Publicado
Versiones
- 2021-11-25 (2)
- 2020-03-31 (1)
Cinética de eflorescencia grasa en muestras de chocolate oscuro comercial en Perú
Kinetic of fat bloom in commercial dark chocolate samples in Peru
Palabras clave:
Función exponencial, índice de blancura, método acelerado., Cacao (es)Accelerated method, exponential function, whiteness index., Cacao (en)
La eflorescencia de la grasa es un proceso de recristalización que da como resultado un chocolate de superficie opaca y blanca. Este trabajo tuvo como objetivo determinar la cinética de aparición de este fenómeno evaluando el Indice de Blancura (IB) en chocolate comercial peruano con 45 y 70% de cacao. La cinética fue determinada por el método acelerado de ciclos de temperaturas de 30 ± 1 ºC durante 8 h y 20 ± 1 ºC durante 16 h a humedades relativas de 30, 50 y 70%. Las mediciones se realizaron cada 48 h (1 día de por medio). Los resultados mostraron que, la humedad relativa no afectó (P > 0.05) la cinética de eflorescencia grasa antes de 48 h de almacenamiento. El mayor IB, promedio, observado fue 55.7 ± 0.25 para el chocolate con 70% de cacao, almacenado a 30% de humedad. La cinética de eflorescencia grasa expresada en IB se ajustó a la función exponencial invertida: IB = IBf - (IBf - IBi) e-Kθ.
The fat bloom is a recrystallization process, resulting in the surface of the chocolate becoming opaque and white. The objective of the research was to determine the kinetics of appearance of the referred phenomenon by evaluating the whiteness index (WI) in Peruvian chocolate for sale with 45 and 70% of cocoa. The kinetics were determined for the accelerated method of temperature cycles with cycles of 30 ± 1°C (for 8 hours) and 20 ± 1°C (for 16 hours) at relative humidity of 30; 50 and 70 percent; the measurements were inter-daily. The relative humidity did not significantly influence (P > 0.05) in the fat bloom kinetic before 48 hours of storage. The highest average (IB) observed was 55.7 ± 0.25, reached by chocolate at 70% cocoa, stored at 30% of humidity. The kinetic of fat bloom is given by the inverted exponential function: WI = WIf - (WIf - WIi) e-Kθ.
Descargas
Citas
Afoakwa E.O.; Paterson A.; Fowler M.; Vieira J. 2009. Fat bloom development and structure-appearance relationships during storage of under-tempered dark chocolates. Journal of Food Engineering, 91(4), 571–581. https://doi.org/10.1016/j.jfoodeng.2008.10.011
Ali A.; Selamat J.; Man Y.B.C.; Suria A.M. 2001. Effect of storage temperature on texture, polymorphic structure, bloom formation and sensory attributes of filled dark chocolate. Food Chemistry, 72, 491–497. https://doi.org/10.1016/S0308-8146(00)00271-5
Altimira P.; Pyle L.; Bouchon P. 2007. Structure–fat migration relationships during storage of cocoa butter model bars: Bloom development and possible mechanisms. Journal of Food Engineering, 80(2), 600–610. https://doi.org/10.1016/j.jfoodeng.2006.06.022
Álvarez C.; Pérez E.; Lares, M. 2007. Caracterización física y química de almendras de cacao fermentadas, secas y tostadas cultivadas en la región de Cuyagua, estado Aragua. Agronomía Tropical, 57(4), 249–256. http://ve.scielo.org/scielo.php?pid=S0002-192X2007000400001&script=sci_arttext&tlng=pt
AOAC. 2016. Official methods of analysis of AOAC international. AOAC, Ed.) (20th edition. AOAC Maryland, USA.
Ashida H.; Morita A.; Karatani N.; Sato R.; Sato K. 2020. Surface topographic analysis of early stages of fat bloom of dark chocolate with 3D-laser scanning confocal microscopy (3D-LSCM). Food structure, 23, 100136. https://doi.org/10.1016/j.foostr.2020.100136
Bahari P.; Akoh C. 2018. Texture, rheology and fat bloom study of ‘chocolates’ made from cocoa butter equivalent synthesized from illipe butter palm mid-fraction. LWT- Food Science and Technology, 97, 349–354. https://doi.org/10.1016/j.lwt.2018.07.013
Beckett, S. 2008. The Science of Chocolate. Royal Society of Chemistry 2nd ed.240 p.
Biswas N.; Cheow Y.; Tan C.; Siow L. 2017. Physical, rheological and sensorial properties, and bloom formation of dark chocolate made with cocoa butter substitute (CBS). LWT- Food Science and Technology, 82, 420–428. https://doi.org/10.1016/j.lwt.2017.04.039
Bricknell J.; Hartel R.W. 1998. Relation of fat bloom in chocolate to polymorphic transition of cocoa butter. Journal of the American Oil Chemists’ Society, 75(11), 1609–1615. https://doi.org/10.1007/s11746-998-0101-0
Briones V.; Aguilera J. 2005. Image analysis of changes in surface color of chocolate. Food Research International, 38(1), 87–94. https://doi.org/10.1016/j.foodres.2004.09.002
Bui, L.; Coad, R. 2014. Military ration chocolate: The effect of simulated tropical storage on sensory quality, structure and bloom formation. Food chemistry, 160, 365–370. https://doi.org/10.1016/j.foodchem.2014.03.084
Chire G.; Hartel R.W. 2011. Efecto de diferentes emulsificantes en las propiedades reológicas y la eflorescencia grasa del chocolate oscuro. Anales Científicos, 72(1), 1–12. http://dx.doi.org/10.21704/ac.v72i1.852
Chire G.; Ureña M.; Hartel R. 2020. Fatty acid profile and solid fat content of peruvian cacao for optimal production of trade chocolate. Rev Chil Nutr., 47(1): 50-56. http://dx.doi.org/10.4067/S0717-75182020000100050
Clercq N.; Depypere F.; Delbaere C.; Nopens I.; Bernaert H.; Dewettinck K. 2014. Influence of cocoa butter diacylglycerols on migration induced fat bloom in filled chocolates. European Journal of Lipid Science and Technology, 116 (10), 1388–1399. https://doi.org/10.1002/ejlt.201300476
Dahlenborg H. 2014. Fat bloom on chocolate confectionery systems - From core to surface. Doctoral thesis. Lund: Department of food technology, engineering and nutrition, Faculty of engineering LTH, Lund University. https://portal.research.lu.se/portal/en/publications/fat-bloom-on-chocolate-confectionery-systems--from-core-to-surface(5dbc4c31-918f-46a2-aa09-571614afd9f3)/export.html
Dahlenborg H.; Millqvist-Fureby A.; Bergenstahl, B. 2015. Effect of particle size in chocolate shell on oil migration and fat bloom development. Journal of Food Engineering, 146, 172-181. http://dx.doi.org/10.1016/j.jfoodeng.2014.09.008
Flores N.; Chire G.; Lescano C. 2017. Rheological, fat bloom, and sensory acceptability effects of mango kernel fat and palm olein blends on chocolate-flavored coatings. Acta Agronómica 66(4), 506-511. https://doi.org/10.15446/acag.v66n4.56219
Galdámez J.R.; Szlachetka K.; Duda J.L.; Ziegler G.R. 2009. Oil migration in chocolate: A case of non-Fickian diffusion. Journal of Food Engineering, 92(3), 261–268. https://doi.org/10.1016/j.jfoodeng.2008.11.003
Ghosh V.; Ziegler G.R.; Anantheswaran R. 2005. Moisture migration trough chocolate flavored confectionery coatings. Journal of Food Engineering, 66(2), 177-186. https://doi.org/10.1016/j.jfoodeng.2004.03.012
Halim H.; Selemat J.; Mirhosseini S.; Hussain N. 2019. Sensory preference and bloom stability of chocolate containing cocoa butter substitute from coconut oil. Journal of the Saudi Society of Agricultural Sciences, 18(4), 443-448. https://doi.org/10.1016/j.jssas.2018.02.005
Huanhuan Z.; Bryoni J. 2018. Fat bloom formation on model chocolate stored under steady and cycling temperatures. Journal of Food Engineering, 249, 9–14. https://doi.org/10.1016/j.jfoodeng.2018.12.008
James, B.; Smith, B. 2009. Surface structure and composition of fresh bloomed chocolate analysed using x-ray photoelectron spectroscopy, cryo-scanning electron microscopy and environmental scanning electron microscopy. LWT-Food Science and Technology, 42(5), 929–937. https://doi.org/10.1016/j.lwt.2008.12.003
Jin J.; Jin Q.; Wang X.; Akoh C. 2018. Improving heat and fat bloom stabilities of “dark chocolates” by addition of mango kernel fat-based chocolate fats. Journal of Food Engineering, 246, 33–41. https://doi.org/10.1016/j.jfoodeng.2018.10.027
Labuza, T. 1982. Moisture gain and lose in package foods. T. Labuza, Ed. Food technology. USA. 97 p
Lohman, M.; Hartel, R.W. 1994. Effect of milk fact fractions on fat bloom in dark chocolate. Journal of American Oil Chemists´ Society, 71(3), 267–276. https://doi.org/10.1007/BF02638052
Masuchi-Buscato, M.; Hara, L.; Bonomi, E.; Calligaris, G. A.; Cardoso, L. P.; Grimaldi, R.; Kieckbusch, T. G. 2018. Delaying fat bloom formation in dark chocolate by adding sorbitan monostearate or cocoa butter stearin. Food Chemistry, 256, 390-396. https://doi.org/10.1016/j.foodchem.2018.02.127
Mexis, S.F.; Badeka, A.V.; Riganakos, K.A.; Kontominas, M.G. 2010. Effect of active and modified atmosphere packaging on quality retention of dark chocolate with hazelnuts. Innovative Food Science and Emerging Technologies, 11(1), 177–186. https://doi.org/10.1016/j.ifset.2009.09.001
Pastor-Navarro, C. 2010. Recubrimientos comestibles a base de hidroxipropil metil: caracterización y aplicación. Tesis doctoral. Universidad Politécnica de Valencia. https://doi.org/10.4995/Thesis/10251/8534
Prieto, J.; Prieto, F.; Román, A.D.; Otazo, E.M. 2012. Correlation of mathematical models of adsortion of humidity in cereal for breakfast. Avances en Ciencia e Ingeniería ACI, 3(1), 137–150. https://www.uaeh.edu.mx/investigacion/productos/5363/
Rubio, D. 2004. Determinación del tiempo óptimo de homogenización de partículas en un mezclador de volteo tipo pantalón. Tesis pregrado. Universidad Nacional Agraria La Molina. http://repositorio.lamolina.edu.pe/
Sánchez-Silva, A.; Cruz-Freire, J. M.; Sendón-García, R.; Franz, R.; Paseiro-Losada, P. 2007. Time temperature study of the kinetics of migration of DPBD from plastic into chocolate, chocolate spread and margarine. Food Research International, 40(6), 679–686. https://doi.org/10.1016/j.foodres.2006.11.012
Seid R.; Hensel, O. 2012. Experimental evaluation sorption isotherms of chilli pepper: an Ethiopian variety, Mareko fana (Capsicum annun L.). Agricutural Engineering International CIGR Journal, 14(4), 163–172. https://cigrjournal.org/index.php/Ejounral/article/view/2187
Skrabal S.; Ackar D.; Babic J.; Milicevié B.; Jozinovic A.; y Subaric D. 2019. Effect of different storage conditions on fat bloom formation in different types of chocolate. Food in health and disease : scientific-professional journal of nutrition and dietetics, 8(2), 97-104. https://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=334633&lang=en
Zarringhalami S.; Sahari M.A.; Barzegar M.; y Hamidi-esfehani Z. 2010. Enzymatically modified tea seed oil as cocoa butter replacer in dark chocolate. International Journal of Food Science and Technology, 45(3), 540–545. https://doi.org/10.1111/j.1365-2621.2009.02162.x
Licencia
Derechos de autor 2020 Acta Agronómica

Esta obra está bajo una licencia internacional Creative Commons Atribución-NoComercial-SinDerivadas 4.0.
Política sobre Derechos de autor:Los autores que publican en la revista se acogen al código de licencia creative commons 4.0 de atribución, no comercial, sin derivados.
Es decir, que aún siendo la Revista Acta Agronómica de acceso libre, los usuarios pueden descargar la información contenida en ella, pero deben darle atribución o reconocimiento de propiedad intelectual, deben usarlo tal como está, sin derivación alguna y no debe ser usado con fines comerciales.

