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Extrapolación a dilución infinita del volumen molar aparente de sales de amonio cuaternario en soluciones acuosas diluidas
Keywords:
Molar, Densidad, Amonio cuaternario, Sales de amonio, Acuosas diluidas (es)Downloads
Se midieron las densidades a 25,000 ± 0,006°C de soluciones acuosas diluidas de los yoduros de bencil trimetll amonio y dimetil dibencil amonio, e mpleando un densímetro de flotación magnética. Se calcularon los volúmenes molares aparentes 0v S^ obtuvieron volúmenes molares parciales a dilución infinita, extrapolando los valores de 0 ^ mediante la ecuación de Redlich y Meyer yj—°y + S^y^c-Fb^c,
sin el término bvc. El cambio progresivo de un grupo metilo por un grupo bencilo en el yoduro de tetrametll amonio produce un incremento en el volumen parcial molar a dilución infinita de 64,4 ml/mol para las sales estudiadas.
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