INVESTIGATE THE STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF CARBON DOPED LiFePO4 PREPARED BY USING CAROXYLON IMBRICATUM FORSSK EXTRACT AS A DOPING AGENT

Published

2025-07-22

INVESTIGATE THE STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF CARBON DOPED LiFePO4 PREPARED BY USING CAROXYLON IMBRICATUM FORSSK EXTRACT AS A DOPING AGENT

INVESTIGACIÓN DE LAS PROPIEDADES ESTRUCTURALES Y ELECTROQUÍMICAS DE LiFePO4 RECUBIERTO DE CARBONO PREPARADO UTILIZANDO EXTRACTO DE CAROXYLON IMBRICATUM FORSSK COMO AGENTE DE RECUBRIMIENTO

Keywords:

conductivity, caroxylon Imbricatum, carbon coated LiFePO4, extract, electrochemical, nanoparticle (en)
conductividad, caroxylon imbricatum, extracto, electroquímica, LiFePO4 recubierto de carbono, nanopartículas (es)

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Authors

Saad S. Mohammed University of Thi-Qar https://orcid.org/0000-0003-3260-7379
Safaa H. Ali Al-Shatrah University https://orcid.org/0000-0003-4924-7453

Abstract (en)
Abstract (es)

This work evaluates the electrochemical performance of carbon-coated LiFePO₄ (LiFePO₄/C) using a plant extract of Caroxylon Imbricatum Forssk via a green synthesis route. The obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy and cyclic voltammetry to investigate the phase, crystalline structure, morphology and electrochemical performance. Both samples, LiFePO₄ and LiFePO₄/C, exhibited an olivine LiFePO₄ structure and the obtained particle sizes were in the nanoscale. The effects of the carbon coating improved the electrochemical performances of carbon-coated LiFePO₄ via enhancing rate capability and electronic conductivity.

Este trabajo evalúa el rendimiento electroquímico del LiFePO₄ (LiFePO₄/C) recubierto de carbono mediante un extracto vegetal de Caroxylon Imbricatum Forssk mediante una ruta de síntesis ecológica. Las muestras obtenidas se caracterizaron mediante difracción de rayos X (DRX), microscopía electrónica de barrido (MEB), espectroscopía Raman y voltamperometría cíclica para investigar la fase, la estructura cristalina, la morfología y el rendimiento electroquímico. Ambas muestras, LiFePO₄ y LiFePO₄/C, presentaron una estructura de LiFePO₄ de olivino y los tamaños de partícula obtenidos fueron a escala nanométrica. Los efectos del recubrimiento de carbono mejoraron el rendimiento electroquímico del LiFePO₄ recubierto de carbono al aumentar su capacidad de velocidad y la conductividad eléctrica.

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References

S. Chu and A. Majumdar, Nature 488, 294 (2012). https://www.nature.com/articles/nature11475

G. Wang, L. Zhang, and J. Zhang, Chem. Soc. Rev. 41, 797 (2012). https://pubs.rsc.org/en/content/articlelanding/2012/cs/c1cs15060j

J. Yan, Q. Wang, and et al., Adv. Energy Mater. 4, (2013). https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.201300816

D. G. Nocera, Chem. Soc. Rev. 38, 13 (2009). https://pubs.rsc.org/en/content/articlelanding/2009/cs/b820660k

J. Neumann, M. Petranikova, and et al., Adv. Energy Mater. 12, 2102917 (2022). https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.202102917

M. Armand and J.-M. Tarascon, Nature 451, 652 (2008). https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.202102917

M. Muratori, M. Alexander, and et al., Prog. Energ. 3, 022002 (2021). https://iopscience.iop.org/article/10.1088/2516-1083/abe0ad

J.-M. Tarascon, N. Recham, and et al., Chem. Mater. 22, 724 (2010). https://pubs.acs.org/doi/10.1021/cm9030478

C. Qi, T. Yao, and et al., Ener. Mater. 71, 103623 (2024). https://www.sciencedirect.com/science/article/abs/pii/S2405829724004495?via%3Dihub

B. Chen, M. Liu, and et al., Mater. Chem. Phys. 279, 125750 (2022). https://www.sciencedirect.com/science/article/abs/pii/S0254058422000566?via%3Dihub

A. Nekahi, A. Kumar M.R., and et al., Mater. Sci. Eng. Rep. 159, 100797 (2024). https://www.sciencedirect.com/science/article/pii/S0927796X24000275?via%3Dihub

S. Peng, D. Zhang, and et al., Appl. Energ. 377, 124435 (2025). https://www.sciencedirect.com/science/article/abs/pii/S030626192401818X?via%3Dihub

N. Nitta, F. Wu, and et al., Mater. Today 18, 252 (2015). https://www.sciencedirect.com/science/article/pii/S1369702114004118?via%3Dihub

W. C. M. de Oliveira, G. D. Rodrigues, and et al., Chem. Eng. J. 322, 346 (2017). https://www.sciencedirect.com/science/article/abs/pii/S1385894717305788?via%3Dihub

M. García-Plaza, D. Serrano-Jiménez, and et al., J Power Sources 275, 595 (2015). https://www.sciencedirect.com/science/article/abs/pii/S0378775314018576?via%3Dihub

P. T. Moseley, D. A. Rand, and K. Peters, J. Power Sources 295, 268 (2015). https://www.sciencedirect.com/science/article/abs/pii/S0378775315300574?via%3Dihub

N. Alias and A. A. Mohamad, J. Power Sources 274, 237 (2015). https://www.sciencedirect.com/science/article/abs/pii/S0378775314016188?via%3Dihub

A. K. Padhi, K. S. Nanjundaswamy, and J. B. Goodenough, J. Electrochem. Soc. 144, 1188 (1997). https://iopscience.iop.org/article/10.1149/1.1837571

P. P. Prosini, M. Lisi, and et al., Solid State Ionics 148, 45 (2002). https://www.sciencedirect.com/science/article/abs/pii/S0167273802001340?via%3Dihub

X. Wang, Z. Feng, and et al., Carbon 127, 149 (2018). https://www.sciencedirect.com/science/article/abs/pii/S0008622317311053?via%3Dihub

A. Fedorková, R. Oriňáková, and et al., Int. J. Electrochem. Sci. 8, 10308 (2013). https://www.sciencedirect.com/science/article/pii/S1452398123131129?via%3Dihub

W. Wang, R. Wang, and et al., Nano Lett. 143, 7485 (2023). https://pubs.acs.org/doi/10.1021/acs.nanolett.3c01991

C. Gao, J. Zhou, G. Liu, and L. Wang, J. Alloy. Compounds 727, 501 (2017). https://www.sciencedirect.com/science/article/abs/pii/S0925838817328785?via%3Dihub

M. Park, X. Zhang, and et al., J. Power Sources 195, 7904 (2010). https://www.sciencedirect.com/science/article/abs/pii/S0378775310010463?via%3Dihub

K.-F. Hsu, S.-Y. Tsay, and B.-J. Hwang, J. Mater. Chem. 14, 2690 (2004). https://pubs.rsc.org/en/content/articlelanding/2004/jm/b406774f

M. Li, L. Sun, and et al., J. Solid State Electrochem. 16, 3581 (2012). https://link.springer.com/article/10.1007/s10008-012-1790-8

M. S. Whittingham, Chem. Rev. 104, 4271 (2004). https://pubs.acs.org/doi/10.1021/cr020731c

J. W. Fergus, J. Power Sources 195, 939 (2010). https://www.sciencedirect.com/science/article/abs/pii/S0378775309015304?via%3Dihub

J. B. Goodenough and Y. Kim, Chem. Mater. 22, 587 (2019). https://pubs.acs.org/doi/10.1021/cm901452z

V. Aravindan, J. Gnanaraj, Y.-S. Lee, and S. Madhavi, J. Mater. Chem. A 1, 3518 (2013). https://pubs.rsc.org/en/content/articlelanding/2013/ta/c2ta01393b

M.-R. Yang, T.-H. Teng, and S.-H. Wu, J.Power Sources 159, 307 (2006). https://www.sciencedirect.com/science/article/abs/pii/S0378775306006847?via%3Dihub

S.-C. Jheng and J.-S. Chen, Int. J. Electrochem. Sci. 8, 4901 (2013). https://www.sciencedirect.com/science/article/pii/S1452398123146505?via%3Dihub

J.-H. Lin and J.-S. Chen, Electrochim. Acta 62, 461 (2012). https://www.sciencedirect.com/science/article/abs/pii/S0013468611018937?via%3Dihub

W.-J. Zhang, J. Power Sources 196, 2962 (2011). https://www.sciencedirect.com/science/article/abs/pii/S037877531002104X?via%3Dihub

X.-X. Zhao and et al., Adv. Mat. 36, 2308927 (2024). https://advanced.onlinelibrary.wiley.com/doi/10.1002/adma.202308927

K. Park, J. Son, H. Chung, and et al., Solid State Commun. 129, 311 (2004). https://www.sciencedirect.com/science/article/abs/pii/S0038109803009414?via%3Dihub

J. Liu, Z. Wang, and et al., Int. J. Electrochem. Sci. 8, 2378 (2013). https://www.sciencedirect.com/science/article/pii/S1452398123143161?via%3Dihub

Y.-W. Chen and J.-S. Chen, Int. J. Electrochem. Sci. 7, 8128 (2012). https://www.sciencedirect.com/science/article/pii/S1452398123179818?via%3Dihub

X. Yin, K. Huang, and et al., J. Power Sources 195, 4308 (2010). https://www.sciencedirect.com/science/article/abs/pii/S0378775310000741?via%3Dihub

M. Pan, X. Lin, and Z. Zhou, J Solid State Electrochem. 16, 1615 (2012). https://link.springer.com/article/10.1007/s10008-011-1564-8

Y.-F. Wu, Y.-N. Liu, and et al., J. Power Sources 256, 336 (2014). https://www.sciencedirect.com/science/article/abs/pii/S0378775314000548?via%3Dihub

J. Mun, H.-W. Ha, and W. Choi, J. Power Sources 251, 386 (2014). https://www.sciencedirect.com/science/article/abs/pii/S0378775313018612?via%3Dihub

F. Croce, A. D’ Epifanio, and et al., Electrochem. Solid St. 5, A47 (2002). https://iopscience.iop.org/article/10.1149/1.1449302

S. Yu, S. Dan, and et al., J. Solid State Electrochem. 16, 1675 (2012). https://link.springer.com/article/10.1007/s10008-011-1571-9

C.-W. Ong, Y.-K. Lin, and J.-S. Chen, J. Electrochem. Soc. 154, A527 (2007). https://iopscience.iop.org/article/10.1149/1.2720714

A. Naik, J. Zhou, and et al., J. Energy Inst. 89, 21 (2016). https://www.sciencedirect.com/science/article/abs/pii/S1743967114204004?via%3Dihub

X. Zhang, H. Guo, and et al., Solid State Ionics 212, 106 (2012). https://www.sciencedirect.com/science/article/abs/pii/S0167273812000598?via%3Dihub

N. Amdouni, K. Zaghib, and et al., Ionics 12, 117 (2006). https://link.springer.com/article/10.1007/s11581-006-0021-7

K. Zheng, Y. Wang, and et al., Water Res. 242, 120300 (2023). https://www.sciencedirect.com/science/article/abs/pii/S0043135423007364?via%3Dihub

J. Li, B. L. Armstrong, and et al., J. Colloid and Interf. Sci. 405, 118 (2013). https://www.sciencedirect.com/science/article/abs/pii/S0021979713004578?via%3Dihub

O. Toprakci, L. Ji, and et al., J. Power Sources 196, 7692 (2011). https://www.sciencedirect.com/science/article/abs/pii/S0378775311008718?via%3Dihub

C. Y. Wu, G. S. Cao, and et al., J. Phys. Chem. C 115, 23090 (2011). https://pubs.acs.org/doi/10.1021/jp205146d

M. M. Doeff, Y. Hu, and et al., Electrochem. Solid State Lett. 6, A207 (2003). https://iopscience.iop.org/article/10.1149/1.1601372

B. Jin, E. M. Jin, and et al., Electrochem. Commun. 10, 1537 (2008). https://www.sciencedirect.com/science/article/abs/pii/S1388248108003469?via%3Dihub

X. Sun, J. Li, and et al., J. Power Sources 220, 264 (2012). https://www.sciencedirect.com/science/article/abs/pii/S0378775312012177?via%3Dihub

L. Kavan, R. Bacsa, and et al., J. Power Sources 195, 5360 (2010). https://www.sciencedirect.com/science/article/abs/pii/S0378775310004180?via%3Dihub

K. Zaghib, A. Guerfi, and et al., J. Power Sources 232, 357 (2013). https://www.sciencedirect.com/science/article/pii/S0378775312019490?via%3Dihub

S. S. M. Safaa H. Ali1 and et al., Chem. Chem. Technol. 19 (2025). http://science2016.lp.edu.ua/chcht/photocatalytic-activity-defective-tio2-x-water-treatmentmethyl-orange-dye-degradation

S. H. Ali and S. S. Mohammed, MOMENTO 70, 45 (2025). https://revistas.unal.edu.co/index.php/momento/article/view/114275

N. Ravet, Y. Chouinard, and et al., J. Power Sources 97-98, 503 (2001). https://www.sciencedirect.com/science/article/abs/pii/S0378775301007273?via%3Dihub

C. Chen, G. Liu, Y. Wang, J. Li, and H. L. al., Electrochimica. Acta 113, 464 (2013). https://www.sciencedirect.com/science/article/abs/pii/S0013468613018574?via%3Dihub

B. Ramasubramanian, S. Sundarrajan, and et al., Batteries 832 (2022). https://www.mdpi.com/2313-0105/8/10/133

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