Published
Copper Recovery Through Smelter Slag Flotation in Atacama, Chile: An Industrial Case Study
Recuperación de cobre mediante flotación de escorias de fundición en Atacama, Chile: un estudio de caso industrial
DOI:
https://doi.org/10.15446/ing.investig.v41n1.84162Keywords:
Copper slag, flotation, concentrate smelting (en)Escoria de cobre, flotación, fusión de concentrados (es)
Copper slag flotation was studied on an industrial scale at a concentrator plant in the region of Atacama, Chile. This study consisted of the physical, chemical, and mineralogical characterization of the copper slag, along with preliminary flotation tests. This article focuses on industrial flotation, which consisted of two oneyear campaigns (2016 and 2017). The first campaign was carried out using an existing copper slag flotation circuit in the plant. During the second campaign (2017), a circuit for sulfide ore flotation with an additional columnar flotation cleaning stage was evaluated. Results showed an improvement in metallurgical parameters on the second campaign (including improvements in processing capacity, concentrate copper grade, and metallurgical recovery). From the industrial copper slag flotation campaigns, it was concluded that it is possible to obtain a commercialquality copper concentrate, suitable for further processing in a copper smelter. This mitigates certain environmental impacts of copper processing.
Se estudió la flotación industrial de cobre en una planta concentradora de la Región de Atacama, Chile. El estudio consistió en la caracterización física, química y mineralógica de la escoria de cobre, además de las pruebas preliminares de flotación. Este artículo se enfoca en la flotación a nivel industrial, la cual consistió en dos campañas de un año cada una (2016 y 2017). En la campaña del 2016 se utilizó un circuito de flotación de escorias existente en la planta. Para la segunda campaña (2017), se utilizó un circuito de flotación de súlfuros, más una etapa adicional de limpieza mediante flotación columnar. Los resultados mostraron un mejor desempeño en la segunda campaña respecto a la primera, al evaluar los parámetros metalúrgicos tales como: capacidad de procesamiento, ley de cobre y recuperación metalúrgica. De los resultados de las campañas a nivel industrial se concluye que, mediante la flotación de escorias de cobre, es posible obtener un concentrado de calidad adecuada para su posterior procesamiento en una fundición.
References
Camus, F. and Tobar, M. (2017). Determinación del índice de trabajo a menas con contenido de valor comercial de diversos sectores de la IV Región. Chile: Universidad de La Serena. https://doi.org/10.13140/RG.2.2.19978.82886
Cardona, N., Coursol, P., Vargas, J., and Parra, R. (2011). The physical chemistry of copper smelting slags and copper losses at the Paipote smelter part 2 Characterisation of industrial slags. Canadian Metallurgical Quarterly, 50(4), 330-340. https://doi.org/10.1179/000844311X13112418194806
Cendoya, P. (2009). Efecto en la Resistencia de las Escorias de Fundición de Cobre como Agregado Fino en el Comportamiento Resistente del Hormigón. Ingeniare. Revista Chilena de Ingeniería, 17(1), 85–94. http://dx.doi.org/10.4067/S0718-33052009000100009
COCHILCO. (2018). Análisis del mercado de insumos críticos en la minería del cobre (Issue 2018). Chile: Gobierno de Chile. https://www.cochilco.cl/Mercado%20de%20Metales/Analisis%20Mercado%20de%20los%20Insumos%20Cr%EDticos%202017%20(empresas).pdf
Couble, C. (2016). Revisión y actualización del método de reconciliación del Convertidor Teniente en Fundición Hernán Videla Lira ENAMI (Master’s thesis in Chemical Engineering, Universidad Técnica Federico Santa María, Spain). http://hdl.handle.net/11673/23169
Delgado, C. (2013). Evaluación de un cambio tecnológico para el procesamiento de minerales de alta dureza. Chile: Universidad de Chile. http://repositorio.uchile.cl/handle/2250/114434
Devia, M., Parra, R., Queirolo, C., Sánchez, M., and Wilkomirsky, I. (2019). Copper smelting and converting: past and present Chilean developments. Mineral Processing and Extractive Metallurgy: Transactions of the Institute of Mining and Metallurgy, 128(12), 108-116. https://doi.org/10.1080/25726641.2018.1542050
Fan, J., Li, H., Wei, L., Li, C., and Sun, C. (2017). The Recovery of Copper from Smelting by Flotation Process. In T. P. (eds) Wang S., Free M., Alam S., Zhang M. (Ed.), Applications of Process Engineering Principles in Materials Processing, Energy and Environmental Technologies. An EPD Symposium in Honor of Professor Ramana G. Reddy. Springer International Publishing AG. https://doi.org/10.1007/978-3-319-51091-0_21
Gorai, B., Jana, R. K., and Premchand. (2003). Characteristics and utilisation of copper slag A review. Resources, Conservation and Recycling, 39(4), 299-313. https://doi.org/10.1016/S0921-3449(02)00171-4
Guarda, N. (2015). Efecto del enfriamiento controlado en el consumo de energía y la recuperación de valiosos en el procesamiento de escorias de fusión de cobre. Chile: Universidad de Chile. http://repositorio.uchile.cl/handle/2250/137113
Guo, Z., Zhu, D., Pan, J., Wu, T., and Zhang, F. (2016). Improving Beneficiation of Copper and Iron from Copper Slag by Modifying the Molten Copper Slag. Metals, 6(4), 86. https://doi.org/10.3390/met6040086
Herrera, P. (2018). Evaluación de circuitos de flotación de escoria en Planta Manuel Antonio Matta (Metallurgical Engineering Thesis, Universidad de Atacama, Atacama Chile).
Mihajlović, A., Kamberović, Ž., Korać, M., Gavrilovski, M., and Jovanović, N. (2015). The effect of primary copper slag cooling rate on the copper valorization in the flotation process. Metallurgical and Materials Engineering, 21(2), 127-141. https://doi.org/10.30544/102
Nazer, A., Pavez, O., Rojas, F., and Aguilar, C. (2010). Una Revisión De Los Usos De Las Escorias De Cobre. X CONAMET/SAM, 1, 5. http://iberomet2010.260mb.com/pdfcongreso/.../T536_nazer_n1_FINAL
Pavez, O., Nazer, A., Rivera, O., Salinas, M., and Araya, B. (2019). Copper slag from different dumps in the Atacama Region used in mortars as partial replacement of cement. Revista Materia, 24(2). http://dx.doi.org/10.1590/s1517-707620190002.0664
Schlesinger, M., King, M., Sole, K., and Davenport, W. (2011). Extractive Metallurgy of Copper (Fifth edition). Amsterdam, Netherlands: Elsevier.
Shamsi, M., Noaparast, M., Shafaie, S. Z., and Gharabaghi, M. (2015). Synergism effect of collectors on copper recovery in flotation of copper smelting slags. Geosystem Engineering, 19(2), 57-68. https://doi.org/10.1080/12269328.2015.1087349
Sibanda, V., Sipunga, E., Danha, G., and Mamvura, T. A. (2020). Enhancing the flotation recovery of copper minerals in smelter slags from Namibia prior to disposal. Heliyon, 6(1) E03135. https://doi.org/10.1016/j.heliyon.2019.e03135
Sipunga, E. (2015). Optimization of the flotation of copper smelter slags from Namibia Custom Smelters ’ Slag Mill Plant (Master’s Thesis University of the Witwatersrand, Johannesburg, South Africa). http://wiredspace.wits.ac.za/handle/10539/20110
Tong, X., Han, B., Ren, S. P., and Yang, B. (2014). Recovery of copper from copper smelter slag by flotation. Applied Mechanics and Materials, 496500, 406-409. https://doi.org/10.4028/www.scientific.net/AMM.496-500.406
Tuck, C. A. (2019). Iron Ore. In U.S. Geological Survey (Eds.) Mineral Commodity Summaries, February 2019. Reston, VA: U.S. Geological Survey. https://doi.org/10.3133/70202434
Valderrama, L., Gonzalez, M., Santander, M., and Zazzali, B. (2018). Recuperación De Cobre Contenido En Escoria De Cobre Mediante Flotación. Holos, 5, 4050. https://doi.org/10.15628/holos.2018.7118
Valenzuela, A. (2016). Mining Waste Management in Chile: Experience, Challenges and Opportunities. Paper presented at XIV Congreso Internacional Expomin 2016: Workshop on best practices on mining policies and technologies. Thematic session 2 Mining waste management and mine rehabilitation. Santiago, Chile.
Velásquez, V. (2018). Optimización de la recuperación de cobre en el circuito de flotación de Codelco-El Salvador en base a la evaluación de nuevas formulaciones de reactivos de flotación (Metallurgical Engineering Thesis, Universidad de Concepción, Concepción, Chile). http://repositorio.udec.cl/jspui/bitstream/11594/3058/4/Tesis_Optimizacion_de_la_recuperacion_de_cobre.Image.Marked.pdf
Voisin, L., Pizarro, C., and Ossandon, J. (2017). Determination of the behaviour of valuable metals during the controlled cooling of copper smelting slags to clarify their recovery by grinding and flotation. Paper presented at the 5th International Slag Valorisation Symposium. http://slag-valorisation-symposium.eu/2017/wp-content/uploads/downloads/Session%203/Camila%20Pizarro%20-%20Paper%20-%20Determination%20of%20the%20behaviour%20of%20valuable%20metals%20during%20the%20controlled%20cooling%20of%20copper%20smelting%20slags%20to%20clarify%20their%20recovery%20by%20grinding%20and%20flotation%20-%20SVS2017.pdf
Wang, J.P. and Erdenebold, U. (2020). A study on reduction of copper smelting slag by carbon for recycling into metal values and cement raw material. Sustainability, 12(1421). https://doi.org/10.3390/su12041421
Xue, P., Li, G., and Qin, Q. (2016). Recovery of copper from slow cooled ausmelt furnace slag by floatation. Characterization of Minerals, Metals, and Materials 2015, 621-628. 10.1007/9783319481913_78
How to Cite
APA
ACM
ACS
ABNT
Chicago
Harvard
IEEE
MLA
Turabian
Vancouver
Download Citation
CrossRef Cited-by
1. Val. V. Spiryagin, I. N. Kravchenko, Yu. A. Kuznetsov, Vit. V. Spiryagin. (2024). Review of International Experience in Substantiating the Technology of Smelting Copper Sulfide-Containing Concentrates Taking into Account the Criterion "Efficiency-Economic Efficiency-Environmental Friendliness". Elektronnaya Obrabotka Materialov, 60(6), p.13. https://doi.org/10.52577/eom.2024.60.6.13.
2. I. N. Kravchenko, Val. V. Spiryagin, Vit. V. Spiryagin, A. M. Kadyrmetov. (2025). Smelting Technology for Copper Sulfide Concentrates: Balancing Efficiency, Economic Feasibility, and Environmental Performance—A Review of International Experience. Russian Metallurgy (Metally), 2025(5), p.1058. https://doi.org/10.1134/S0036029525701897.
3. Tonmoy Kundu, Suchismita Senapati, Surya Kanta Das, Shivakumar I. Angadi, Swagat S. Rath. (2023). A comprehensive review on the recovery of copper values from copper slag. Powder Technology, 426, p.118693. https://doi.org/10.1016/j.powtec.2023.118693.
4. Luis Valderrama, Jaime Tapia, Osvaldo Pavez, Mario Santander, Víctor Rivera, Miguel Gonzalez. (2024). Recovery of Copper from Slags Through Flotation at the Hernán Videla Lira Smelter. Minerals, 14(12), p.1228. https://doi.org/10.3390/min14121228.
5. Denis Shishin, Nagendra Tripathi, Svetlana Sineva, Evgueni Jak. (2024). Thermodynamic Modeling and Research for Processing Complex Concentrate Blends in Custom Copper Smelters for Maximum Revenue. Processes, 12(12), p.2820. https://doi.org/10.3390/pr12122820.
6. Val. V. Spiryagin, I. N. Kravchenko, Yu. A. Kuznetsov, Vit. V. Spiryagin. (2025). Review of International Experience in Substantiating the Technology of Smelting Copper Sulfide-Containing Concentrates Taking into Account the Criteria of Efficiency, Cost Effectiveness, and Environmental Friendliness. Surface Engineering and Applied Electrochemistry, 61(2), p.192. https://doi.org/10.3103/S1068375525700097.
7. Denis Shishin, Nagendra Tripathi, Igor Babaian, Evgueni Jak. (2025). Proceedings of the 63rd Conference of Metallurgists, COM 2024. , p.315. https://doi.org/10.1007/978-3-031-67398-6_56.
Dimensions
PlumX
Article abstract page views
Downloads
License
Copyright (c) 2020 Osvaldo Pavez, Pablo Herrera, Miguel González, Oscar Rivera

This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors or holders of the copyright for each article hereby confer exclusive, limited and free authorization on the Universidad Nacional de Colombia's journal Ingeniería e Investigación concerning the aforementioned article which, once it has been evaluated and approved, will be submitted for publication, in line with the following items:
1. The version which has been corrected according to the evaluators' suggestions will be remitted and it will be made clear whether the aforementioned article is an unedited document regarding which the rights to be authorized are held and total responsibility will be assumed by the authors for the content of the work being submitted to Ingeniería e Investigación, the Universidad Nacional de Colombia and third-parties;
2. The authorization conferred on the journal will come into force from the date on which it is included in the respective volume and issue of Ingeniería e Investigación in the Open Journal Systems and on the journal's main page (https://revistas.unal.edu.co/index.php/ingeinv), as well as in different databases and indices in which the publication is indexed;
3. The authors authorize the Universidad Nacional de Colombia's journal Ingeniería e Investigación to publish the document in whatever required format (printed, digital, electronic or whatsoever known or yet to be discovered form) and authorize Ingeniería e Investigación to include the work in any indices and/or search engines deemed necessary for promoting its diffusion;
4. The authors accept that such authorization is given free of charge and they, therefore, waive any right to receive remuneration from the publication, distribution, public communication and any use whatsoever referred to in the terms of this authorization.










