results obtained with the Modified Apelblat equation presents a high correlation index for the solubility of SMR and SMT in cosolvent mixtures, followed by the van’t Hoff-Yaws model that presents a high fit of the estimated data with respect to the theoretical ones. According to the two parameter Weibull function model, the solubility of SMR and SMT in the co-solvent mixtures shows important deviations from ideality, which is consistent with the literature. The results are discussed in terms of the solute-solvent interactions that occur in this system.
Introducción: las solubilidades experimentales de la sulfamerazina (SMR) y la sulfametazina (SMT) en algunas mezclas cosolvents (metanol + agua), (etanol + agua) y (1-propanol + agua), se revisaron en la literatura a cinco temperaturas de 293,15 a 313,15 K. Metodología: los resultados se analizaron con el modelo van’t Hoff, Apelblat modificado, Buchowski-Ksiazaczak λh, van’t Hoff-Yaws, y el modelo de la función Weibull de dos parámetros. Se determinó que los modelos que mejor describen la solubilidad de estas sulfonamidas en mezclas (alcohol + agua) son los modelos de van’t Hoff y Apelblat, obteniendo índices de correlación superiores a 0,99 en todos los casos. Resultados: los resultados obtenidos con la ecuación de Apelblat modificada presentan un alto índice de correlación para la solubilidad de SMR y SMT en mezclas de cosolventes, seguido del modelo van’t Hoff-Yaws que presenta un alto ajuste de los datos calculados con respecto a los teóricos. Según el modelo de la función de Weibull de dos parámetros, la solubilidad de la SMR y la SMT en las mezclas de cosolventes muestra importantes desviaciones de las ideales, lo que es coherente con la literatura. Los resultados se discuten en términos de las interacciones soluto-solvente que se producen en este sistema.
Introdução: as solubilidades experimentais de sulfamerazina (SMR e sulfametazina (SMT) em algumas misturas de cossolventes (metanol + água), (etanol + água) e (1 propanol + água), foram revisadas na literatura em cinco temperaturas de 293,15 a 313,15 K. Metodologia: os resultados foram analisados com o modelo van’t Hoff, Apelblat modificado, Buchowski-Ksiazaczak λh, van’t Hoff-Yaws e o modelo de função Weibull de dois parâmetros. Determinou-se que os modelos que melhor descrevem a solubilidade dessas sulfonamidas em misturas (álcool + água) são os modelos van’t Hoff e Apelblat, obtendo índices de correlação superiores a 0,99 em todos os casos. Resultados: os resultados obtidos com a equação de Apelblat modificada apresentam um alto índice de correlação para a solubilidade de SMR e SMT em misturas de cosolventes, seguido pelo modelo de van’t Hoff-Yaws que apresenta um alto ajuste dos dados calculados em relação a teóricos. De acordo com o modelo de função Weibull de dois parâmetros, a solubilidade de SMR e SMT em misturas de cosolventes apresenta desvios significativos dos ideais, o que é consistente com a literatura. Os resultados são discutidos em termos das interações soluto-solvente que ocorrem neste sistema.
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1. Rossember E. Cárdenas-Torres, Claudia Patricia Ortiz, William E. Acree, Abolghasem Jouyban, Fleming Martínez, Daniel Ricardo Delgado. (2022). Thermodynamic study and preferential solvation of sulfamerazine in acetonitrile + methanol cosolvent mixtures at different temperatures. Journal of Molecular Liquids, 349, p.118172. https://doi.org/10.1016/j.molliq.2021.118172.
2. Andrea Torres-Cardozo, Nestor Enrique Cerquera, Claudia Patricia Ortiz, Jhonny Osorio-Gallego, Rossember Edén Cardenas-Torres, Fredy Angarita-Reina, Fleming Martinez, Daniel Ricardo Delgado. (2023). Thermodynamic analysis of the solubility of progesterone in 1-octanol + ethanol cosolvent mixtures at different temperatures. Alexandria Engineering Journal, 64, p.219. https://doi.org/10.1016/j.aej.2022.08.035.
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