Publicado

2017-01-01

Evaluación mecanística matemática del desempeño de electrodo polimérico conductor, modificado por fragmentos de safranina, en la detección de compuestos hidroquinónicos. Posible ejemplo de galato de propilo

Mechanistic mechanism evaluation of the performance of polymeric conductor electrode, modified by fragments of safranin, in the detection of hydroquinonic compounds. Possible example of propyl gallate

Palabras clave:

Higiene de los alimentos, compuestos quinónicos, cuantificación, electrodos químicamente modificados, safranina, estado estacionario estable (es)
Food hygiene, quinone compounds, quantification, chemically modified electrodes, safranin, stable steady state (en)

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Autores/as

  • Volodymyr Tkach Universidad Nacional de Chernivtsi, 58012, Calle de Kotsyubyns´ky, 2, Ucrania
  • Yana G. Ivanushko Universidad Nacional de Chernivtsi, 58012, Calle de Kotsyubyns´ky, 2, Ucrania
  • Sílvio C. de Oliveira Universidade Federal de Mato Grosso do Sul, Av. Sen. Felinto. Müller, 1555, C/P. 549, 79074- 460, Campo Grande, MS
  • Reza Ojani Universidad de Mazandarán, tercer km Ruta de Fuerzas Aéreas, 47416-95447, Babolsar
  • Petró I. Yagodynets´ Universidad Nacional de Chernivtsi, 58012, Calle de Kotsyubyns´ky, 2
Se evaluó teóricamente el desempeño electroanalítico de un electrodo polimérico conductor, modificado por fragmentos de safranina, en la cuantificación electroquímica de compuestos hidroquinónicos (con el ejemplo de galato de propilo). El modelo matemático correspondiente se evaluó mediante la teoría de estabilidad lineal y de análisis de bifurcaciones. El desempeño de safranina como modificadora
de electrodo se comparó con el de las otras sustancias modificadoras. La presencia de inestabilidades electroquímicas también se averiguó.

The electroanalytical performance of a conducting polymer electrode, modified by safranin fragments, was theoretically evaluated in the electrochemical quantification of hydroquinone compounds (with the example of propyl gallate). The corresponding mathematical model was evaluated using linear stability theory and bifurcation analysis. The performance of safranin as an electrode modifier was compared to that of the other modifying substances. The presence of electrochemical instabilities was also investigated. 

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