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The theoretical description for cobalt oxyhydroxide-assisted resveratrol electrochemical determination in vines and juices
La descripción teórica de la detección electroanalítica de resveratrol en vinos y jugos, asistida por el oxihidróxido de cobalto
A descrição teórica da detecção eletroanalítica de resveratrol em vinhos e sucos, assistida pelo oxihidróxido de cobalto
DOI:
https://doi.org/10.15446/rcciquifa.v53n2.114424Palavras-chave:
resveratrol, electrochemical sensor, cobalt oxyhydroxide, conducting polymer, stable steady-state (en)resveratrol, sensor electroquímico, oxihidróxido de cobalto, polímeros conductores, estado estacionario estable (es)
resveratrol, sensor eletroquímico, oxihidróxido de cobalto, polímeros condutores, estado estacionário estável (pt)
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Introduction: The possibility of resveratrol electrochemical determination, assisted by cobalt (III) oxyhydroxide and its composites with conducting polymers has been evaluated from the theoretical point of view. Methodology: The correspondent mathematical model has been developed and analyzed by means of the linear stability theory and bifurcation analysis. Results: The analysis of the model confirms that the cobalto oxyhydroxide may serve as an efficient electrode modifier for resveratrol electroanalytical determination. Conclusion: Depending on the analysis conditions, the electroanalytical process may be either diffusion- or kinetically controlled. On the other hand, the oscillatory behavior is also possible being even more probable than in the simplest cases, due to the impact of the chemical and electrochemical stages on DEL.
Introducción: La posibilidad de la detección electroanalítica de resveratrol, asistida por el oxihidróxido de cobalto y sus compuestos con polímeros conductores ha sido teóricamente evaluada. Metodología: El modelo matemático correspondiente ha sido desarrollado y analizado mediante la teoría de estabilidad lineal y análisis de bifurcaciones. Resultados: El análisis del modelo confirma que el oxihidróxido de cobalto puede ser eficaz en la detección electroanalítica de resveratrol. Conclusión: Dependiendo de las condiciones de análisis, el proceso electroanalítico puede ser controlado tanto por la difusión como por la cinética del proceso. Por otro lado, el comportamiento oscilatorio también es posible, siendo, además, más probable que en los casos más simples, visto el impacto de las etapas químicas y la electroquímica en la doble capa eléctrica.
Introdução: A possibilidade da detecção eletroanalítica de resveratrol, assistida pelo oxihidróxido de cobalto e seus compósitos com polímeros condutores tem sido avaliada do ponto de vista teórico. Metodologia: O modelo matemático correspondente tem sido desenvolvido e analisado mediante a teoria de estabilidade linear e análise de bifurcações. Resultados: A análise do modelo confirma que o oxihidróxido de cobalto pode servir de uma substância ativa eficaz na detecção eletroanalítica de resveratrol. Conclusão: A depender das condições da análise, o processo eletroanalítico pode ser controlado tanto pela difusão como pela cinética do processo. Por outro lado, o comportamento oscilatório também é possível, sendo, ademais, mais provável que nos casos mais simples, haja vista o impacto das etapas químicas e eletroquímica na dupla camada eléctrica.
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