Obtaining ceramic substrates for inorganic membranes
Estudio de la obtención de sustratos cerámicos para membranas inorgánicas
DOI:
https://doi.org/10.15446/ing.investig.v25n2.14641Keywords:
sol-gel, membrane, support, sintering, SEM (en)sol-gel, membranas, soportes, sintetización a AL2O3 (es)
Downloads
This project investigated the effect of compacting pressure and sintering temperature on supports’ physical and mechanical properties. The supports were prepared by axial compacting of a Al2O3 powders using pseudoboehmita and silica gel as binder. Hydrated magnesium oxide was used as sintering helper. the prepared agglutinants were characterized by x-ray sedigraphy. The supports were synthesized by SEM and their compression strength and porosity were evaluated and characterized by EDX sweeping electron microscope (SEM). These binders and the helper were prepared by the sol-gel process.
En este proyecto, primeramente, se elaboraron soportes para membranas inorgánicas usando a Al2O3 como componente base y empleando como aglutinantes pseudoboehmita y sílica coloidal, y como coadyuvante de sinterizado un óxido hidratado de magnesio; todas estas sustancias fueron sintetizadas mediante el empleo de procesos sol - gel. También se analizó el efecto que sobre las propiedades físicas y mecánicas de los soportes ejercen la presión de compactación y la temperatura de sintonización. Los aglutinantes preparados se caracterizaron por sedigrafía de rayos X, y a los soportes elaborados se les midió la resistencia a la compresión y porosidad y fueron caracterizados por microscopia electrónica de barrido (SEM) análisis EDX.
References
Ananthakumar, S. y Warrier, K.G.K, “Extrusion Characteristics of Alumina Aluminium Titanate Composite Using Boehmite as a Reactive Binder”, en Journal of the European Ceramic Society, Vol. 21, No. 1, Ene., 2001, pp. 71-78. DOI: https://doi.org/10.1016/S0955-2219(00)00164-3
Barrera, V. y Barón, W, “Empleo de la técnica sol - gel en la elaboración de membranas cerámicas porosas soportadas. Fase I”, Tesis presentada a la Universidad Nacional de Colombia para optar al título de ingeniero químico, 2001.
Belin S, Santos L.R y Briois V., “Preparation of Ceramic Membranes from Surface Modified Tin Oxide Nanoparticles”, en Colloids and Surfaces A: Physicochemical. Eng. Aspects. Vol. 216, No. 1-3, Abr. 2003. DOI: https://doi.org/10.1016/S0927-7757(02)00548-4
Bhave, R., Inorganic Membranes: Synthesis, Characteristics and Applications, Chapman Hall, 1991. DOI: https://doi.org/10.1007/978-94-011-6547-1
Binner, Jon G. P Advanced ceramic processing and Technology, Vol.1, Noyes Publication (1990).
Brinker, C y Scherer, W, Sol Gel Science: The physics and Chemistry of Sol - Gel Processing, Academic Press, 1990.
Carberry J. J.; Varma A., Chemical Reaction and Reaction Engineering. Marcel Dekker. 1995.
Chang, C.H; Gopalan, C.; Lin, Y.S., “A Comparative Study on Thermal and Hydrothermal Stability of Alumina, Titania and Zirconia Membranes”, En Journal of Membrane Science. Vol. 91. No. 1-2, May 1994. pp. 27-45 DOI: https://doi.org/10.1016/0376-7388(94)00041-7
Chaudhuri S.; Bhattachartiee B. y Ganguli; D; Pal, A. K “Synthesis and Optical Characterization of Sol-Gel Derived Zinc Sulphide Nanoparticles Confined in Amorphous Silica Thin Films,” en Materials Chemistry and Physics, Vol. 78, No. 2, Feb 2002, pp 372-379. DOI: https://doi.org/10.1016/S0254-0584(02)00159-1
Conde A.; Durdn A.; De Damborenea, J.J., Polymeric, Sol - Gel Coatings as Protective Layers of Aluminium Alloys”. en Progress in Organic Coatings, Vol. 46, No. 4, Jun, 2003, pp. 1-9. DOI: https://doi.org/10.1016/S0300-9440(03)00014-6
Dilsiz, Nursel y Akovali, G., “Study of Sol - Gel Processing for Fabrication of Low Density Alumina Microspheres”. en Materials Science and Engineering A., Vol. 332, No. 1-2, Jun, 2002, pp. 91-96. DOI: https://doi.org/10.1016/S0921-5093(01)01726-9
Dima, A.; Dima, O; Moldovan, C; Cobianu, C; Savaniu, C; Zaharescu, M., “Substrate Influence on The Response of Sol - Gel Derived SnO2 Gas - Sensors”, en Thin Solid Films. Vol. 427, No. 1-2, Mar, 2003, pp. 427-431. DOI: https://doi.org/10.1016/S0040-6090(02)01217-8
Dongare.; M.K; Sonawane.; R.S; Hegde, S.G, “Preparation of Titanium (IV) Oxide Thin Film Photocatalyst By Sol-Gel Dip Coating”, en Materials Chemistry and Physics, Vol. 77, No. 3, Ene., 2002, pp. 744-750. DOI: https://doi.org/10.1016/S0254-0584(02)00138-4
Duran A; Gallardo, J., Di Martino, D.; Almeida, R, “Structure of Inorganic and Hybrid SiO2 sol-gel coatings studied by variable incidence infrared spectroscopy”, en Journal of Non-Crystalline Solids, Vol. 298, No. 2-3; Mar., 2002, pp. 219-225. DOI: https://doi.org/10.1016/S0022-3093(02)00921-3
Eksi, A.; Saritas, S, “Effects of powder hardness and particle size on the densification of cold isostatically pressed powder”, en Turkish J. Eng. Env. Sci, Vol. 54, No. 7-8, Jun., 2002, pp. 377-384.
Erdogan, G.; Seker, E., “Single Step Sol - Gel Made Gold on Alumina Catalyst for Selective Reduction of NOx Under Oxidizing Conditions: Effect of Gold Precursor and Reaction Conditions”, en Applied Catalysis A: General. Vol. 232, No. 1-2, Jun., 2002, pp. 203-217. DOI: https://doi.org/10.1016/S0926-860X(02)00115-1
Espinoza Beltrán, F.J; Díaz-Flores L.L.; Mendoza-Galván, R.; González Hernández J. “Qualitative evaluation of sol-gel SiO2 as a protective layer for soft surfaces”, en Surface and Coatings Technology. Vol. 148, No. 1, Nov., 2001, pp. 1-7. DOI: https://doi.org/10.1016/S0257-8972(01)01331-7
Falamaki, C.; Aghaie A.; Ardestani, N. “Membranes/ Catalitic Supports with Enhanced Permeability”, Journal of European Ceramics Society, Vol. 21, No. 13, Nov., 2001, pp. 2267-2274. DOI: https://doi.org/10.1016/S0955-2219(01)00094-2
Falamaki, C.; Shafiee, A.; Aghaie A., “Initial sintering stage pore growth mechanism applied to the manufacture of ceramic membrane supports”. en Journal of European Ceramics Society, Vol. 24, No. 8, Jul., 2004, pp. 2285-2292. DOI: https://doi.org/10.1016/S0955-2219(03)00643-5
Galindo, V. Hugo., Estudio de los procesos sol - gel para la obtención de un aglutinante apropiado para el peletizado de alúmina. tesis presentada a la Universidad Nacional de Colombia para optar al grado de magister, 2000.
Galusek, D.; Riley, F, “The Influence of Sintering Additives on the Indentation Response of Liquid - Phase Sintered Polycrystalline Alúminas”, en Philosophical magazine A. Vol. 82, No. 10, Oct., 2001, pp. 2041-2057. DOI: https://doi.org/10.1080/01418610208235715
Gaponenko N. V., Sol - Gel Derived Films in, Mesoporous Matrices: Porous Silicon, Anodic Alumina and Artificial Opals”, en Synthetic Metals, Vol. 124, No. 1, Oct., 2001, pp. 125-130. DOI: https://doi.org/10.1016/S0379-6779(01)00447-7
García-Cerda, L.A.; Mendoza-González, O.; Pérez-Robles, J.F., “Structural Characterization and Properties of Colloidal Silica Coatings on Copper Substrates”, end Materials Letters. Vol. 56, No. 4, Oct., 2002, pp. 450-453. DOI: https://doi.org/10.1016/S0167-577X(02)00526-8
García-Miquel, J.L.; Zhang Q.; Allen, S.J.; Rougier, A., et al., “Nickel Oxide Sol-Gel Films from Nickel Diacetate for Electrochromic Applications”, en Thin Solid Films. Vol. 424, No. 2, Ene., 2003, pp. 165-170. DOI: https://doi.org/10.1016/S0040-6090(02)01041-6
Giannelis, E.P; Podeghirero, E.D.; Moore, B.C.; Wolkenberg, M.; Wuthenow, O.K., “Sol-Gel Synthesis of Ceramic Matrix Composites”, en Materials Science and Engineering A., Vol. 244, No. 1, Mar., 1998, pp. 11-21. DOI: https://doi.org/10.1016/S0921-5093(97)00821-6
González - Hernández, J., “Preparation and Characterization of Sol-Gel Silica Based Neutral Optical Density Coatings by The Addition of Graphite Particles”, en Thin Solid Films, Vol. 423, No. 2, Ene., 2003, pp.196-200. DOI: https://doi.org/10.1016/S0040-6090(02)01054-4
Guillard, C.; Beaugiraud, B.; Dutriez, C.; Herrmann, J.M.; Jaffrezic, H.; Jaffrezic-Renault, N.; Lacroix M., “Physicochemical Properties and Photo Catalytic Activities of TiO2 Films Prepared by Sol - Gel Methods”, en Thin Solid Films. Vol. 340, No. 1-2, Feb., 1999, pp. 280-287.
Guillén, C.; Gandía, J.; Morales, A.; Herrero, J., “SiO2 Sol-Gel Coated Conducting Substrates for CuInSe2 Electrodeposition”, en Surface and Coatings Technology, Vol. 115, No. 1, Jun., 1999, pp. 45-51. DOI: https://doi.org/10.1016/S0257-8972(99)00138-3
Gutiérrez, A.; González-Cruz, M.; Trombetta, G.; Ramirez, J., “Characterization of Alumina -Titania Mixed Oxide Supports. Part II Al2O3 - based supports”, en Microporous and Mesoporous Materials., Vol. 23, No. 5-6, Sep., 1998, pp. 265-275. DOI: https://doi.org/10.1016/S1387-1811(98)00121-8
Hofacker, S.; Menchelt, M.; Mange L, M.; Kraus H. “Sol - Gel: A New Tool for Coatings Chemistry”, en Progress in Organic Coatings, Vol. 45, No. 2-3, Oct., 2002, pp. 159-164. DOI: https://doi.org/10.1016/S0300-9440(02)00045-0
Humphrey, K. L.; Keller, G.E., Separation Process Technology, Mc Graw Hill (1997) Cap. 5.
Hwang, Y.; Liu, M.; Jiang S, “Preparation and Electrical Properties of ZnO-Glass Ceramic Films”, en Microelectronic Engineering, 1 (2002), DOI: https://doi.org/10.1016/S0167-9317(02)00996-6
Ibrahim, D.M.; Khalil T.; Mostafa, A.A., “Densification of Alumina Produced by Urea Formaldehyde Sol - Gel Polymeric Route”, en Ceramics International Vol. 25, No. 3, Abr.,1999, pp. 273-280. DOI: https://doi.org/10.1016/S0272-8842(98)00036-4
Ivanova, T.; Harizanova, A.; Surtchev, M.; Nenova, Z., “Investigation of sol-Gel Derived Thin Films Titanium Dioxide Doped with Vanadium Oxide”, en Solar Energy Materials and Solar Cells., Vol. 76, No. 4, Abr., 2003, pp. 591-598. DOI: https://doi.org/10.1016/S0927-0248(02)00269-6
Jayavel, R.; Madeswaran, S.; Giridharan, N. V., “Sol-Gel Synthesis and Property Studies of Layered Perovskite Bismuth Titanate Thin Films”, en Materials Chemistry and Physics, Vol. 80, No. 1, Abr., 2003, pp. 23-28. DOI: https://doi.org/10.1016/S0254-0584(02)00489-3
Jones, C.D.; Hidalgo, Maria.; Wiesner, M.; Barron, A., “Alumina Ultrafiltration Membranes Derived from Carboxylate - Alumoxane Nanoparticles”, en Journal of Membrane Science, Vol. 193, No. 2, Nov., 2001, pp.175-184. DOI: https://doi.org/10.1016/S0376-7388(01)00490-2
King, D. J.; Hang, H.; Oh Hoon S.; Kim, J., “Influence of Calcination Temperature on Structural and Optical Properties of TiO2 Thin Films Prepared by Sol - Gel Dip Coating”, en Materials Letters, Vol. 57, No. 2, Dic., 2002, pp. 355-360. DOI: https://doi.org/10.1016/S0167-577X(02)00790-5
Kirszensztejn, P; Szymkowiak, A.; Marciniak, P; Martyla, A.; Przekop R., “Texture of Al2O3 - SnO2 binary oxides system obtained via Sol - Gel Chemistry”, en Applied Catalysis A: General., Vol. 245, No. 1, May., 2003, pp. 159-166. DOI: https://doi.org/10.1016/S0926-860X(02)00651-8
Kwang Hsien y Lin Bor-Horng., “The Effect of Sol - Gel Particle Reaction on Properties of Two Dimensional Ceramics Matrix Composites”, en Materials Letters, Vol. 48, No. 3-4, Abr., 2001, pp. 230-241. DOI: https://doi.org/10.1016/S0167-577X(00)00309-8
Molina, D.; Patarroyo Diana., “Estudio de la síntesis de geles de óxido de magnesio a partir de procesos sol gel por precursores metalorgánicos”, Bogotá, tesis presentada a la universidad, Nacional de Colombia, Bogotá, para optar al título de Ingeniero químico, 2004.
Sepúlveda, J.; Virguez, M., “Remoción de fenol En medio acuoso diluido por medio de catálisis heterogénea en operación continua”, Tesis presentada a la universidad, Nacional de Colombia, Bogotá, para optar al título de ingeniero químico.
Orjuela, A., Tesis presentada a la Universidad Nacional de Colombia, Bogotá, para optar al título de maestra en ingeniería. 2003.
How to Cite
APA
ACM
ACS
ABNT
Chicago
Harvard
IEEE
MLA
Turabian
Vancouver
Download Citation
License
Copyright (c) 2005 Gabriel Camargo Vargas, Hugo Martín Galindo V
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors or holders of the copyright for each article hereby confer exclusive, limited and free authorization on the Universidad Nacional de Colombia's journal Ingeniería e Investigación concerning the aforementioned article which, once it has been evaluated and approved, will be submitted for publication, in line with the following items:
1. The version which has been corrected according to the evaluators' suggestions will be remitted and it will be made clear whether the aforementioned article is an unedited document regarding which the rights to be authorized are held and total responsibility will be assumed by the authors for the content of the work being submitted to Ingeniería e Investigación, the Universidad Nacional de Colombia and third-parties;
2. The authorization conferred on the journal will come into force from the date on which it is included in the respective volume and issue of Ingeniería e Investigación in the Open Journal Systems and on the journal's main page (https://revistas.unal.edu.co/index.php/ingeinv), as well as in different databases and indices in which the publication is indexed;
3. The authors authorize the Universidad Nacional de Colombia's journal Ingeniería e Investigación to publish the document in whatever required format (printed, digital, electronic or whatsoever known or yet to be discovered form) and authorize Ingeniería e Investigación to include the work in any indices and/or search engines deemed necessary for promoting its diffusion;
4. The authors accept that such authorization is given free of charge and they, therefore, waive any right to receive remuneration from the publication, distribution, public communication and any use whatsoever referred to in the terms of this authorization.