Analysing a method for small and medium sized companies to rate oil quality during immersion frying
Método de análisis de calidad del aceite durante el freído por inmersión para pequeñas y medianas empresas
DOI:
https://doi.org/10.15446/ing.investig.v31n1.20566Keywords:
immersed frying, viscosity, Lovibond colour, anisidine value, oil deterioration. (en)freído por inmersión, viscosidad, color Lovibond, índice de anisidina, deterioro del aceite. (es)
Downloads
This work studied the deterioration of commercial Frytol oil in controlled frying conditions using the anisidine index (AI) as standard evaluation method. The effect of temperature and time was studied at 170°C for up to 10 hours and at 200°C for up to 6 hours in the presence of factors which speeded up oil deterioration: 1% and 8% water based on the mass of oil and non-lipid material, 1% and 6% based on the mass of oil. Air flow rate was kept constant at 25 L h-1. The relationship between AI, colour and viscosity was studied to evaluate the technical viability of measuring these variables as a function of time to be used as a method for rating oil deterioration by small and medium sized enterprises (SME). Oil deterioration was higher and faster at maximum study interval values for each experimental factor, although only the effect of temperature was significant (p<0.05). Red and yellow on the Lovibond scale were weakly related (AI R2=0.558 and R2=0.526, respectively), colour depending on frying temperature. Viscosity measured at 30°C had the highest coefficient of determination (R2=0.809) and was independent of frying temperature. Viscosity is thus a variable which can be used for determining frying oil deterioration in SME as a consequence of a significant change from 10 cP to 45 cP which is closer to frying oil deterioration limit (AI 156). It can facilitate determination and lower associated costs, there-by improving product quality and customer confidence in them.
Este trabajo estudió el deterioro de un aceite comercial, Frytollíquido, bajo condiciones controladas de freído, empleando como método estandarizado para su evaluación el índice de anisidina (IAn). Se determinó el efecto de la temperatura y del tiempo de fritura, 170 °C hasta 10 horas y 200 °C hasta 6 horas, en presencia de los acelera-dores: agua, 1% y 8% en peso con respecto al aceite, y material no lipídico, 1% y 6% en peso con respecto al aceite, manteniendo constante el flujo de aire en 25 L h-1. Posteriormente se estableció la relación del IAn con las propiedades color y viscosidad, para determinar su viabilidad técnica como métodos de valoración del deterioro de los aceites de fritura en pequeñas y medianas empresas (pyme). El aceite se deterioró más y en menor tiempo en los valores máximos del intervalo de estudio para cada uno de los factores experimentales, aunque sólo la temperatura tuvo un efecto estadísticamente diferente de cero (p <0,05), en el intervalo de estudio. Los colores rojo y amarillo en escala Lovibond tuvieron una relación débil con el Ian, R2 = 0,558 y R2 = 0,526 respectivamente, existiendo dependencia del color con la temperatura de freído. La viscosidad, medida a 30 °C, tuvo la mayor correlación (R2 = 0,809) y fue independiente de la temperatura de freído, de tal forma que puede emplearse para determinar el deterioro de los aceites de fritura en pyme. Un cambio radical en el valor de la viscosidad, de 10 cP a 45 cP en las cercanías del límite de deterioro de los aceites de fritura (IAn 156), la facilidad de su determinación y los bajos costos asociados, permitirá que este tipo de empresas puedan implementarla como variable de seguimiento, lo que mejorará la calidad de los productos y la confianza de los clientes en ellos.
Downloads
References
AOAC 925.10, 1990., Solids/Total Solids, Moisture, Official Methods of Analysis of the Association of Official Agricultural Chemists (AOAC), 17th Edition, USA, 2000.
AOAC 920.85, 1998., Fat/Crude Fat, Fat/Ether Extract, Official Methods of Analysis of the Association of Official Agricultural Chemists (AOAC), 17th Edition, USA, 2000.
AOAC 960.52, 1998., Elemental Analysis / Nitrogen, Official Methods of Analysis of the Association of Official Agricultural Chemists (AOAC), 17th Edition, USA, 2000.
AOAC 942.05, 1998., Ash, Official Methods of Analysis of AOAC International, Official Methods of Analysis of the Association of Official Agricultural Chemists (AOAC), 17th Edition, USA, 2000.
AOAC 962.09, 1990., Fiber / Crude Fiber, Official Methods of Analysis of the Association of Official Agricultural Chemists (AOAC)
AOCS Ca 5a40 (09)., Free Fatty Acids, Official Methods and Recommended Practices of the American Oil Chemists´ Society, 6th Edition, USA, 2009.
AOCS Cd 853 (03)., Peroxide Value, Acetic AcidChloroform Method, Official Methods and Recommended Practices of the American Oil Chemists´ Society, 6th Edition, USA, 2009.
AOCS Cc 625 (09)., Cloud Point Test, Official Methods and Recommended Practices of the American Oil Chemists´ Society, 6th Edition, USA, 2009.
AOCS Cc 13e92 (09)., Lovibond (per ISO Standard), Official Methods and Recommended Practices of the American Oil Chemists´ Society, 6th Edition, USA, 2009.
ASTM D154507., Standard Test Method for Viscosity of Transparent Liquids by Bubble Time Method., American Standards for Testing Materials, USA, 2007.
Benedito, J., García, J. V., Dobarganes, M., Mulet, A., Rapid Evaluation of Frying Oil Degradation Using Ultrasonic Technology., Food Research International, Vol. 40, 2007, pp. 406-414.
Boatella, J., Codony, R., Rafecas, M., Guardiola, F., Recycled cooking oils: Assessment of risks for public health en European Parliament STOA Programme., Chambers, G., (ed.), European Parlament, Directorate General for Research. Luxembourgg, Septiembre, 2000., pp. 64.
Choe, E., Min, D. B., Chemistry of Deep-Fat Frying Oils., Journal of food science., Vol. 72, No. 5, 2007, pp. R77-R86.
Clark, W. L., Serbia, G. W., Safety Aspects of Frying Fats and Oils., Institute of Food Technologists., Vol. 45, No. 2, 1991, pp. 84-89.
Dobarganes, M. C., Velasco, J., Márquez, R. G., La calidad de los Aceites y Grasas de Fritura., Alimentación, Nutrición y Salud., Vol. 9, No. 4, 2002, pp. 109-118.
Firestone, D., Regulatory Requirements for the Frying Industry., En: Gupta, M. K., Warner, White P. J., (ed.), Frying technology and practices., AOCS Press., Champaign., 2004, pp. 200-216.
Gertz, C., Chemical and Physical Parameters as a Quality Indicator of Used Frying Fats., The European Journal Lipid Science Technology., Vol. 102, No. 8, 2000, pp. 566-572.
Gupta, M. K., The Effect of Oil Processing on Frying Oil Stability., En: Gupta, M. K., Warner, White P. J., (ed.), Frying technology and practices., AOCS Press., Champaign., 2004.
Gupta, M. K., Frying Oils, in Bailey´s Industrial Oil and Fats Products, Edible Oil and Fat Products: Products and Applications, Fereidoon Shahidi (ed.), 6th Ed., John Wiley and Sons., New York., USA., Vol. 4, 2005.
Keuneke, R., Health Destructive Effects of Frying., Total Health, Vol. 21, No.3, 1999, pp. 26-28.
Navas, J.A., Optimización y Control de la Calidad y Estabilidad de Aceites y Productos de Fritura., Tesis presentada a la Universidad de Barcelona España, Facultad de Farmacia, para optar al grado de Doctor en Medicamentos, Alimentación y Salud, 2005.
ICONTEC, NTC 4197, Grasas y Aceites Animales y Vegetales., Determinación del Índice de Anisidina., Equivalente a la ISO 6885:1998., Instituto Colombiano de Normas Técnicas y Certificación ICONTEC. I.C.S.: 67.200.20., Bogotá, Colombia, 2001.
O´Brien, R.D., Fats and Oils: Formulating and Processing for Applications., CRC Press., 2nd ed., Boca Ratón., USA., 2004.
Pokorny, J., (ed.), Yanishlieva, N., Gordon, M., Antioxidants in Food: Practical Applications., CRC Press., Woodhead Publishing Limited., Cambridge., 2001.
Rosell, J. B., Frying. Improving Quality., J. B. Rosell (ed.), Cambridge, England., Woodhead Publishing Limited., 2001.
Saguy, I.S., Dana, D., Integrated Approach to Deep Fat Frying: Engineering, Nutrition, Health and Consumer Aspects., Journal of Food Engineering., Vol. 56, 2003, pp. 143-152.
Sahin, S., Gülum, S. S., Advances in Deep Fat Frying., Contemporary Food Engineering Series., Sun, D., (ed.), CRC press, 2008.
Schaich, K., Lipid Oxidation: Theoretical Aspects, in Bailey´s Industrial Oil and Fats Products, Edible Oil and Fat Products: Chemistry, Properties and Health Effects, Fereidoon Shahidi (ed.), 6th ed., John Wiley and Sons., New York., USA., Vol. 1, 2005.
Shahidi, F., (ed.), Edible oil and Fat Products: Chemistry, Properties and Health Effects., En: Bailey´s Industrial Oil and Fat Products., Vol. 1, 6th ed., Wiley Interscience, New Jersey., 2005.
Santos, J., Santos, I., Souza, A., Effect of Heating and Cooling on Rheological Parameters of Edible Vegetable Oils., Journal of Food Engineering., Vol. 67, 2005, pp. 401-405.
Warner, K., Chemical and Physical Reactions in Oil During Frying. En: Gupta, M. K., Warner, White P. J., (ed.), Frying technology and practices., AOCS Press., Champaign., 2004.
Yagüe, M. A., Estudio de la Utilización de Aceites para Fritura en Establecimientos Alimentarios de Comidas Preparadas., Observatorio de la Seguridad Alimentaria., Septiembre, 2003., En internet: http://magno.uab.es/epsi/alimentaria/mangelesaylon.pdf. Visitada el 26 Agosto de 2008.
Zakrzewski, S., Principles of Envirommental Toxicology., American Chemical Society Professional Reference Book., Washington D.C., United States of America, 1991, pp 4455.
License
Copyright (c) 2011 Efraín Hisnardo Rojas Uribe, Paulo César Narváez Rincón

This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors or holders of the copyright for each article hereby confer exclusive, limited and free authorization on the Universidad Nacional de Colombia's journal Ingeniería e Investigación concerning the aforementioned article which, once it has been evaluated and approved, will be submitted for publication, in line with the following items:
1. The version which has been corrected according to the evaluators' suggestions will be remitted and it will be made clear whether the aforementioned article is an unedited document regarding which the rights to be authorized are held and total responsibility will be assumed by the authors for the content of the work being submitted to Ingeniería e Investigación, the Universidad Nacional de Colombia and third-parties;
2. The authorization conferred on the journal will come into force from the date on which it is included in the respective volume and issue of Ingeniería e Investigación in the Open Journal Systems and on the journal's main page (https://revistas.unal.edu.co/index.php/ingeinv), as well as in different databases and indices in which the publication is indexed;
3. The authors authorize the Universidad Nacional de Colombia's journal Ingeniería e Investigación to publish the document in whatever required format (printed, digital, electronic or whatsoever known or yet to be discovered form) and authorize Ingeniería e Investigación to include the work in any indices and/or search engines deemed necessary for promoting its diffusion;
4. The authors accept that such authorization is given free of charge and they, therefore, waive any right to receive remuneration from the publication, distribution, public communication and any use whatsoever referred to in the terms of this authorization.










